(2R)-3,3’-Diphenyl[2,2’-Binaphthalene]-1,1’-Diol (2R)-3,3’-二苯基[2,2’-联萘]-1,1’-二醇

CAS 147702-13-4 MFCD08459338

化学结构图

147702-13-4
SMILES:

化学属性

Mol. FormulaC32H22O2
Mol. Weight439
Melting Point200-204 °C

别名和识别编码

Chemical Name(2R)-3,3’-Diphenyl[2,2’-Binaphthalene]-1,1’-Diol
Synonym (2R)-(+)-3,3′-二苯基-[2,2′-联二萘]-1,1′-二醇 (2R)-(+)-3,3′-二苯基-[2,2′-联二萘]-1,1′-二醇 (R)-3,3′-二苯基-2,2′-二-1-萘酚 (2S)-(-)-3,3′-二苯基-[2,2′-联二萘]-1,1′-二醇 (2S)-(-)-3,3′-二苯基-[2,2′-联二萘]-1,1′-二醇 (S)-3,3′-二苯基-2,2′-二-(1-萘酚) (R)-3,3′-二苯基-2,2′-二-1-萘酚 (S)-3,3′-二苯基-2,2′-二-(1-萘酚) (S)-VANOL
MDL NumberMFCD08459338
PubChem Substance ID24885264
CAS Number147702-13-4
Chemical Name Translation(2R)-3,3’-二苯基[2,2’-联萘]-1,1’-二醇
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分类

  • Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

相关文献及参考

  • 1. Bao. J. et al. J. Am. Chem. Soc. 118 , 3392, (1996)
  • 2. Zhang, Y. et al. Org. Lett. 5 , 1813, (2003) 摘要
  • 3. Yu. S. et al. Org. Lett. 7 , 367, (2005) 摘要

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Hazard statements
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
Risk Statements
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINOLs - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Chiral Ligands

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