Dibenzofuran 二苯并呋喃

CAS 132-64-9 MFCD00004968

化学结构图

132-64-9
SMILES: c1ccc2c(c1)oc1ccccc12

化学属性

Mol. FormulaC12H8O
Mol. Weight168.20
Density1.08
Boiling Point154-155°C at 760 mmHg
Melting Point80-82°C
Flash Point130°C
TSCAYes
Solubility<0.1 G/100 ML AT 20 ºC
Appearance 浅黄色结晶

别名和识别编码

Chemical NameDibenzofuran
Synonym Dibenzo[b,d]furan {LY} Dibenzo[b,d]furan {} {LY} Dibenzo[b,d]furan {} {} {LY} Dibenzo[b,d]furan {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {} {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {} {} {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {} {} {} {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzo[b,d]furan {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00004968
CAS Number132-64-9
EC Number205-071-3
Beilstein Registry Number121100
PubChem Substance ID87566876
Chemical Name Translation二苯并呋喃
Reaxys-RN121100
LabNetwork Molecule IDLN00189809
InChIInChI=1S/C12H8O/c1-3-7-11-9(5-1)10-6-2-4-8-12(10)13-11/h1-8H
Canonical SMILESC12=CC=CC=C1C3=CC=CC=C3O2
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分类

  • {SNA} Benzofurans,
  • {SA} All PAH Standards, Alphabetic, Analytical Standards, Analytical/Chromatography, CRMs, Chromatography, D, DIA - DIC, Environmental Standards, PAHs, Volatiles/ Semivolatiles, neat
  • {SNA} Alpha Sort,
  • {SNA} Additional Standards,

产品应用

  • 用于医药，消毒剂，防腐剂，染料；合成树脂及高温润滑剂等的原料。

相关文献及参考

  • Short: II/3
  • Short: III/35E
  • {
  • Merck: 14,10494
  • Lithiation with n-BuLi occurs at the 4-position (ortho to the O atom). The 4-lithio derivative has been silylated and a second metallation effected at the 6- (second ortho) position, using n-BuLi and TMEDA, as a route to 4,6-disubstituted derivatives: J. Org. Chem., 62, 2259 (1997).
  • Merck: 14,10494 Beilstein:17,70
  • Short: II/5
  • Short: III/10a

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S29 Do not empty into drains 不要排入下水道；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R51/53
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSHP4430000
Packing GroupIII
UN Number 3077 UN3077
Hazard Codes 9
Hazard Class9
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} 
TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 10 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

其他信息

  • MOL 文件:132-64-9.mol
  • Alfa Aesar:二苯并呋喃,98% Dibenzofuran, 98%(132-64-9)
  • 二苯并呋喃价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0147 二苯并呋喃 Dibenzofuran 500G 2800元 2014/06/02 D0147 二苯并呋喃 Dibenzofuran 25G 300元 2010/06/21 159300250 二苯并呋喃 Dibenzofuran 98% 25 GR 851元
  • Acros Organics:二苯并呋喃 Dibenzofuran, 99+%(132-64-9)
  • 用途一:用于生产治疗牛羊肝吸虫药物，制消毒剂、防腐剂、染料、合成树脂及高温润滑剂等
  • MSDS 信息:Diphenylene oxide(132-64-9).msds
  • 海关编码:29329995
  • 用途三:用于医药，消毒剂，防腐剂，染料；合成树脂及高温润滑剂等的原料。
  • 二苯并呋喃价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D0147 二苯并呋喃 Dibenzofuran 500G 3680元 2011/04/16 D0147 二苯并呋喃 Dibenzofuran 25G 400元 2010/06/21 159300250 二苯并呋喃 Dibenzofuran 98% 25 GR 851元
  • TCI Shanghai:二苯并呋喃 Dibenzofuran,>;98.0%(GC)(132-64-9)
  • 图谱信息:二苯并呋喃(132-64-9)质谱(MS) 二苯并呋喃(132-64-9)核磁图( 13 CNMR) 二苯并呋喃(132-64-9)核磁图( 1 HNMR) 二苯并呋喃(132-64-9)红外图谱(IR2) 二苯并呋喃(132-64-9)红外图谱(IR1)
  • Sigma Aldrich:132-64-9(sigmaaldrich)
  • 检测方法:GC,NMR
  • 水溶性<0.1 g/100 mL （20℃）。不溶于水，微溶于苯、醚和醇
  • 用途二:用于医药，消毒剂，防腐剂，染料；合成树脂及高温润滑剂等的原料
  • 下游产品:邻苯基苯酚 --> 联硝氯酚

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Benzofurans 苯并呋喃
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Volatiles/ Semivolatiles - Environmental Standards
  6. PAHs - Volatiles/ Semivolatiles
  7. All PAH Standards - PAHs
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Heterocyclics - Chemical Class
  5. Oxygen containing - Heterocyclics
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DIA - DIC - D

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