Trifluoromethanesulfonic acid 三氟甲磺酸

CAS 1493-13-6 MFCD00007514

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H99696
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 5g ¥ 42
库存 辽宁
中国国内现货 96-99 %
INFI H99696
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 25g ¥ 78
库存 辽宁
中国国内现货 96-99 %
INFI H99696
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 100g ¥ 159
库存 辽宁 安庆市
中国国内现货 96-99 %
INFI H72186
Trifluoromethanesulfonic acid 三氟甲磺酸
0.1 M Solution In Acetonitrile 1mL ¥ 120
库存 辽宁
中国国内现货 0.1 M solution 乙腈
INFI H72186
Trifluoromethanesulfonic acid 三氟甲磺酸
0.1 M Solution In Acetonitrile 5mL ¥ 520
库存 辽宁
中国国内现货 0.1 M solution 乙腈
INFI H72186
Trifluoromethanesulfonic acid 三氟甲磺酸
0.1 M Solution In Acetonitrile 25mL ¥ 1,480
库存 辽宁
中国国内现货 0.1 M solution 乙腈
Innochem A49725
Trifluoromethanesulfonic acid
99% 5g ¥ 60
库存 北京
中国国内现货 96-99 %
Innochem A49725
Trifluoromethanesulfonic acid
99% 25g ¥ 195
库存 北京
中国国内现货 96-99 %
Innochem A49725
Trifluoromethanesulfonic acid
99% 100g ¥ 502
库存 北京
中国国内现货 96-99 %
Innochem A49725
Trifluoromethanesulfonic acid
99% 500g ¥ 980
库存 北京
中国国内现货 96-99 %
Bellen Bellen10003416
Trifluoromethanesulfonic acid 三氟甲磺酸
5g ¥ 60
Bellen Bellen10003416
Trifluoromethanesulfonic acid 三氟甲磺酸
25g ¥ 100
Bellen Bellen10003416
Trifluoromethanesulfonic acid 三氟甲磺酸
100g ¥ 240
TCI T0751
Trifluoromethanesulfonic Acid >
>98.0%(T) 10g ¥ 180
库存 上海市 天津市 Tokyo, Japan
中国国内现货 96-99 %
TCI T0751
Trifluoromethanesulfonic Acid >
>98.0%(T) 25g ¥ 360
库存 上海市 天津市 Tokyo, Japan
中国国内现货 96-99 %
TCI T0751
Trifluoromethanesulfonic Acid >
>98.0%(T) 250g ¥ 1,380
库存 上海市 天津市 Tokyo, Japan
中国国内现货 96-99 %
Alfa 035367
Trifluoromethanesulfonic acid hydrate
99% 5g ¥ 329
96-99 %
Alfa A10173
Trifluoromethanesulfonic acid
98+% 10g ¥ 210
库存 上海市 北京 China, PRC
中国国内现货 96-99 %
Alfa A10173
Trifluoromethanesulfonic acid
98+% 50g ¥ 744
库存 上海市 北京 China, PRC
中国国内现货 96-99 %
Alfa A10173
Trifluoromethanesulfonic acid
98+% 250g ¥ 3,290
库存 上海市 China, PRC
中国国内现货 96-99 %
J&K 242768
Trifluoromethanesulfonic acid, 99%
99% 10g ¥ 171
库存 HB
中国国内现货 96-99 %
J&K 242768
Trifluoromethanesulfonic acid, 99%
99% 50g ¥ 621
96-99 %
J&K 242768
Trifluoromethanesulfonic acid, 99%
99% 250g ¥ 1,311
库存 HB
中国国内现货 96-99 %
J&K 242768
Trifluoromethanesulfonic acid, 99%
99% 500g ¥ 2,099
库存 HB SH
中国国内现货 96-99 %
J&K 197653
Trifluoromethanesulfonic acid, 99.5%
99.5% 10g ¥ 186
库存 HB
中国国内现货 99e1 %
J&K 197653
Trifluoromethanesulfonic acid, 99.5%
99.5% 50g ¥ 628
库存 HB
中国国内现货 99e1 %
J&K 197653
Trifluoromethanesulfonic acid, 99.5%
99.5% 250g ¥ 1,368
库存 HB
中国国内现货 99e1 %
J&K 197653
Trifluoromethanesulfonic acid, 99.5%
99.5% 1kg ¥ 4,319
库存 HB
中国国内现货 99e1 %
Fluka 35317
Trifluoromethanesulfonic acid solution 三氟甲磺酸 溶液
for titration in non-aqueous medium, standard, 0.1 M in acetic acid 1L ¥ 1,456
96-99 %
Fluka 35317
Trifluoromethanesulfonic acid solution 三氟甲磺酸 溶液
for titration in non-aqueous medium, standard, 0.1 M in acetic acid 6x1L ¥ 4,868
96-99 %
Acros 16989
