1-Chloropinacolone 一氯频哪酮

CAS 13547-70-1 MFCD00035688

化学结构图

13547-70-1
SMILES: CC(C)(C)C(=O)CCl

化学属性

Mol. Formula(CH3)3CCOCH2Cl
Mol. Weight135
Refractive index1.4400 to 1.4430
Boiling Point173°C
Density1.025
Melting Point-13
Flash Point67°C(lit.)
TSCAYes
Appearance 白色或淡黄色透明液体,密度 1.03,熔点 -1°C,沸点 170-173°C,折射率 1.441-1.443,闪点 67°C

别名和识别编码

Chemical Name1-Chloropinacolone
Synonym 1-CHLORO-3,3-DIMETHYL-BUTANONE 1-氯-3,3-二甲基-2-丁酮 1-CHLORO-3,3-DIMETHYLBUTAN-2-ONE 1-氯频哪酮 1-CHLORO-3,3-DIMETHYL- 2-BUTANONE: CHLOROPINACOLONE 1-monochloropinacoline Chlorpinakolin 1-CHLORO-3,3-DIMETHYL-2-BUTANONE MONOCHLOROPINAKOLONE 1-Chloro-3,3-dimethylbutan-2-one 1-chloro-3,3-dimethyl-2-butanon alpha-Chloropinacolone
PubChem Substance ID87566347
EC Number236-920-6
MDL NumberMFCD00035688
CAS Number13547-70-1
Chemical Name Translation一氯频哪酮
Reaxys-RN1744162
Beilstein Registry Number1(4)3313
LabNetwork Molecule IDLN00201518
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分类

  • {SNA} Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks

相关文献及参考

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H330 Fatal if inhaled 吸入致命
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSEL7078000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340+P312
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P332+P313
  • P302+P352+P332+P313+P362+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P370+P378
  • P305+P351+P338+P337+P313
  • P301+P312+P330
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P403+P235
Signal word
Packing GroupIII
UN Number UN 2810
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R23 Toxic by inhalation 吸入有毒
  • R22 Harmful if swallowed 吞咽有害
  • R26 Very toxic by inhalation 吸入极毒
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时,佩带适当的呼吸器;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Hazard Codes T+ T,T+
Hazard Class6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 355 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 52(12),91,1987

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4600 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 52(12),91,1987

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 550 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 52(12),91,1987

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 675 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 52(12),91,1987

其他信息

  • MSDS 信息:1-Chloropinacolone(13547-70-1).msds
  • MOL 文件:13547-70-1.mol
  • 用途一:用作医药、农药等的中间体
  • Sigma Aldrich:13547-70-1(sigmaaldrich)
  • 图谱信息:一氯频呐酮(13547-70-1)核磁图( 13 CNMR) 一氯频呐酮(13547-70-1)核磁图( 1 HNMR) 一氯频呐酮(13547-70-1)红外图谱(IR1) 一氯频呐酮(13547-70-1)质谱(MS)
  • Alfa Aesar:1-氯哪酮,97% 1-Chloropinacolone, 95%(13547-70-1)
  • 下游产品:三唑酮 --> 烯唑醇
  • 上游原料:甲醇
  • TCI Shanghai:1-氯频哪酮 1-Chloropinacolin,>;96.0%(GC)(13547-70-1)
  • 一氯频呐酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 C1335 1-氯频哪酮 1-Chloropinacolin 500ML 3900元 2011/04/16 C1335 1-氯频哪酮 1-Chloropinacolin 25ML 468元 2010/05/25 A16576 1-氯哪酮, 97% 1-Chloropinacolone, 95% 25g 308元

系列性分类


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