N-[(2R)-2-Pyrrolidinylmethyl]Trifluoromethanesulfonamide N-[(2R)-2-吡咯烷甲基]三氟甲磺酰胺

CAS 1186049-30-8 MFCD11656044

化学结构图

1186049-30-8
SMILES:

化学属性

Mol. FormulaC6H11F3N2O2S
Mol. Weight232.22

别名和识别编码

Chemical NameN-[(2R)-2-Pyrrolidinylmethyl]Trifluoromethanesulfonamide
Synonym 1,1,1-三氟-N-[(2R)-2-吡咯烷甲基]-甲磺酰胺 N-[(2R)-2-吡咯烷甲基]-三氟甲磺酰胺
MDL NumberMFCD11656044
Beilstein Registry Number10255865
CAS Number1186049-30-8
Chemical Name TranslationN-[(2R)-2-吡咯烷甲基]三氟甲磺酰胺
PubChem Substance ID329761202
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Heterocyclic Building Blocks, Proline-Based Organocatalysts, Pyrrolidines
  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Heterocyclic Building Blocks, Proline-Based Organocatalysts, Pyrrolidines

相关文献及参考

  • Zu, L.-S.; et al. , Highly Enantioselective Aldol Reactions Catalyzed by a Recyclable Fluorous ( S ) Pyrrolidine Sulfonamide on Water Org. Lett. 10 , 1211-1214, (2008) 摘要
  • Zu, L.-S.; et al. , A Recyclable Fluorous ( S )-Pyrrolidine Sulfonamide Promoted Direct, Highly Enantioselective Michael Addition of Ketones and Aldehydes to Nitroolefins in Water Org. Lett. 8 , 3077-3079, (2006) 摘要
  • Wang, W.; et al. , Direct, Highly Enantioselective Pyrrolidine Sulfonamide Catalyzed Michael Addition Reactions of Aldehydes to Nitrostyrenes Angew. Chem. Int. Ed. Engl. 44 , 1369-1371, (2005) 摘要

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Hazard Codes C
Risk Statements
  • R34 Causes burns 会导致灼伤

系列性分类


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