Bis(cyclopentadienyl)hafnium dichloride 二氯二茂铪

CAS 12116-66-4 MFCD00001438

化学结构图

12116-66-4
SMILES: Cl[Hf]Cl.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 |^1:3,4,5,6,7,8,9,10,11,12|

化学属性

Mol. FormulaC10H10Cl2Hf
Mol. Weight379.58
Melting Point230-233 °C(lit.)
TSCAYes
Appearance off-white xtl.
Stabilitymoisture sensitive

别名和识别编码

Chemical NameBis(cyclopentadienyl)hafnium dichloride
Synonym Dichlordicyclopentadienylhafnium bis(η-cyclopentadienyl)hafnium chloride Bis(cyclopentadienyl)hafnium dichloride Hafnocendichlorid Dichlorobis(eta-cyclopentadienyl)hafnium Dicyclopentadienylhafnium dichloride Dichlorodi-pi-cyclopentadienylhafnium bis(η-cyclopentadienyl)-hafnium chloride Hafnium, dichlorobis(eta(5)-2,4-cyclopentadien-1-yl)- Dichlorodicyclopentadienylhafnium Hafnium, dichlorobis(η(5)-2,4-cyclopentadien-1-yl)- 二(环戊二烯基)二氯化铪(IV) 二(环戊二烯基)二氯化铪(IV) 二氯二茂铪 双(环戊二烯)二氯化铪(IV) 二(环戊二烯基)二氯化铪 双(环戊二烯)二氯化铪 dichlorobis(η5-cyclopenta-2,4-dien-1-yl)hafnium 二氯二茂铪 Hafnocene dichloride Hafnium dicyclopentadiene dichloride Hafnium, dichlorobis(η5-2,4-cyclopentadien-1-yl)-
MDL NumberMFCD00001438
EC Number235-177-5
CAS Number12116-66-4
PubChem Substance ID87571272
Chemical Name Translation二氯二茂铪
Wiswesser Line NotationL50J 0-HF-GG- 0L50J
InChIKeyUHCOEQZUSAFLHQ-UHFFFAOYSA-L
LabNetwork Molecule IDLN01745958
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分类

  • {uni_hamburg} no charge; metal-organic; other heterocycle; carbocycle; alicycle; fused rings; 3ring; 4ring; 5ring; 6ring; 1fragment; zwitterion
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Hafnium Catalysts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Hafnium

相关文献及参考

  • Short: IV/20A Title: Vapor Pressure and Antoine Coefficients for Hydrocarbons and Sulfur-, Selenium-, Tellurium-, and Halogen-Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20A Year: 1999 Keyword: organic compounds; vapor pressure ISBN: 3-540-64735-X ISBN: 978-3-540-64735-5 Internet Resource: DOI:10.1007/b71086 RefComment: VIII, 373 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
  • P308+P311
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
WGK Germany3
Signal word Warning
RTECSMG4815000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Packing GroupIII
UN Number UN3261
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R34 Causes burns 会导致灼伤
Storage condition Air & Moisture Sensitive
Hazard Codes Xn Xi 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04787

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Hafnium 铪
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Reagents for Polymerization - Polymer Science
  4. Catalysts for Polymerization - 烯烃聚合催化
  5. Olefin Polymerization - Catalysts for Polymerization
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metallocenes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Metallocenes, Derivatives & Cp Precursors
  2. Hafnium

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