Methacrylonitrile 甲基丙烯腈

CAS 126-98-7 MFCD00001872

化学结构图

126-98-7
SMILES: C=C(C)C#N

化学属性

Mol. FormulaC9H6N2O2
Mol. Weight174.16
Refractive index1.399-1.401
Boiling Point251°C(lit.)
Density0.8
Melting Point-35.8 ºC
Vapor Pressure64 mmHg ( 20 °C)
Flash Point12 ºC
Solubility2.57 G/100 ML (20 ºC)

别名和识别编码

Chemical NameMethacrylonitrile
CAS Number126-98-7
Synonym ######## 1-Methyl-1-cyanoethylene 1-Methylethenyl cyanide 2-Cyano-1-propene 2-Cyanopropene 2-Cyanopropene-1 2-METHYL-2-PROPENENITRILE 2-Methacrylonitrile 2-Methyl-2-propenenitrile 2-Methyl-2-propennitril 2-Methylacrylonitrile 2-Methylpropenecarbonitrile 2-Methylpropenenitrile 2-Propenenitrile, 2-methyl- 2-Propenenitrile,2-methyl- 2-methyl-2-propene nitrile 2-methyl-2-propenenitril 2-methyl-2-propenenitrile 2-methyl-acrylonitrile 2-甲基-2-丙烯腈 2-甲基丙烯腈 ALPHA-METHYLACRYLIC ACID NITRILE ALPHA-METHYLACRYLONITRILE CH2C(CH3)CN I ISOPROPENYL CYANIDE Isobutenenitrile Isopropene cyanide
PubChem Substance ID31368
EC Number204-817-5
Beilstein Registry Number13,138
MDL NumberMFCD00002011
Chemical Name Translation甲基丙烯腈
Merck Number9530
Wiswesser Line NotationNCY1&U1
LabNetwork Molecule IDLN00883770
Reaxys-RN744602
InChIInChI=1S/C4H5N/c1-4(2)3-5/h1H2,2H3
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分类

  • Alpha Sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, M, META - METH, Volatiles/ Semivolatiles
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Acrylic Monomers, Acrylonitrile, Materials Science, Monomers, Polymer Science

产品应用

  • ########

相关文献及参考

  • Ahmed, A., et al.: Toxicol Lett., 12, 157 (1982),
  • El Hadri, L., et al.: Toxicol. Appl. Pharmacol., 205, 116 (2005),
  • Farooqui, M., et al.: J. Biochem. Toxicol., 5, 109 (1990),
  • Merck 14 ,5942
  • Beil. 2 ,IV,1539
  • Aldrich MSDS 1 , 1171:B / Corp MSDS 1 (2), 2226:C / FT-IR 2 (1), 1430:D / FT-IR 1 (1), 843:D / FT-NMR 1 (1), 1359:B / IR-Spectra (3), 504:B / NMR-Reference 2 (1), 701:C / RegBook 1 (1), 991:H / Sax 6 , 1795 / Structure Index 1 , 154:D:8 / Vapor Phase 3 , 803:A
  • Short: II/24B Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24B Year: 2000 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-65345-7 ISBN: 978-3-540-65345-5 Internet Resource: DOI:10.1007/b58835 RefComment: VIII, 525 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24B contains an introduction and tables of rotational and centrifugal distortion constants of asymmetric-top molecules, i.e. data which roughly specifies the frequencies o

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H301 Toxic if swallowed 吞食有毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H330 Fatal if inhaled 吸入致命
  • H331 Toxic if inhaled 吸入中毒
  • H370 Causes damage to organs 导致器官损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F;T F,T
RTECSCZ6300000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P316
  • P302+P352
  • P302+P352+P333+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P307+P311
  • P308+P311
  • P308+P313
  • P308+P316
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P316
  • P318
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P333+P313
  • P333+P317
  • P337+P313
  • P337+P317
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
Signal word Danger
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S18 Handle and open container with care 小心搬运和开启容器；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S29 Do not empty into drains 不要排入下水道；
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R11 Highly flammable 非常易燃
UN Number 3079 2078 UN 3079 3/PG 1
Packing GroupII
Hazard Class6.1
Storage condition 2-8°C 0-10°C
Restrict {} 剧毒化学品 危险品
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 120 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 29(5),37,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2080 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 36 ppm/4H
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   29,202,1968

