Methyldiphenylphosphine 二苯基甲基膦

CAS 1486-28-8 MFCD00008508

化学结构图

1486-28-8
SMILES: CP(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC13H13P
Mol. Weight200.22
Density1.076
Boiling Point186°C/50mmHg(lit.)
Refractive index1.6230 to 1.6260
Flash Point>110°(230°F)
TSCANo
Stability对空气敏感
Appearance colorless liq.
Melting Point117-118 °C

别名和识别编码

Chemical NameMethyldiphenylphosphine
CAS Number1486-28-8
EC Number216-065-5
Beilstein Registry Number16(2)371
MDL NumberMFCD00008508
Synonym Methyldiphenylphosphine {LY} Methyldiphenylphosphine {} {LY} Methyldiphenylphosphine {} {} {LY} Methyldiphenylphosphine {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY}
PubChem Substance ID73879
Reaxys-RN743075
Chemical Name Translation二苯基甲基膦
InChIKeyUJNZOIKQAUQOCN-UHFFFAOYSA-N
LabNetwork Molecule IDLN00201887
InChIInChI=1S/C13H13P/c1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3
Canonical SMILESCP(C1=CC=CC=C1)C2=CC=CC=C2
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands

相关文献及参考

  • Beilstein:16(2)371

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S17 Keep away from combustible material 远离可燃物料；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from lig
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Hazard Codes Xn
Restrict 危险品

其他信息

  • 图谱信息:二苯基甲氧基膦(1486-28-8)红外图谱(IR1) 二苯基甲氧基膦(1486-28-8)核磁图( 13 CNMR) 二苯基甲氧基膦(1486-28-8)核磁图( 1 HNMR) 二苯基甲氧基膦(1486-28-8)质谱(MS)
  • TCI Shanghai:二苯基甲基膦 Methyldiphenylphosphine,>;97.0%(GC)(1486-28-8)
  • 敏感性:Air Sensitive
  • Sigma Aldrich:1486-28-8(sigmaaldrich)
  • Acros Organics:二苯基甲基膦 Methyldiphenylphosphine, 99%(1486-28-8)
  • F:1-10
  • 二苯基甲氧基膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1318 二苯基甲基膦 Methyldiphenylphosphine 5G 714元 2014/06/02 M1318 二苯基甲基膦 Methyldiphenylphosphine 1G 240元 2010/06/21 408970050 二苯基甲氧基膦 Methyldiphenylphosphine 99% 5 GR 681元
  • Alfa Aesar:甲基联苯膦,99% Methyldiphenylphosphine, 99%(1486-28-8)
  • MOL 文件:1486-28-8.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Others - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Elemental Phosphorus
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  3. Phosphines

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