Tert-Butyl Propiolate 叔丁基丙炔酸酯

CAS 13831-03-3 MFCD00060100

化学结构图

13831-03-3
SMILES: C#CC(=O)OC(C)(C)C

化学属性

Mol. FormulaC7H10O2
Mol. Weight126.16
Refractive index1.4180 to 1.4200
Boiling Point53°C/27mmHg(lit.)
Density0.919 g/mL at 25 °C(lit.)
Melting Point18-20 °C(lit.)
Flash Point28°C(lit.)
TSCANo

别名和识别编码

Chemical NameTert-Butyl Propiolate
Synonym tert-Butyl acetylenecarboxylate; Propiolic acid tert-butyl ester Propiolic acid tert-butyl ester 丙炔酸叔丁酯 叔丁基丙炔酸酯
CAS Number13831-03-3
PubChem Substance ID87575150
Beilstein Registry Number1747175
MDL NumberMFCD00060100
Reaxys-RN1747175
Chemical Name Translation叔丁基丙炔酸酯
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分类

  • {SNA} Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

相关文献及参考

  • 1. Tetrahedron 48 , 669, (1992)
  • 2. Tetrahedron Lett. 30 , 3625, (1989)
  • 3. J. Am. Chem. Soc. 112 , 7682, (1990)
  • 4. Tetrahedron Lett. 29 , 6183, (1988)
  • Beil. 2 ,IV,1680
  • FT-IR 2 (3), 4040:B / Structure Index 1 , 427:E:1

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning {} {} {} {} {} {} {TCI}
Storage condition 0-10 0-10°C Air Sensitive
UN Number 3272 UN3272
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
Packing GroupIII
Hazard Class3

系列性分类