(+)-Diisopinocampheyl Chloroborane (+)-二异松蒎基氯硼烷
CAS 112246-73-8 MFCD00074808
化学结构图
SMILES: C[C@@H]1[C@@H](B(Cl)[C@H]2C[C@@H]3C[C@H]([C@@H]2C)C3(C)C)C[C@@H]2C[C@H]1C2(C)C
化学属性
| Mol. Formula | C20H34BCl |
|---|---|
| Mol. Weight | 320.75 |
| Density | 0.90 |
| Flash Point | 110°C |
| Melting Point | 53-55°C |
| Boiling Point | 369.6±25.0 °C at 760 mmHg |
别名和识别编码
| Chemical Name | (+)-Diisopinocampheyl Chloroborane |
|---|---|
| MDL Number | MFCD01317328 |
| CAS Number | 112246-73-8 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 2384789 |
| Reaxys-RN | 13205713 |
| PubChem Substance ID | 13515837 |
| Chemical Name Translation | (+)-二异松蒎基氯硼烷 |
| Synonym | (+)-B-Chlorodiisopinocampheylborane {LY} (+)-B-Chlorodiisopinocampheylborane {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {} {} |
| InChI | InChI=1S/C20H34BCl/c1-11-15-7-13(19(15,3)4)9-17(11)21(22)18-10-14-8-16(12(18)2)20(14,5)6/h11-18H,7-10H2,1-6H3/t11-,12-,13-,14-,15+,16+,17-,18-/m0/s1 |
| LabNetwork Molecule ID | LN01745777 |
| Canonical SMILES | CC1(C)[C@@]2([H])C[C@H](B(Cl)[C@@H]3[C@@H](C)[C@@](C4)([H])C(C)(C)[C@@]4([H])C3)[C@@H](C)[C@]1([H])C2 |
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安全信息
GHS Symbol
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+P353
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P308+P313
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P403+P233
- P305+P351+P338+P310
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
其他信息
- Sigma Aldrich:112246-73-8(sigmaaldrich)
- MOL 文件:112246-73-8.mol
- 和水剧烈反应
- (+)-二异松蒎基氯硼烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1614 (+)-B-二异松蒎基氯硼烷(58%的己烷溶液,约1.6mol/L) (+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca. 1.6mol/L) 100ML 2570元 2010/06/21 388428000 (+)-二异松蒎基氯硼烷 (+)-Diisopinocampheylchloroborane , 1.8M solution in hexanes, AcroSeal® 800 ML 20648元 2010/06/21 388421000 (+)-二异松蒎基氯硼烷 (+)-Diisopinocampheylchloroborane , 1.8M solution in hexanes, AcroSeal® 100 ML 6938元
- 稳定性:(+)-二异松蒎基氯硼烷（112246-73-8）对水较敏感, 极易与空气中或溶剂中的水分反映生成氯化氢。受到空气中氧气氧化作用使其对酮的还原性降低。
- TCI Shanghai:(+)-二异松蒎基氯硼烷(58%的正己烷溶液,约1.6mol/L) (+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca. 1.6mol/L)(112246-73-8)
- 用途一:(+)-二异松蒎基氯硼烷(112246-73-8) are used for high enantiselective asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.
- F:10-21
- 外观:无色透明液体
- Acros Organics:(+)-二异松蒎基氯硼烷 (+)-Diisopinocampheylchloroborane, 1.8M solution in hexanes, AcroSeal?(112246-73-8)
- Alfa Aesar:(+)-DIP chloride, 97%(112246-73-8)
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