CAS 102-69-2 MFCD00009363-N,N-Dipropyl-1-Propanamine 三正丙胺 -LabNovo

N,N-Dipropyl-1-Propanamine 三正丙胺

CAS 102-69-2 MFCD00009363

化学结构图

SMILES: CCCN(CCC)CCC

化学属性

Mol. Formula	C9 H21 N
Mol. Weight	143.27
Autoignition Point	356 °F
Refractive index	1.4160 to 1.4180
Vapor Density	4.9 (vs air)
Boiling Point
Vapor Pressure	2.9 mmHg ( 20 °C)
Density	0.753
Melting Point	No Data Available
Flash Point	41°C(lit.)
TSCA	Yes
Solubility	微溶于水，溶于乙醚，易溶于乙醇。
Stability	对光敏感;对湿度敏感; 对二氧化碳敏感

别名和识别编码

Chemical Name	N,N-Dipropyl-1-Propanamine
MDL Number	MFCD00009363
CAS Number	102-69-2
Synonym	(n-C3H7)3N 1-Propanamine, N,N-dipropyl- 1-Propanamine,N,N-dipropyl- N,N-Dipropyl-1-propanamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	87576449
EC Number	203-047-7
Beilstein Registry Number	1098331
Reaxys-RN	1098331
Chemical Name Translation	三正丙胺
Wiswesser Line Notation	3N3&3
LabNetwork Molecule ID	LN01246944

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产品应用

溶剂。有机合成原料,合成全氟化人造血浆和石油化工季铵分子筛催化剂。在激光技术上也有重要用途。

安全信息

GHS Symbol

WGK Germany2

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H301+H311
H330 Fatal if inhaled 吸入致命

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSTX1575000

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241+P242+P243
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P301+P310
P301+P330+P331+P310
P303+P361+P353
P303+P361+P353+P310+P363
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P370+
P370+P378
P403+P235
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Packing GroupIII

UN Number 2260

Risk Statements

R10 Flammable 易燃
R21 Harmful in contact with skin 与皮肤接触有害
R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
R25 Toxic if swallowed 吞咽有毒
R34 Causes burns 会导致灼伤
R52/53

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S20 When using do not eat or drink 使用时，不得进食，饮水；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/38
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Hazard Codes 3 T T,C,Xn

Hazard Class3/8

Storage condition +4°C 4 4℃ Flammables area Hygroscopic 密封阴凉避光保存。

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 5100 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv.
   Toxicology of New Industrial Chemical Substances.  For English translation,
   see TNICS*.  (Izdatel'stvo Meditsina, Moscow, USSR)  No.1-    1961-
   Volume(issue)/page/year: 14,80,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 570 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 96 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5100 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982

其他信息

上游原料:正丙胺 --> 二正丙胺
图谱信息:三正丙胺(102-69-2)红外图谱(IR1) 三正丙胺(102-69-2)红外图谱(IR2) 三正丙胺(102-69-2)质谱(MS) 三正丙胺(102-69-2)核磁图( 13 CNMR)
TCI Shanghai:三正丙胺 Tripropylamine,>;98.0%(GC)(T)(102-69-2)
Alfa Aesar:三丙胺,98% Tri-n-propylamine, 98%(102-69-2)
用途三:溶剂。有机合成原料,合成全氟化人造血浆和石油化工季铵分子筛催化剂。在激光技术上也有重要用途。
灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
用途二:有机合成原料。用于合成全氟化人造血浆和石油化工季铵分子筛催化剂。在激光技术上也有重要用途。
有氨的气味。对二氧化碳敏感。能与乙醇、乙醚混溶，微溶于水。
海关编码:29211980
F:34
类别:易燃液体
急性毒性:口服-大鼠 LD50:72 毫克/公斤; 吸入-小鼠 LC50:3800 毫克/立方米/2小时
Acros Organics:三丙胺 Tripropylamine, 98%(102-69-2)
可燃性危险特性:遇明火、高温、氧化剂较易燃; 燃烧产生有毒氮氧化物烟雾
方法一:以正丙醇为原料在Ni-Cu-Al2O3催化剂作用下，脱氢生成丙醛，然后与氨加成，脱水、加氢生成丙胺，再经反复脱水、加氢生成二丙胺和三丙胺。反应温度为（210±10）℃，压力为396.66kPa。正丙醇空速为0.25-0.51L/L·h-1。原料配比为醇：氨：氢＝4：2：4。正丙醇转化率为75%-83%，二、三丙胺总产率为75%-80%，其中二丙胺37%-41%，三丙胺35%-40%。原料消耗定额：丙醇3500kg/t、氨500kg/t、氢气1200m3。
下游产品:正丙胺 --> 二正丙胺
MSDS 信息:三正丙胺(102-69-2).msds
三正丙胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80137127 三正丙胺 250ml 37元 2011/04/16 T0522 三丙胺 Tripropylamine 500ML 371元 2011/04/16 T0522 三丙胺 Tripropylamine 25ML 124元
蒸气密度:4.9 (vs air)
毒性分级:高毒
蒸气压:2.9 mm Hg ( 20 °C)
FEMA:4247
储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
用途一:用于制药物、农药、橡胶和纤维加工助剂等
MOL 文件:102-69-2.mol
外观性质:无色液体，有氨的气味。
Sigma Aldrich:102-69-2(sigmaaldrich)

N,N-Dipropyl-1-Propanamine 三正丙胺

CAS 102-69-2 MFCD00009363

化学结构图

化学属性

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相关产品推荐

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