N-Methylpyridin-4-amine 4-甲氨基吡啶

CAS 1121-58-0 MFCD00152625

化学结构图

1121-58-0
SMILES: CNc1ccncc1

化学属性

Mol. FormulaC6H8N2
Mol. Weight108
Density1.422
Boiling Point100 °C/0.1 mmHg(lit.)
Melting Point125.0 to 129.0 deg-C
TSCANo

别名和识别编码

Chemical NameN-Methylpyridin-4-amine
Synonym N-Methyl-N-(4-pyridinyl)amine 4-(Methylamino) pyridine 4-(Methylamino)pyridine N-METHYL-4-PYRIDINAMINE 4-Methylaminopyridine Methyl-pyridin-4-yl-amine 4-(METHYLAMINO)PYRIDINE 4-Methylaminopyridine ,99% 4-Methylamino pyridine N-Methyl-4-aminopyridine JandaJel™-4-甲基氨基吡啶 JANDA-JEL(TM)-4-METHYLAMINOPYRIDINE 4-甲基氨基吡啶 N-Methyl-4-pyridinamine 4-氨甲基吡啶 4-Pyridinamine, N-methyl- Pyridine, 4-(methylamino)- 4-甲氨基吡啶 4-(N-Methylamino)pyridine
MDL NumberMFCD00152625
CAS Number1121-58-0
EC Number250-023-7
Beilstein Registry Number108213
PubChem Substance ID135726918
Reaxys-RN108213
Chemical Name Translation4-甲氨基吡啶
InChIKeyLSCYTCMNCWMCQE-UHFFFAOYSA-N
LabNetwork Molecule IDLN00176905
InChIInChI=1S/C6H8N2/c1-7-6-2-4-8-5-3-6/h2-5H,1H3,(H,7,8)
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分类

  • {SNA} JandaJel, Chemical Synthesis, Solid Supported Synthesis, Specialty Synthesis
  • {SNA} Building Blocks, C6, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines
  • {SA} Building Blocks, C6, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines
  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: III/35D3 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 3: Heterocycles Author: Gupta, R.R.; Jain, M.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D3 Year: 2007 Keyword: C-13; NMR; carbon-13; chemical shifts; coupling constants; heterocycles; nuclear magnetic resonance ISBN: 978-3-540-29731-4 ISBN: 3-540-29731-6 Internet Resource: DOI: 10.1007/978-3-540-47067-0 RefComment: VIII, 342 p., 1 illus., Hardcover RefComment: Written for Science and engineers in the fields of physics, chemistry and physical chemistry who inted to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, orient by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. NMR is now a leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei B-11 and P-31, subvolume III/35B contains the nuclei F-19 and N-15, subvolume III/35C contains the nucleus H-1, subvolume III/35D contains the nucleus C-13, subvolume III/35E contains the nucleus O-17, and subvolume III/35G contains the nucleus Se-77. More nuclei are planned for future volumes.
  • Short: IV/20C Title: Vapor Pressure and Antoine Coefficients for Nitrogen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20C Year: 2001 Keyword: organic compounds; vapor pressure I

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Hazard Codes Xi
Packing GroupIII
Hazard Class6.1
UN Number 2811

其他信息

  • F:34
  • 4-甲氨基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L19626 4－甲基氨基吡啶, 99% 4-(Methylamino)pyridine, 99% 5g 1065元 2010/05/25 L19626 4－甲基氨基吡啶, 99% 4-(Methylamino)pyridine, 99% 25g 3822元 2010/05/25 L19626 4－甲基氨基吡啶, 99% 4-(Methylamino)pyridine, 99% 1g 319元
  • Alfa Aesar:4－甲基氨基吡啶,99% 4-(Methylamino)pyridine, 99%(1121-58-0)
  • MOL 文件:1121-58-0.mol
  • 上游原料:碳酸钾 --> 三氯甲烷 --> 一甲胺 --> 4-溴吡啶盐酸盐
  • Sigma Aldrich:1121-58-0(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Specialty Synthesis 特殊合成技术
  3. Solid Supported Synthesis - Specialty Synthesis
  4. JandaJel™ - Solid Supported Synthesis
  1. C6 - Pyridines
  1. C6 to C7 - Pyridines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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