Methyl 10-Undecenoate 10-十一烯酸甲酯
CAS 111-81-9 MFCD00016689
化学结构图
SMILES: C=CCCCCCCCCC(=O)OC
化学属性
| Mol. Formula | C12H22O2 |
|---|---|
| Mol. Weight | 198 |
| Density | 0.888 |
| Boiling Point | 248 |
| Refractive index | 1.4380 to 1.4400 |
| Flash Point | 122°C(lit.) |
| Appearance | 10-烯酸甲酯(111-81-9)为无色液体，有酯类香味。熔点-27.5℃，沸点248℃，相对密度0.889，折光率1.4393。溶于乙醇、乙醚、乙酸，不溶于水。 |
别名和识别编码
| Chemical Name | Methyl 10-Undecenoate |
|---|---|
| CAS Number | 111-81-9 |
| Alfabeta Name | METHYLUNDECENOATE 10-- |
| MDL Number | MFCD00016689 |
| Synonym | 10-Hendecenoic acid methyl ester 10-UNDECANOIC ACID METHYL ESTER 10-UNDECENOIC ACID METHYL ESTER 10-UNDECENOIC ACID:METHYL ESTER 10-Undecenoic acid methyl ester 10-Undecenoic acid, methyl ester 10-十一烯酸甲基酯 十一碳烯酸甲酯 HENDECENOIC ACID METHYL ESTER Maskod MNS 01-10 Methyl 10-undecenate Methyl 10-undecenoate Methyl 10-undecylenate Methyl ester of 10-Undecenoic acid Methyl undecenate Methyl undecenoate Methyl-10-undecenoat Undecylenic acid methyl ester Undecylenic acid, methyl ester methylundec-10 methylundec-10-enoate undec-10-enoic acid methyl ester undec-10-enoicacidmethylester {} {} {Chemical {} {} {uni_hamburg} ω-十一烯酸甲酯; ω-十一烯酸甲酯;十一碳烯酸甲酯 |
| PubChem Substance ID | 87577766 |
| EC Number | 203-910-8 |
| Reaxys-RN | 1765394 |
| Beilstein Registry Number | 1765394 |
| Chemical Name Translation | 10-十一烯酸甲酯 |
| LabNetwork Molecule ID | LN00168972 |
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分类
- {uni_hamburg} no charge; ester; 1fragment
- {SNA} Alphabetical Listings, Flavors and Fragrances, M-N
- {SNA} Building Blocks, C12 to C63, Carbonyl Compounds, Chemical Synthesis, Esters, Fatty Acids and conjugates, Fatty Acyls, Methyl Esters, Organic Building Blocks, Unsaturated Fatty Acids and Derivatives, 生化试剂, 脂类
- {SNA} Biochemicals and Reagents, Building Blocks, C12 to C63, Carbonyl Compounds, Chemical Synthesis, Esters, Fatty Acids and conjugates, Fatty Acyls, Lipids, Methyl Esters, Organic Building Blocks,
- {SNA} Biochemicals and Reagents,
产品应用
- Methyl 10-undecenoate, unsaturated fatty acid ester, is used to modify commercial silicone monomer, 1,3,5,7-tetramethylcyclotetrasiloxane for the preparation of silicone hollow nano/microstructures in water.
相关文献及参考
- Merck: 14,9848
- Merck: 14,9848 Beilstein:2(4)1613
- Short: EINECS
- Short: III/38B
- Short: IV/16
- Short: IV/20B
安全信息
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
GHS Symbol
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H302+H332
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
其他信息
- 上游原料:10-十一烯酸 --> 蓖麻油酸
- TCI Shanghai:10-十一烯酸甲酯 Methyl 10-Undecenoate,>;98.0%(GC)(111-81-9)
- 用途二:十一烯酸的中间体。香料的中间体。
- Sigma Aldrich:111-81-9(sigmaaldrich)
- 10-烯酸甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 U0036 10-十一烯酸甲酯 Methyl 10-Undecenoate 500ML 1500元 2014/06/02 U0036 10-十一烯酸甲酯 Methyl 10-Undecenoate 25ML 278元
- MOL 文件:111-81-9.mol
- 用途三:十一稀酸的中间体，香料的中间体。
- 用途一:用作香料中间体及医药中间体
- 有酯类香味。溶于乙醇，乙醚，乙酸，不溶于水。
- FEMA:4253
- 下游产品:10-十一烯酸 --> 庚醛 --> -十一醛
- 图谱信息:10-烯酸甲酯(111-81-9)红外图谱(IR2) 10-烯酸甲酯(111-81-9)红外图谱(IR1) 10-烯酸甲酯(111-81-9)质谱(MS) 10-烯酸甲酯(111-81-9)Raman光谱
- Methyl 10-undecenoate is the chain stopper in the polymerization of long-chain aliphatic α,ω-diene through acyclic diene metathesis (ADMET). This helps in tuning the molecular weight of the resulting polyester in a range varying from 10 to 45 kDa.
- 方法一:可从甘油三蓖麻醇酸酯中制取，亦可用十一烯酸在硫酸催化下以甲醇酯化制得。
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