Trichlorooctadecylsilane 三氯十八烷基硅烷

CAS 112-04-9 MFCD00000484

化学结构图

112-04-9
SMILES: CCCCCCCCCCCCCCCCCC[Si](Cl)(Cl)Cl

化学属性

Mol. FormulaC18H37Cl3Si
Mol. Weight388
Refractive index1.4570 to 1.4620
Boiling Point223
Density0.984
Flash Point191°C(lit.)
TSCAYes
Melting Pointca 20°
Vapor Density>;1 (vs air)
Vapor Pressure<;5 mmHg ( 20 °C)
Solubility溶于醚、苯、过氯乙烯、庚烷。

别名和识别编码

Chemical NameTrichlorooctadecylsilane
Synonym Octadecyltrichlorosilane Trichloro(octadecyl)silane
CAS Number112-04-9
PubChem Substance ID87574091
EC Number203-930-7
Beilstein Registry Number1778847
MDL NumberMFCD00000484
Reaxys-RN1778847
Alfabeta NameOCTADECYLTRICHLOROSILANE N-
Chemical Name Translation三氯十八烷基硅烷
LabNetwork Molecule IDLN00184897
InChIInChI=1S/C18H37Cl3Si/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-22(19,20)21/h2-18H2,1H3
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分类

  • {SNA} Materials for Surface Modification, Micro/NanoElectronics, Nanomaterials, Organic and Printed Electronics, POSS Precursors and Intermediates, RSiCl3, Self Assembly & Contact Printing, Self-Assembly Materials, Silanes, Silsesquioxanes: POSS Nanohybrids, Substrates and Electrode Materials, 材料科
  • Materials Science, Materials for Surface Modification, Micro/NanoElectronics, Nanomaterials, Organic and Printed Electronics, POSS Precursors and Intermediates, RSiCl3, Self Assembly & Contact Printing, Self-Assembly Materials, Silanes, Silsesquioxanes: POSS Nanohybrids, Substrates and Electrode Materials

相关文献及参考

  • Beil. 4 ,IV,4256
  • Aldrich MSDS 1 , 1399:C / Corp MSDS 1 (2), 2637:A / FT-IR 2 (3), 4361:A / FT-IR 1 (2), 1107:A / FT-NMR 1 (3), 651:C / IR-Spectra (3), 1541:D / IR-Spectra (2), 1318:C / NMR-Reference 2 (2), 997:A / RegBook 1 (2), 2965:A / Sax 6 , 2080 / Sigma FT-IR 1 (2), 981:A / Structure Index 1 , 469:D:2 / Vapor Phase 3 , 1638:A
  • Short: IV/16 Title: Surface tension of pure liquids and binary mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/16 Year: 1997 Keyword: organic compounds; surface tension; liquids; mixtures ISBN: 3-540-63276-X ISBN: 978-3-540-63276-4 Internet Resource: DOI:10.1007/b60566 RefComment: VII, 439 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S8 Keep container dry 保持容器干燥；
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 1800
RTECSVV4680000
Storage condition Moisture Sensitive
Packing GroupII
Warnings IRRITANT 危化品目录(2015) 危险化学品
Hazard Class8

其他信息

  • 灭火剂:干粉、二氧化碳
  • 可燃性危险特性:易燃; 遇水放出有毒氯化氢气体; 火中放出有毒气体
  • MSDS 信息:十八烷基三氯硅烷(112-04-9).msds
  • 蒸气压:<;5 mm Hg ( 20 °C)
  • Acros Organics:十八烷基三氯硅烷 Octadecyltrichlorosilane, 95%(112-04-9)
  • 图谱信息:十八烷基三氯硅烷(112-04-9)质谱(MS) 十八烷基三氯硅烷(112-04-9)红外图谱(IR1) 十八烷基三氯硅烷(112-04-9)核磁图( 1 HNMR)
  • 类别:腐蚀物品
  • 蒸气密度:>;1 (vs air)
  • 外观性质:无色液体，有刺激气味。
  • 储运特性:库房通风低温干燥; 与碱、氧化剂、酸分开存放
  • 十八烷基三氯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 O0079 十八烷基三氯硅烷 Trichlorooctadecylsilane 25G 274元 2014/06/02 O0079 十八烷基三氯硅烷 Trichlorooctadecylsilane 500G 2440元 2010/06/21 147400250 十八烷基三氯硅烷 Octadecyltrichlorosilane 95% 25 ML 311元
  • 用途一:制造硅酮的中间体。用来合成有机硅中间体及高分子聚合物。
  • MOL 文件:112-04-9.mol
  • 上游原料:镁 --> 甲基叔丁基醚 --> 四氯化硅 --> 硬脂基溴
  • Alfa Aesar:正十八烷基三氯硅烷,95%,cont.5-10%branchedisomers n-Octadecyltrichlorosilane, 95%, cont. 5-10% branched isomers(112-04-9)
  • F:10-21
  • TCI Shanghai:十八烷基三氯硅烷 Trichlorooctadecylsilane,>;85.0%(GC)(112-04-9)
  • 敏感性:Moisture Sensitive
  • Sigma Aldrich:112-04-9(sigmaaldrich)
  • TSCA:Yes

系列性分类

  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Self Assembly &amp; Contact Printing - Micro/NanoElectronics
  4. Self-Assembly Materials - Self Assembly &amp; Contact Printing
  5. Silanes - Self-Assembly Materials
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Silicon-Based - Protecting and Derivatizing Reagents
  1. Materials Science 材料科学
  2. Nanomaterials - Materials Science
  3. Silsesquioxanes: POSS&reg; Nanohybrids - Nanomaterials
  4. POSS&reg; Precursors and Intermediates - Silsesquioxanes: POSS&reg; Nanohybrids
  5. RSiCl3 - POSS&reg; Precursors and Intermediates
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Materials Science 材料科学
  2. Silane Coupling Agents 硅烷偶联剂

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