TYPE OF TEST

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 88 ppm/4H
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   29,202,1968

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 350 mg/kg
SEX/DURATION            : female 1-7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - other effects
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 48,696,1992

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 100 ppm/6H
SEX/DURATION            : female 6-20 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   20,365,1993

其他信息

  • 下游产品:2-甲基丙烯酸
  • 爆炸物危险特性:与空气混合, 受热、明火可爆
  • 蒸气压:64 mm Hg ( 20 °C)
  • 用途一:重要有机合成原料，经水解、酯化可得甲基丙烯酸甲酯，它本身也能聚合成高分子材料。
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氮氧化物和氰化物烟雾
  • 毒性分级:剧毒
  • Acros Organics:甲基丙烯腈（禁运） Methacrylonitrile, stabilized, 99%(126-98-7)
  • 类别:易燃液体
  • 职业标准:TWA 3 毫克/ 立方米; STEL 9 毫克/立方米
  • 刺激数据:眼睛- 兔子 500 毫克/ 24小时 轻度; 皮肤- 兔子 200 毫克 轻度
  • MSDS 信息:2-甲基丙烯腈(126-98-7).msds
  • Sigma Aldrich:126-98-7(sigmaaldrich)
  • 方法一:由混合碳四烃氨氧化制得。原料碳四烃主要含正丁烯-1为44.2%，异丁烯为31.6%，丁烯-2为12.5%，基余为少量其他碳四烃。原料碳四烃、氨和以水饱和的湿空气按配比（1：1.4：13-14）在预热器中混合，并预热到180-200℃，从反应器底部进入反应器，以0.5m/s的线速度使催化剂呈流化状态，在440-460℃进行催化反应，催化剂为磷-钽-铋-锑，异丁烯转化率为77.15%，甲基丙烯腈单程转化率为51.7%。由于碳四烃饱分中含有正丁烯，经氧化为丁二烯，收率为44.9%以上，1-丁烯转化率达76.31%，因此，采用此可得两种产品。
  • MOL 文件:126-98-7.mol
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • 图谱信息:甲基丙烯腈(126-98-7)红外图谱(IR2) 甲基丙烯腈(126-98-7)红外图谱(IR1) 甲基丙烯腈(126-98-7)质谱(MS) 甲基丙烯腈(126-98-7)核磁图( 1 HNMR) 甲基丙烯腈(126-98-7)核磁图( 13 CNMR)
  • 上游原料:1,3-丁二烯 --> 压凝汽油 --> 正丁烯 --> 铋 --> 钽
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放; 不宜久储, 防聚合
  • 甲基丙烯腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 187435000 甲基丙烯腈 Methacrylonitrile 99%, stabilized 500 ML 1011元 2010/06/21 187431000 甲基丙烯腈 Methacrylonitrile 99%, stabilized 100 ML 317元 2010/06/21 187430025 甲基丙烯腈 Methacrylonitrile 99%, stabilized 2.5 LT 3521元
  • 急性毒性:口服- 大鼠 LD50: 120 毫克/ 公斤; 口服- 小鼠 LD50: 17 毫克/ 公斤
  • 外观性质:无色液体，有轻微杏仁气味。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Cyanides/Nitriles - Nitrogen Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Volatiles/ Semivolatiles - Environmental Standards
  6. Alpha Sort - Volatiles/ Semivolatiles
  7. M - Alpha Sort
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Acrylic Monomers 丙烯酸单体
  5. Acrylic Acids and Salts

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