N-Methoxy-N-Methyl(Triphenylphosphoranylidene)Acetamide N-甲氧基-N-甲基(三苯基正膦亚基)乙酰胺

CAS 129986-67-0 MFCD00134433

化学结构图

129986-67-0
SMILES: CON(C)C(=O)C=P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC22H22NO2P
Mol. Weight363
Melting Point173-175 °C(lit.)

别名和识别编码

Chemical NameN-Methoxy-N-Methyl(Triphenylphosphoranylidene)Acetamide
Synonym N-甲氧基-N-甲基(三苯基正膦亚基)乙酰胺 (N-甲氧基甲基氨基羰基亚甲基)三苯基正膦
Beilstein Registry Number4198472
PubChem Substance ID24863472
CAS Number129986-67-0
MDL NumberMFCD00134433
Chemical Name TranslationN-甲氧基-N-甲基(三苯基正膦亚基)乙酰胺
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. Fang, F.; et al. Eur. J. Org. Chem. , 1084, (2011)
  • 2. Sinisi, R.; et al. Proc. Natl. Acad. Sci. U. S. A. 107 , 20652, (2010)
  • 3. Aroyan, C. E.; et al. J. Org. Chem. 75 , 5784, (2010)
  • 4. Farwick, A.; Helmchen, G. Adv. Synth. Catal. 352 , 1023, (2010)
  • 5. Calo, F.; et al. Org. Lett. 11 , 4910, (2009)
  • FT-NMR 1 (2), 1681:A / RegBook 1 (2), 2281:K / Structure Index 1 , 357:C:5

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Others - Olefination

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