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分类

• {uni_hamburg} no charge; 1fragment
• {SNA} Chemical Synthesis, Specialty Gases, Synthetic Reagents

相关文献及参考

• Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
• Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
• Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Lando

安全信息

GHS Symbol

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 750 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de
   Securite Sociale.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.7-    1946-
   Volume(issue)/page/year: 27,509,1966

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 11200 mg/m3/4H
TOXIC EFFECTS :
   Behavioral - muscle contraction or spasticity
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 15(2),38,1971

其他信息

• 外观性质:无色无臭气体。
• 储运特性:库房通风低温干燥; 轻装轻卸; 与易燃物分开存放
• 上游原料:四氟乙烯
• 毒性分级:中毒
• 下游产品:聚全氟乙烯-丙烯树脂 --> 七氟丙烷
• 类别:有害气体
• Sigma Aldrich:116-15-4(sigmaaldrich)
• 用途二:该品是合成含氟高分子材料（如氟橡胶F20-41、F246和氟塑料F46等）的单体之一。还可用于全氟磺酸离子交换膜（用于食盐电解）、氟碳油和全氟环氧丙烷等的原料。
• Hazard Note:Irritant
• 用途一:可制备多种含氟精细化工产品、药物中间体、灭火剂等，还可制得含氟高分子材料
• 可燃性危险特性:常温不燃; 高热产生有毒氟化物气体
• 爆炸物危险特性:高热可爆
• F:4.5
• 方法一:由四氟乙烯热裂解而得。将四氟乙烯通入高温裂解炉在700℃裂化，裂化气经除酸、干燥、压缩后进行粗馏，馏出物冷冻、脱气，最后精馏得到成品。
• MOL 文件:116-15-4.mol
• MSDS 信息:六氟丙烯(116-15-4).msds
• 急性毒性:吸入-大鼠 LC50:11200毫克/立方米/4小时;吸入-小鼠 LC50:750 PPM/4小时