(-)-Isoborneol 异冰片

CAS 124-76-5 MFCD00074821

化学结构图

124-76-5
SMILES: CC1(C)[C@@H]2CC[C@@]1(C)[C@H](O)C2

化学属性

Mol. FormulaC10H18O
Mol. Weight154
Melting Point212-214 °C (subl.)(lit.)
Flash Point74°(165°F)
TSCAYes
Solubility不溶
Appearance 白色晶体。有近似樟脑的气味。 溶于乙醇、乙醚、氯仿、石油醚而不浑浊。
Boiling Point214°C

别名和识别编码

Chemical Name(-)-Isoborneol
CAS Number124-76-5
Beilstein Registry Number6(2)80
Reaxys-RN6474286
PubChem Substance ID6321405
MDL NumberMFCD00074821
Merck Number5128
Synonym (+/-)-ISOBORNEOL 1,7,7-Trimethyl-bicyclo[2.2.1]heptan-2-ol (isoborneol) 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol 1,7,7-trimethyl-exo-Bicyclo[2.2.1]heptan-2-ol 1,7,7-三甲基双环[2.2.1]庚-2-醇 2-exo-Borneol 2-exo-Bornylalcohol 3-莰醇 7,7-trimethyl-exo-bicyclo(2.2.1)heptan-2-o 7,7-trimethyl-exo-bicyclo[2.2.1]heptan-2-o BORNEOL(ISO) Bicyclo(2.2.1)heptan-2-ol, 1,7,7-trimethyl-, exo- Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, exo- Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-,(1R,2R,4R)-rel- Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-,1R,2R,4R-rel- Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-,exo- DL-ISOBORNEOL DL-ISOBORNYL ALCOHOL DL-ISOCAMPHAL DL-Isoborneol DL-异冰片 D
EC Number204-712-4
Chemical Name Translation异冰片
LabNetwork Molecule IDLN00194864
InChIInChI=1S/C10H18O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7-8,11H,4-6H2,1-3H3/t7-,8-,10+/m1/s1
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分类

  • {Chemicalbook} 食品添加剂: 食用香料（增香剂）: 天然等同香料和人造香
  • {SNA} Alphabetical Listings, Certified Food Grade Products, Flavors and Fragrances, H-J, I-L, I-N, Kosher Certified Products
  • {SNA} Alcohols, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Curcuma longa (Turmeric), Nutrition Research, Organic Building Blocks, Phytochemicals by Plant (Food/Spice/Herb), Zingiber officinale (Ginger), 细胞生物学
  • {SNA} Alcohols, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Curcuma longa (Turmeric), Organic Building Blocks, Phytochemicals by Plant (Food/Spice/Herb),

安全信息

RTECSNP7300000
Signal word Danger {} {} {} {} {} {TCI}
Hazard statements
  • H228 Flammable solid 易燃固体
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P309+P311
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R38 Irritating to skin 刺激皮肤
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
WGK Germany2
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes F,Xi
UN Number UN1325 UN 1312 4.1/PG 3
Packing GroupIII 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03209

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 17,531,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 17,531,1979

其他信息

  • 毒性:GRAS(FEMA，FDA，§1.72．515，2000)。
  • Alfa Aesar:异冰片醇,96% ()-Isoborneol, 96%(124-76-5)
  • 参考质量标准:FCC，1996 醇中溶解度 1g溶于lmL 95%乙醇 熔点 212～214℃
  • MOL 文件:124-76-5.mol
  • Sigma Aldrich:124-76-5(sigmaaldrich)
  • 食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称 允许使用该种添加剂的食品中文名称 添加剂功能 最大允许使用量（g/kg） 最大允许残留量（g/kg） 异龙脑 食品 食品用香料 用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
  • 下游产品:2-莰酮 --> 乙酸异龙脑酯
  • 用途一:作为香料用于日化产品中，也用作防腐剂
  • 上游原料:氢氧化钠 --> 盐酸 --> 乙酸 --> 二甲苯 --> 松节油 --> 水合二氧化钛
  • 用途二:食用香料。
  • Acros Organics:DL-异冰片醇 DL-Isoborneol, tech., 93%(124-76-5)
  • 方法一:用一蒎烯经氯化氢加成进行分子重排生成莰烯，再水化，重排而成。
  • 图谱信息:异龙脑(124-76-5)核磁图( 13 CNMR) 异龙脑(124-76-5)红外图谱(IR1) 异龙脑(124-76-5)质谱(MS) 异龙脑(124-76-5)红外图谱(IR2)
  • FEMA:2158
  • MSDS 信息:1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol(124-76-5).msds
  • 使用限量:FEMA(mg/kg)：饮料6.2；冰淇淋23；糖果11；焙烤制品8.3；胶姆糖0.80。 适度为限(FDA，§172．515，2000)。
  • 异龙脑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 I0275 (+/-)-异冰片 (+/-)-Isoborneol 500G 824元 2014/06/02 I0275 (+/-)-异冰片 (+/-)-Isoborneol 25G 150元 2010/06/21 122495000 异龙脑 DL-Isoborneol 93%, tech. 500 GR 777元
  • 异龙脑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 I0275 (+/-)-异冰片 (+/-)-Isoborneol 500G 938元 2011/04/16 I0275 (+/-)-异冰片 (+/-)-Isoborneol 25G 146元 2010/06/21 122495000 异龙脑 DL-Isoborneol 93%, tech. 500 GR 777元
  • TCI Shanghai:异冰片 (+/-)-Isoborneol,>;90.0%(GC)(124-76-5)

系列性分类

  1. Application Areas 应用领域分类
  2. Flavors and Fragrances 香精香料
  3. Kosher Certified Products - Flavors and Fragrances
  4. I-N - Kosher Certified Products
  1. Life Science 生命科学
  2. Nutrition Research 营养研究
  3. Phytochemicals by Plant (Food/Spice/Herb) - Nutrition Research
  4. Curcuma longa (Turmeric) - Phytochemicals by Plant (Food/Spice/Herb)
  1. Life Science 生命科学
  2. Nutrition Research 营养研究
  3. Phytochemicals by Plant (Food/Spice/Herb) - Nutrition Research
  4. Zingiber officinale (Ginger) - Phytochemicals by Plant (Food/Spice/Herb)
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Salts - Synthetic Reagents
  4. Potassium - Inorganic Salts
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Alcohols - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Alcohols - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Acid Halides 酰卤
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Terpenes

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