Tris(2-Chloroethyl) Phosphite 亚磷酸三(2-氯乙基)酯

CAS 140-08-9 MFCD00000968

化学结构图

140-08-9
SMILES: ClCCOP(OCCCl)OCCCl

化学属性

Mol. FormulaC6H12Cl3O3P
Mol. Weight269.48
Density1.328 g/mL at 25 °C(lit.)
Boiling Point98°C/1mmHg(lit.)
Refractive index1.4860 to 1.4910
Flash Point89°C(lit.)
Appearance 50 D 1.4870，相对密度 1.3280，f.p.1 90℃。 本品为无色油状液体，b.p.112～115℃/266 pa，n

别名和识别编码

Chemical NameTris(2-Chloroethyl) Phosphite
MDL NumberMFCD00000968
CAS Number140-08-9
Synonym AURORA KA-1232 tris(2-chloroethyl)esterofphosphorusacid Ethanol,2-chloro-,phosphite(3:1) 亚磷酸三(2-氯乙基)酯 Phosphorigsäuretris-(2-chlorethylester) 2-chloroethanolphosphite(3:1) 2-chloro-ethanophosphite(3:1) tris-(2-chloro-ethyl) phosphite TRI-2-CHLOROETHYL PHOSPHITE Tri(2-chloroethyl) phosphite CLP-1 PHOSPHOROUS ACID TRIS(2-CHLOROETHYL) ESTER TRIS(2-CHLOROETHYL) PHOSPHITE 三(2-氯乙基)亚磷酸酯 CLP 1 Ethanol, 2-chloro-, phosphite (3:1) 2三-(氯乙基)亚磷酸酯 Tris(2-chloroethyl) phosphite Phosphorigsäure-2-chlorethanylester 2-氯乙醇亚磷酸盐(3:1) 2-CHLOROETHANOL PHOSPHITE tris(chloroethyl)phosphite 2-氯乙醇亚磷酸盐 Phosphorous acid tris(2-chloroethyl) Phosphorous acid, tris(2-chloroethyl) ester tris(beta-chloroethyl)phosphite Tris(β-chloroethyl) phosphite Tris(2-chloroethoxy)phosphine Tris(chloroethyl) phosphite
Reaxys-RN1704979
PubChem Substance ID8783
EC Number205-397-6
Chemical Name Translation亚磷酸三(2-氯乙基)酯
LabNetwork Molecule IDLN01307841
InChIInChI=1S/C6H12Cl3O3P/c7-1-4-10-13(11-5-2-8)12-6-3-9/h1-6H2
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分类

  • {Chemicalbook} 农药中间体: 植物生长调节剂中间体
  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds

相关文献及参考

  • Aldrich MSDS 1 , 1814:A / Corp MSDS 1 (2), 3528:A / FT-IR 1 (1), 911:A / FT-IR 2 (1), 1547:A / IR-Spectra (2), 486:E / IR-Spectra (3), 548:F / NMR-Reference 2 (2), 863:B / RegBook 1 (1), 1093:G / Sax 6 , 2220 / Structure Index 1 , 169:D:1
  • Short: III/38A Title: Refractive Indices of Inorganic, Organometallic, and Organononmetallic Liquids and Binary Liquid Mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38A Year: 1996 Keyword: organicmetallic compounds; inorganic compounds; refractive index; liquids; mixtures ISBN: 3-540-60539-8 ISBN: 978-3-540-60539-3 Internet Resource: DOI:10.1007/b55612 RefComment: VII, 400 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSKK2810000
UN Number 2810 UN 2810 6.1/PG 3
Signal word Danger {} {} {} {} {} {} {TCI}
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H330 Fatal if inhaled 吸入致命
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H350 May cause cancer 可能致癌
  • H340 May cause genetic defects 可能导致遗传性缺陷
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H301+H311
  • H227 Combustible liquid 可燃液体
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P332+P313
  • P302+P350
  • P337+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P403+P235
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P305+P351+P338+P337+P313
WGK Germany3
GHS Symbol
Hazard Codes T
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R46 May cause inheritable genetic damage 可能引起遗传基因损害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R25 Toxic if swallowed 吞咽有毒
  • R21 Harmful in contact with skin 与皮肤接触有害
Packing GroupIII
Hazard Class6.1

其他信息

  • 图谱信息:2-氯乙醇亚磷酸盐(3:1) (140-08-9)红外图谱(IR1) 2-氯乙醇亚磷酸盐(3:1) (140-08-9)质谱(MS) 2-氯乙醇亚磷酸盐(3:1) (140-08-9)核磁图( 1 HNMR) 2-氯乙醇亚磷酸盐(3:1) (140-08-9)核磁图( 13 CNMR)
  • 用途一:三-(氯乙基)亚磷酸酯是植物生长调节剂乙烯利的中间体。
  • TCI Shanghai:亚磷酸三(2-氯乙基)酯 Tris(2-chloroethyl) Phosphite,>;90.0%(GC)(140-08-9)
  • 方法一:其制备方法是在搪瓷釜中投入一定量的三氯化磷，在冰盐冷却下，将环氧乙烷气体通入三氯化磷中，反应温度控制在(30±5)℃，待通入量达到三氯化磷质量时停止通气，继续搅拌4h，出料得产品。
  • MOL 文件:140-08-9.mol
  • 上游原料:曙光红(四溴荧光素)
  • 下游产品:双(2-氯乙基)-(2-氯乙基)膦酸酯
  • Sigma Aldrich:140-08-9(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Organic Phosphates/Phosphites - Phosphorus Compounds

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