(3R)-1-N-Cbz-3-Aminopyrrolidine (R)-1-苄氧羰基-3-氨基吡咯烷

CAS 122536-73-6 MFCD05864624

化学结构图

122536-73-6
SMILES: N[C@@H]1CCN(C1)C(=O)OCC1C=CC=CC=1

化学属性

Mol. FormulaC12H16N2O2
Mol. Weight220.27
Density1.155 g/mL at 25 °C
Boiling Point315 °C
Refractive indexn20/D 1.548
Flash Point>110°(230°F)
TSCANo
Melting Point310-316°

别名和识别编码

Chemical Name(3R)-1-N-Cbz-3-Aminopyrrolidine
Synonym (R)-1-苄氧羰基-3-氨基吡咯烷 (R)-(-)-1-Cbz-3-aminopyrrolidine (R)-(-)-1-Cbz-3-氨基吡咯烷
MDL NumberMFCD05864624
PubChem Substance ID24884456
CAS Number122536-73-6
Chemical Name Translation(R)-1-苄氧羰基-3-氨基吡咯烷
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Pyrrolidines

安全信息

WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word Warning
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Storage condition Air Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Heterocyclic Building Blocks - Chiral Building Blocks
  5. Pyrrolidines - Heterocyclic Building Blocks

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