(2-Bromoethyl)benzene (2-溴乙基)苯

CAS 103-63-9 MFCD00000240

化学结构图

103-63-9
SMILES: BrCCc1ccccc1

化学属性

Mol. FormulaC8H9Br
Mol. Weight185.06
Density1.355
Refractive index1.5560 to 1.5580
Boiling Point220-221°C at 760 mmHg
Flash Point96°C
TSCAYes
Melting Point-67.5°C
Solubility不溶
Appearance 无色液体。熔点-56℃,沸点220-221℃，217-218℃（97.62kPa），92℃（1.46kPa），相对密度1.3589，折光率1.5572。能与乙醚、苯混溶，不溶于水。闪点89℃。
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical Name(2-Bromoethyl)benzene
Synonym (2-Bromoethyl)benzene {LY} (2-Bromoethyl)benzene {} {LY} (2-Bromoethyl)benzene {} {} {LY} (2-Bromoethyl)benzene {} {} {} {LY} (2-Bromoethyl)benzene {} {} {} {} {LY} (2-Bromoethyl)benzene {} {} {} {} {} {LY} (2-Bromoethyl)benzene {} {} {} {} {} {} {LY} (2-Bromoethyl)benzene {} {} {} {} {} {} {} {LY} (2-Bromoethyl)benzene {} {} {} {} {} {} {} {} {LY} (2-Bromoethyl)benzene {} {} {} {} {} {} {} {} {} {LY} (2-Bromoethyl)benzene {} {} {} {} {} {} {} {} {} {} {LY} (2-Bromoethyl)benzene {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Bromoethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Bromoethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Bromoethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Bromoethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Bromoethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number103-63-9
EC Number203-130-8
Beilstein Registry Number5,356
MDL NumberMFCD00000240
PubChem Substance ID87563609
Reaxys-RN507487
Chemical Name Translation(2-溴乙基)苯
InChIInChI=1S/C8H9Br/c9-7-6-8-4-2-1-3-5-8/h1-5H,6-7H2
Canonical SMILESBrCCC1=CC=CC=C1
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分类

  • {SNA} Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

产品应用

  • 有机合成，农药中间体。

相关文献及参考

  • Sh
  • Short: IV/20A
  • Short: III/38B
  • Beilstein:5,356
  • Short: IV/16

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn
RTECSCY9032000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P311
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R36 Irritating to eyes 刺激眼睛
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} { 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 811 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0536710

Restrict -

其他信息

  • 用途二:有机合成，农药中间体。
  • 用途一:用作医药与农药中间体
  • 能与乙醚、苯混溶，不溶于水。
  • 下游产品:4-氯甲基苯乙烯 --> 1-(1-苯基乙基)哌嗪 --> n-甲基苯基乙胺 --> 苯基-1,2-乙二醇
  • TCI Shanghai:β-溴苯乙烷 (2-Bromoethyl)benzene,>;97.0%(GC)(103-63-9)
  • Sigma Aldrich:103-63-9(sigmaaldrich)
  • 上游原料:碳酸钾 --> 苯乙醇
  • 海关编码:29036990
  • beta-溴代苯乙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0594 (2-溴乙基)苯 (2-Bromoethyl)benzene 25G 156元 2014/06/02 B0594 (2-溴乙基)苯 (2-Bromoethyl)benzene 500G 947元 2010/06/21 106940025 beta-溴代苯乙烷 (2-Bromoethyl)benzene 98% 2.5 LT 4981元
  • Alfa Aesar:(2-溴乙基)苯,98% (2-Bromoethyl)benzene, 98%(103-63-9)
  • 方法一:由苯乙醇与溴化氢反应而得。将苯乙醇加热至110℃，慢慢通入溴化氢，回流反应。反应结束，冷却，依次用水、10%碳酸钠溶液、水洗涤。用无水碳酸钾干燥后减压分馏，收集97-99℃（2.0kPa）馏分，产率90%以上。
  • 图谱信息:beta-溴代苯乙烷(103-63-9)Raman光谱 beta-溴代苯乙烷(103-63-9)红外图谱(IR1) beta-溴代苯乙烷(103-63-9)质谱(MS) beta-溴代苯乙烷(103-63-9)红外图谱(IR2) beta-溴代苯乙烷(103-63-9)核磁图( 1 HNMR) beta-溴代苯乙烷(103-63-9)核磁图( 13 CNMR)
  • Acros Organics:(2-溴乙基)苯 (2-Bromoethyl)benzene, 98%(103-63-9)
  • MOL 文件:103-63-9.mol
  • MSDS 信息:1-Bromo-2-phenylethane(103-63-9).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C8 - Aryl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳香卤代烃
  6. C7