Allyl Glycidyl Ether 烯丙基缩水甘油醚

CAS 106-92-3 MFCD00005143

化学结构图

106-92-3
SMILES: C=CCOCC1CO1

化学属性

Mol. FormulaC6H10O2
Mol. Weight114
Refractive index1.4330 to 1.4360
Boiling Point154
Density0.962
Flash Point49°C(lit.)
TSCAYes
Melting Point-100°C
Vapor Density3.9 (vs air)
Vapor Pressure4.7 mmHg ( 25 °C)
Solubility溶于水，溶于丙酮、苯、四氯化碳、醇。

别名和识别编码

Chemical NameAllyl Glycidyl Ether
Synonym 1,2-EPOXY-3-ALLYLOXYPROPANE 1,2-Epoxy-3-allyloxypropane 1-(Allyloxy)-2,3-epoxypropane 1-ALLYLOXY-2,3-EPOXYPROPANE 1-Allilossi-2,3 epossipropano 1-Allyloxy-2,3-epoxy-propaan 1-Allyloxy-2,3-epoxy-propan 1-Allyloxy-2,3-epoxypropane 1-allilossi-2,3epossipropano ALLYL 2,3-EPOXYPROPYL ETHER Allyl 2,3-epoxypropyl ether Allyl oxiranemethyl ether Glycidyl 2-propenyl ether Glycidyl allyl ether Oxirane, [(2-propenyloxy)methyl]- Oxyde d'allyle et de glycidyle [(2-Propenyloxy)-methyl] oxirane [(2-propenyloxy)methyl]-Oxirane [2-Propenyloxy-methyl] oxirane allyl glycidyl ether allyl-2,3-epoxypropyl ether 烯丙基-2,3-环氧丙醚 烯丙基環氧丙基醚
CAS Number106-92-3
PubChem Substance ID7838
EC Number203-442-4
Beilstein Registry Number105871
MDL NumberMFCD00005143
Reaxys-RN105871
Chemical Name Translation烯丙基缩水甘油醚
Wiswesser Line NotationT3OTJ B1O2U1
LabNetwork Molecule IDLN00224533
InChIInChI=1S/C6H10O2/c1-2-3-7-4-6-5-8-6/h2,6H,1,3-5H2
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; alicycle; 3ring; ether; racemate; 1fragment
  • {SNA} Epoxide Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Epoxide Monomers, Materials Science, Monomers, Polymer Science

产品应用

  • 分子内既含有碳碳双键又有环氧键，是重要的聚合单体和有机合成中间体。

相关文献及参考

  • Short: EINECS
  • Short: IV/20B
  • Beilstein:17(3/4)990

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 3 Xn
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H351 Suspected of causing cancer 怀疑致癌
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSRR0875000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P312
  • P301+P312+P330
  • P302+P352
  • P302+P352+P333+P313+P362+P364
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P304+P340+P311
  • P305+P351+P338
  • P305+P351+P338+P310
  • P307+P311
  • P308+P311
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2219 UN 2219 3/PG 3
Risk Statements
  • R10 Flammable 易燃
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R52/53
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Packing GroupIII
Hazard Class3
Storage condition Refrigerator (+4°C)
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10 ppm/6H/2Y-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Sense Organs and Special Senses (Olfaction) - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-376,1990

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 10 ppm/6H/2Y-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Sense Organs and Special Senses (Olfaction) - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-376,1990

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 270 ppm/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Lungs, Thorax, or Respiration - dyspnea
   Gastrointestinal - changes in structure or fu

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 670 ppm/8H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - corneal damage
   Lungs, Thorax, or Respiration - acute pulmonary edema
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 14,250,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2550 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 14,250,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 390 mg/kg
TOXIC EFFECTS :
   Brain and Coverings - recordings from specific areas of CNS
   Behavioral - somnolence (general depressed activity)
   Behavioral - ataxia
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 14,250,1956

TYPE OF TEST            : LD50 - Le

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Klebsiella pneumoniae
DOSE/DURATION           : 500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 89,269,1981

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 5500 ppm
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7,349,1985

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 20 umol/L
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   46,277,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-376,1990

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 625 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 249,55,1991

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 3300 ug/L
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/p

其他信息

  • 储运特性:库房通风低温干燥; 与氧化剂分开储运
  • MSDS 信息:烯丙基缩水甘油醚(106-92-3).msds
  • 蒸气压:4.7 mm Hg ( 25 °C)
  • 海关编码:29109000
  • 急性毒性:口服-大鼠 LD50: 1600 毫克/公斤; 口服-小鼠 LD50: 390 毫克/公斤
  • 爆炸物危险特性:蒸气与空气混合可爆
  • 用途二:分子内既含有碳碳双键又有环氧键，是重要的聚合单体和有机合成中间体。
  • 类别:易燃液体
  • 外观性质:无色、透明液体, 有特殊的臭味。
  • 可燃性危险特性:易燃; 火场释放辛辣刺激烟雾
  • 蒸气密度:3.9 (vs air)
  • 烯丙基缩水甘油醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0221 烯丙基缩水甘油醚 Allyl Glycidyl Ether 25ML 109元 2014/06/02 A0221 烯丙基缩水甘油醚 Allyl Glycidyl Ether 500ML 305元 2010/06/21 102941000 烯丙基缩水甘油醚 Allyl glycidyl ether 99+% 100 GR 341元
  • MOL 文件:106-92-3.mol
  • 水中溶解度: 50 g/l (20°C) ，溶于乙醇、丙酮、乙醚和苯。
  • 灭火剂:干粉, 二氧化碳, 雾状水, 泡沫
  • Acros Organics:烯丙基缩水甘油醚 Allyl glycidyl ether, 99+%(106-92-3)
  • Sigma Aldrich:106-92-3(sigmaaldrich)
  • Alfa Aesar:烯丙基-2,3-环氧丙醚,97% Allyl glycidyl ether, 97%(106-92-3)
  • 毒性分级:高毒
  • 用途一:用作聚氨酯橡胶的原料及环氧树脂的稀释剂
  • 职业标准:TWA 22 毫克/立方米; STEL 45 毫克/立方米
  • 图谱信息:烯丙基缩水甘油醚(106-92-3)红外图谱(IR2) 烯丙基缩水甘油醚(106-92-3)红外图谱(IR1) 烯丙基缩水甘油醚(106-92-3)质谱(MS) 烯丙基缩水甘油醚(106-92-3)Raman光谱 烯丙基缩水甘油醚(106-92-3)核磁图( 13 CNMR)
  • 刺激数据:皮肤-兔子 485 毫克/3天 中度; 眼睛-兔子 97 毫克 重度
  • 下游产品:不饱和聚酯树脂
  • TCI Shanghai:烯丙基缩水甘油醚 Allyl Glycidyl Ether,>;99.0%(GC)(106-92-3)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Epoxide Monomers - Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Enol Ethers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Simple 3-Membered Ring Compounds 简单三元环化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Carboxylic Acid Monomers

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