THALLIUM(III) OXIDE 三氧化二铊(III),

CAS 1314-32-5 MFCD00011276

化学结构图

1314-32-5
SMILES: O=[Tl]O[Tl]=O

化学属性

Mol. FormulaTl2O3
Mol. Weight456.76
Melting Point717 °C (lit.)
Density9.65
TSCAYes
Boiling Point875°
SolubilityInsoluble in water and alkalies. Decomposes in HCl and H2SO4
Flash Point875°C

别名和识别编码

Chemical Name96% Thallium(III) oxide, 96%
MDL NumberMFCD00011276
PubChem Substance ID24852848
CAS Number1314-32-5
EC Number215-229-3
Synonym thallium(iii) rcrawastenumberp113 thalliumoxide(tl2o3) Thallium(111) oxide THALLIUM(+3)OXIDE Dithallium Trioxide thallium(111)oxide THALLIUM (IC) OXIDE Thallium trioxide Thallium(III) oxide, 98+% 氧化铊 Thallium (III) oxide (99.5%-Tl) THALLIUM OXIDE Thallium sesquioxide Thallium (III) oxide (99.999%-Tl) PURATREM Dithallium trioxide Thallium(Ⅲ)oxide 三氧化二铊 氧化铊(III) 三氧化二铊, 99.9% (METALS BASIS) THALLIUM OXIDE (IC) Tl2O3 Thalliumoxideblackpowder Thalliumsesquioxide 三氧化二铊, 99.99% (METALS BASIS) THALLIUM(III) OXIDE,
Merck Number14,9268
Chemical Name Translation三氧化二铊(III),
Wiswesser Line Notation.TL2.O3
LabNetwork Molecule IDLN01303344
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分类

  • {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Oxides, Thallium
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Oxides, Thallium
  • {SNA} Catalysis and Inorganic Chemistry,

相关文献及参考

  • Aldrich MSDS 1 , 1693:D / Corp MSDS 1 (2), 3317:B / RegBook 1 (3), 3275:D / Sax 6 , 2555
  • Fieser 1 ,1150 / Fieser 2 ,406 / Fieser 4 ,492
  • Merck 14 ,9268
  • Short: III/21e Title: Superconductors: Transition Temperatures and Characterization of Elements, Alloys and Compounds: Tl ... Zr Author: Flükinger, R.; Hulliger, F.; Luo, H.L.; Wolf, T.; Xu, J.Q. Editor: Flükiger, R.; Klose, W. Source: Landolt-Börnstein, New Series Volume: III/21e Year: 2002 Keyword: Landolt-Börnstein; Quantum Fluids; Superconductivity; Superfluidity ISBN: 3-540-56049-1 ISBN: 978-3-540-56049-4 Internet Resource: DOI:10.1007/b47748 RefComment: XXXI, 443 pages, with CD-ROM, Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: In volume III/21 a compilation is given of all reported experimental data on superconducting materials from the discovery of this phenomenon. The presented data include not only the superconducting properties related to a given material, but also the full metallurgical and crystallographical characterization. In addition to other low temperature physical properties, which are explicitly given in a particular column are presented. The substances are arranged alphabetically by the base element, i.e. that element with the highest concentration in an alloy or compound. Only original and critically reviewed experimental data are retained.
  • Short: III/7b1 Title: Crystal Structure Data of Inorganic Compounds: Key Element : O Author: Pies, W.; Weiss, A. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/7b1 Page: 1-674 Year: 1975 ISBN: 3-540-06919-4 ISBN: 978-3-540-06919-5 Internet Resource: DOI:10.1007/b19973 RefComment: 23 figs., XXIII, Hardcover Abstract: Volume III/7 contains structure data on those compounds which contain at least one of the elements F, Cl, Br, I, O, N, and P and cannot b

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Hazard statements
  • H330 Fatal if inhaled 吸入致命
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H300 Fatal if swallowed 吞食致命
Hazard Codes T+,N
RTECSXG2975000
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
UN Number UN 1707 6.1/PG 2 UN1707
Risk Statements
  • R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
  • R33 Danger of cumulative effects 有累积作用的危险
  • R51/53
Packing GroupII
Hazard Class6.1
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : M

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 34 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   21,399,1960

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 67 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   21,399,1960

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 40 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CUTOEX Current Toxicology.  (Nova Science Publishers, Inc., 6080 Jericho
   Turnpike, Suite 207, Commack, NY  11725)  V.1    1993-
   Volume(issue)/page/year: 1,39,1993

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 44 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:

其他信息

  • 毒性分级:剧毒
  • MSDS 信息:氧化铊(1314-32-5).msds
  • Sigma Aldrich:1314-32-5(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 与酸类, 食品分开储运
  • 职业标准:TLV-TWA 0.1 毫克 (铊)/立方米
  • 氧化铊[三氧化(二)铊]价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80127680 三氧化二铊（剧毒） 5g 950元
  • 可燃性危险特性:不燃； 火场产生含铊烟雾
  • 外观性质:棕色至黑色六面晶系结晶或无定形粉末。
  • 灭火剂:二氧化碳, 砂土
  • MOL 文件:1314-32-5.mol
  • 用途一:用作铊标准试剂的配制和高纯分析试剂等
  • Alfa Aesar:三氧化二铊,99.99%(metalsbasis) Thallium(III) oxide, 99.99% (metals basis)(1314-32-5)
  • 类别:有毒物品
  • 急性毒性:口服-大鼠 LD50: 44 毫克/公斤

系列性分类

  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Oxides 金属氧化物
  4. Thallium (Tl) Oxide

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