N,N,N',N'-Tetramethyl-1,3-propanediamine N,N,N′,N′-四甲基-1,3-丙二胺

CAS 110-95-2 MFCD00008337

化学结构图

110-95-2
SMILES: CN(C)CCCN(C)C

化学属性

Mol. FormulaC7H18N2
Mol. Weight130.24
Refractive index1.4220 to 1.4240
Boiling Point145-146°C at 760 mmHg
Density0.78
Flash Point32°C
TSCAYes
Vapor Pressure760 mmHg ( 145 °C)
Stability对湿度敏感
Melting Point28.9 °C

别名和识别编码

Chemical NameN,N,N',N'-Tetramethyl-1,3-propanediamine
Synonym N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {LY} N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {} {LY} N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {} {} {LY} N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {} {} {} {LY} N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {} {} {} {} {LY} N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {} {} {} {} {} {LY} N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {} {} {} {} {} {} {LY} N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {} {} {} {} {} {} {} {} {} {LY} N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {} {} {} {} {} {} {} {} {} {} {LY} N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N1,N3,N3-Tetramethylpropane-1,3-diamine {} {} {} {} {} {} {} {} {} {}
CAS Number110-95-2
PubChem Substance ID8084
EC Number203-818-8
MDL NumberMFCD00008337
Reaxys-RN1734176
Beilstein Registry Number4,262
Chemical Name TranslationN,N,N′,N′-四甲基-1,3-丙二胺
Wiswesser Line Notation1N1&3N1&1
LabNetwork Molecule IDLN00223464
InChIInChI=1S/C7H18N2/c1-8(2)6-5-7-9(3)4/h5-7H2,1-4H3
Canonical SMILESCN(C)CCCN(C)C
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • Bioactive Small Molecules, Building Blocks, Cell Biology, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines, T
  • {SA} Bioactive Small Molecules, Building Blocks, Cell Biology, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines, T
  • {SNA} Bioactive Small Molecules, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines,

产品应用

  • 环氧树脂固化剂,生产聚氨酯泡沫塑料催化剂。

相关文献及参考

  • Beilstein:4,262

安全信息

GHS Symbol
WGK Germany2
Hazard Codes T
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H310 Fatal in contact with skin 皮肤接触致命
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H330 Fatal if inhaled 吸入致命
  • H331 Toxic if inhaled 吸入中毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTX8400000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P312
  • P301+P317
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P350
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
UN Number UN 2734 8/PG 2 2734
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R22 Harmful if swallowed 吞咽有害
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Packing GroupII
Hazard Class8/3
Storage condition 2-8°C {LY} 2-8°C Flammables area {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : >316 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EESADV Ecotoxicology and Environmental Safety.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1977-  Volume(issue)/page/year:
   6,149,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 410 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 300 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 375 ppm/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   WADTAA Wright Air Development Center, Technical Report, U.S. Air Force.
   (Wright-Patterson Air Force Base, OH 45433)  Volume(issue)/page/year:
   55-250,10,1955

其他信息

  • MOL 文件:110-95-2.mol
  • Acros Organics:N,N,N',N'-四甲基-1,3-丙二胺 N,N,N',N'-Tetramethyl-1,3-propanediamine, 99+%(110-95-2)
  • 能溶于水、醇混溶。
  • 蒸气压:760 mm Hg ( 145 °C)
  • Sigma Aldrich:110-95-2(sigmaaldrich)
  • MSDS 信息:N,N,N',N'-Tetramethyl-1,3-propanediamine(110-95-2).msds
  • 图谱信息:四甲基丙二胺(110-95-2)核磁图( 1 HNMR) 四甲基丙二胺(110-95-2)红外图谱(IR1) 四甲基丙二胺(110-95-2)Raman光谱 四甲基丙二胺(110-95-2)核磁图( 13 CNMR) 四甲基丙二胺(110-95-2)质谱(MS)
  • TCI Shanghai:N,N,N,N'-四甲基-1,3-丙二胺 N,N,N',N'-Tetramethyl-1,3-diaminopropane,>;98.0%(GC)(T)(110-95-2)
  • Hazard Note:Irritant
  • 外观性质:无色至浅黄色透明液体,能溶于水、醇混溶。沸点:145-146℃折射率n20/D:1.4234密度:0.779 闪点:32℃
  • F:10-34
  • 四甲基丙二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0548 N,N,N,N'-四甲基-1,3-丙二胺 N,N,N',N'-Tetramethyl-1,3-diaminopropane 25ML 137元 2014/06/02 T0548 N,N,N,N'-四甲基-1,3-丙二胺 N,N,N',N'-Tetramethyl-1,3-diaminopropane 500ML 817元 2010/06/21 155510500 四甲基丙二胺 N,N,N',N'-Tetramethyl-1,3-propanediamine 99+% 50 GR 243元
  • 用途一:环氧树脂固化剂,生产聚氨酯泡沫塑料催化剂。
  • Alfa Aesar:N,N,N',N'-四甲基-1,3-丙二胺,99% N,N,N',N'-Tetramethyl-1,3-propanediamine, 99%(110-95-2)

系列性分类


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