1-Bromo-2-Chloroethane 1-溴-2-氯乙烷-kg

CAS 107-04-0 MFCD00000962

化学结构图

107-04-0
SMILES: ClCCBr

化学属性

Mol. FormulaC2H4BrCl
Mol. Weight143
Density1.723
Refractive index1.4880 to 1.4920
Boiling Point106-107
Melting Point-18--14
Flash PointNone
TSCAYes
Solubility难溶于水,可混溶于乙醇、乙醚、四氯化碳等。
Stability对光敏感

别名和识别编码

Chemical Name1-Bromo-2-Chloroethane
CAS Number107-04-0
EC Number203-456-0
Beilstein Registry Number605265
MDL NumberMFCD00000962
Synonym 1,2-溴氯乙烷 1-Brom-2-chlorethan 1-Bromo-2-chloroethane 1-bromo-2-chloro-ethan 1-bromo-2-chloro-ethane 1-bromo-4-chloro-butane 1-chloro-bromoethane(cbe) 1-氯-2-溴乙烷,氯乙基溴,2-氯-1-溴乙烷 1-溴-2-氯乙烷, 98+% 2-Bromo-1-chloroethane 2-Bromoethyl chloride 2-CHLORO-1-BROMOETHANE 2-CHLOROETHYL BROMIDE Chlorobromoethane ETHYLENE BROMOCHLORIDE ETHYLENE CHLOROBROMIDE Ethylen chlorobromid Ethylene bromochl Ethylene bromochloride, Ethylene chlorobromide beta-Chloroethyl bromide caswellno.436b epapesticidechemicalcode042001 ethylene chlorobromide s-Chlorobromoethane {} {} {} {} {Chemica Äthylenchlorbromid 亚乙基氯溴化物 氯乙基溴 溴乙基氯
PubChem Substance ID87563590
Reaxys-RN605265
Chemical Name Translation1-溴-2-氯乙烷-kg
Wiswesser Line NotationG2E
LabNetwork Molecule IDLN00222137
InChIInChI=1S/C2H4BrCl/c3-1-2-4/h1-2H2
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分类

  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 用于有机合成,溶剂,薰蒸剂。

相关文献及参考

  • Beilstein:1(4)155
  • Short: II/25B
  • Short: IV/10A
  • Short: III/38B

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Risk Statements
  • R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R25 Toxic if swallowed 吞咽有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P302+P350
  • P302+P352+P312+P362+P364
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P332+P313
  • P337+P313
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H312+H332
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H350 May cause cancer 可能致癌
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSKH6500000
Packing GroupIII
UN Number 2810 UN2810
Storage condition Light Sensitive
Hazard Codes 6.1 T
Hazard Class6.1
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 64 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College
   Science Pub., 1969  Volume(issue)/page/year: 4,73,1969

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 285,209,1993

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 500 umol/kg
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 4,1491,1983

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 7 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 285,209,1993

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   MUREAV

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 2,499,1981

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 10 mg/plate
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   34,2576,1974

Restrict 危险品

其他信息

  • TCI Shanghai:1-溴-2-氯乙烷 1-Bromo-2-chloroethane,>;98.0%(GC)(107-04-0)
  • 图谱信息:1-溴-2-氯乙烷(107-04-0)核磁图( 1 HNMR) 1-溴-2-氯乙烷(107-04-0)质谱(MS) 1-溴-2-氯乙烷(107-04-0)红外图谱(IR2) 1-溴-2-氯乙烷(107-04-0)红外图谱(IR1) 1-溴-2-氯乙烷(107-04-0)核磁图( 13 CNMR)
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 毒性分级:高毒
  • 上游原料:碳酸钠 --> 2-氯乙醇
  • MSDS 信息:氯乙基溴(107-04-0).msds
  • Alfa Aesar:1-溴-2-氯乙烷,98+% 1-Bromo-2-chloroethane, 98+%(107-04-0)
  • Acros Organics:1-溴-2-氯乙烷 1-Bromo-2-chloroethane, 98%(107-04-0)
  • 溶于醇和醚,微溶于水。
  • 灭火剂:水
  • 用途一:用作农药、医药中间体
  • 1-溴-2-氯乙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0572 1-溴-2-氯乙烷 1-Bromo-2-chloroethane 500G 1710元 2014/06/02 B0572 1-溴-2-氯乙烷 1-Bromo-2-chloroethane 25G 206元 2010/06/21 214181000 1-溴-2-氯乙烷 1-Bromo-2-chloroethane 98% 100 ML 852元
  • 可燃性危险特性:遇热分解卤化物有毒蒸气
  • MOL 文件:107-04-0.mol
  • 用途二:用于有机合成,溶剂,薰蒸剂。
  • 类别:有毒物品
  • 海关编码:29034980
  • 急性毒性:口服- 大鼠 LD50: 64 毫克/ 公斤
  • 外观性质:无色挥发性液体,有类似氯仿的甜味。
  • 方法一:由氯乙醇与三溴化磷反应而得。向反应瓶中先加入氯乙醇,用水冷却,于搅拌下逐渐滴加入三溴化磷,控制温度为20-30℃,在常温下搅拌半小时,加热回流1h,冷却,用5%氢氧化钠洗涤,分去水层,再洗至中性,水洗,再用无水碳酸钠脱水,将所得粗品进行分馏,收集106-108℃馏分即为成品。

系列性分类