2-Methoxyethylamine 2-甲氧基乙胺

CAS 109-85-3 MFCD00008180

化学结构图

109-85-3
SMILES: COCCN

化学属性

Mol. FormulaC3H9NO
Mol. Weight75
Refractive index1.4040 to 1.4070
Boiling Point95
Density0.864
Flash Point12°C(lit.)
TSCAYes
Melting Point-82
Stability对空气敏感

别名和识别编码

Chemical Name2-Methoxyethylamine
Synonym Methyl 2-aminoethyl ether 2-Aminoethylmethylether O-METHYLETHANOLAMINE 2-氨乙基甲醚;2-甲烷氧基乙基胺;2-甲烷氧基乙基胺;2-氨基乙基甲醚 2-Methoxyaminoethan 2-甲烷氧基乙基胺 Ethanamine, 2-methoxy- Ethylamine, N-methoxy- 2-甲氧基乙胺 β-Methoxyethylamine 2-Methoxyethylamine, 99+% Methoxyethylamine 2-methoxyethylamine (2-Aminoethyl)-methylether 1-Amino-2-methoxyethane 2-Methoxyethanamine 2-METHOXYETHYLAMINE 2-AMINOETHYL METHYL ETHER 2-methoxy-ethylamine CH3OCH2CH2NH2 1-Methoxy-2-aminoethane 2-Methoxy-1-ethanamine 2-methoxy-ethylamin Ethylamine, 2-methoxy- 2-Aminoethyl methyl ether 2-METH
CAS Number109-85-3
PubChem Substance ID8018
EC Number203-712-1
Beilstein Registry Number741854
MDL NumberMFCD00008180
Reaxys-RN741854
Chemical Name Translation2-甲氧基乙胺
Wiswesser Line NotationZ2O1
LabNetwork Molecule IDLN00186848
InChIInChI=1S/C3H9NO/c1-5-3-2-4/h2-4H2,1H3
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分类

  • {uni_hamburg} no charge; ether; 1fragment
  • {SNA} Amino Alcohols, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
  • Amino Alcohols, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • Beil. 4 ,IV,1411
  • Aldrich MSDS 1 , 1183:D / Corp MSDS 1 (2), 2250:D / FT-IR 2 (1), 514:A / FT-IR 1 (1), 327:C / FT-NMR 1 (1), 524:C / IR-Spectra (3), 192:A / IR-Spectra (2), 173:A / NMR-Reference 2 (1), 283:D / RegBook 1 (1), 355:A / Sax 6 , 1775 / Structure Index 1 , 49:A:2 / Vapor Phase 3 , 414:C
  • Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
  • Short: II/19b Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19b Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54578-6 ISBN: 978-3-540-54578-1 Internet Resource: DOI:10.1007/b44334 RefComment: XI, 488 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new obj

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes
RTECSKR8750000
Precautionary statements
  • P303+P361+P353+P310+P363
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P301+P330+P331
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P304+P340
Signal word
UN Number UN 2733 3/PG 2 UN2733
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Packing GroupII
Hazard Class3/8
Storage condition Flammables area 充氩保存
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - dyspnea
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0546426

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD691-490

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - muscle weakness
   Behavioral - ataxia
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0546426

其他信息

  • Kinetics of reaction of 2-methoxyethylamine with guanosine 5′-phospho-2-methylimidazolide (2-MeImpG) was studied.
  • 图谱信息:2-甲氧基乙胺(109-85-3)核磁图( 1 HNMR) 2-甲氧基乙胺(109-85-3)红外图谱(IR1) 2-甲氧基乙胺(109-85-3)核磁图( 13 CNMR) 2-甲氧基乙胺(109-85-3)质谱(MS)
  • 下游产品:双(2-甲氧乙基)胺
  • Sigma Aldrich:109-85-3(sigmaaldrich)
  • Alfa Aesar:2-甲烷氧基乙基胺,98% 2-Methoxyethylamine, 98%(109-85-3)
  • 2-甲氧基乙胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0611 2-甲氧基乙胺 2-Methoxyethylamine 25ML 148元 2010/06/21 162580010 2-甲氧基乙胺 2-Methoxyethylamine 99% 1 LT 1065元 2010/06/21 162580025 2-甲氧基乙胺 2-Methoxyethylamine 99% 2.5 LT 2272元
  • MOL 文件:109-85-3.mol
  • Acros Organics:2-甲氧基乙胺 2-Methoxyethylamine, 99+%(109-85-3)
  • TCI Shanghai:2-氨乙基甲醚 2-Methoxyethylamine,>;99.0%(GC)(109-85-3)

系列性分类


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