Trifluoromethanesulfonic acid, 99%, extra pure
1mL ¥ 94
库存 上海市 北京 China, PRC
中国国内现货 96-99 %
Acros 16989
Trifluoromethanesulfonic acid, 99%, extra pure
10mL ¥ 295
库存 上海市 北京 China, PRC
中国国内现货 96-99 %
Acros 16989
Trifluoromethanesulfonic acid, 99%, extra pure
50mL ¥ 869
库存 上海市 北京 China, PRC
中国国内现货 96-99 %
Acros 16989
Trifluoromethanesulfonic acid, 99%, extra pure
250mL ¥ 3,720
96-99 %
Apollo PC7410
Trifluoromethanesulfonic acid
250g ¥ 1,100
96-99 %
Apollo PC7410
Trifluoromethanesulfonic acid
500g ¥ 1,804
96-99 %
Apollo PC7410
Trifluoromethanesulfonic acid
1kg ¥ 3,498
96-99 %
Fluka 91738
purum, >=98.0% (T) 1L ¥ -
96-99 %
Energy-chemical W330028
Trifluoromethanesulfonic acid 三氟甲磺酸
99%,TeflonSeal 25g ¥ 55
96-99 %
Energy-chemical W330028
Trifluoromethanesulfonic acid 三氟甲磺酸
99%,TeflonSeal 100g ¥ 199
96-99 %
Energy-chemical W330028
Trifluoromethanesulfonic acid 三氟甲磺酸
99%,TeflonSeal 500g ¥ 750
96-99 %
Energy-chemical W330028
Trifluoromethanesulfonic acid 三氟甲磺酸
99%,TeflonSeal 5kg ¥ 4,500
96-99 %
Energy-chemical W330028
Trifluoromethanesulfonic acid 三氟甲磺酸
99%,TeflonSeal 25kg ¥ 20,000
96-99 %
Acros 169890100
extra pure 10mL ¥ 717
96-99 %
Adamas 25256D
99%+ 500g ¥ 1,819
库存 上海市 China, PRC
中国国内现货 96-99 %
Adamas 25256A
99%+ 5g ¥ 84
库存 上海市 China, PRC
中国国内现货 96-99 %
Adamas 25256B
99%+ 25g ¥ 159
库存 上海市 China, PRC
中国国内现货 96-99 %
Adamas 25256C
99%+ 100g ¥ 396
库存 上海市 China, PRC
中国国内现货 96-99 %
Shao Yuan SY003089
50g ¥ 348
96-99 %
SIAL 158534-100G
98% reagent grade, 98% 100g ¥ 1,718
96-99 %
SIAL 158534-10G
98% reagent grade, 98% 10g ¥ 358
96-99 %
SIAL 158534-50G
98% reagent grade, 98% 50g ¥ 1,116
96-99 %
Aladdin T104298
Trifluoromethanesulfonic acid 三氟甲烷磺酸
98% 5g ¥ 79
库存 上海市
中国国内现货 96-99 %
Aladdin T104298
Trifluoromethanesulfonic acid 三氟甲烷磺酸
98% 10g ¥ 99
库存 上海市
中国国内现货 96-99 %
Aladdin T104298
Trifluoromethanesulfonic acid 三氟甲烷磺酸
98% 25g ¥ 92
库存 上海市
中国国内现货 96-99 %
Aladdin T104298
Trifluoromethanesulfonic acid 三氟甲烷磺酸
98% 100g ¥ 373
库存 上海市
中国国内现货 96-99 %
Aladdin T104298
Trifluoromethanesulfonic acid 三氟甲烷磺酸
98% 500g ¥ 1,990
库存 上海市
中国国内现货 96-99 %
Strem 09-7410
Trifluoromethanesulfonic acid
99+% 10g ¥ 540
库存 HB
中国国内现货 96-99 %
Strem 09-7410
Trifluoromethanesulfonic acid
99+% 50g ¥ 1,830
96-99 %
HY Y51998
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 10g ¥ -
96-99 %
HY Y51998
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 25g ¥ -
96-99 %
HY Y51998
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 50g ¥ -
96-99 %
HY Y51998
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 100g ¥ -
96-99 %
HY Y51998
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 250g ¥ -
96-99 %
HY Y51998
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 500g ¥ -
96-99 %
HY Y51998
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 1kg ¥ -
96-99 %
Energy-chemical W330001
Trifluoromethanesulfonic acid 三氟甲磺酸
500g ¥ 980
库存 上海市 北京市
中国国内现货
Aldrich 158534
10g ¥ 358
Aldrich 158534
50g ¥ 1,116
Aldrich 158534
100g ¥ 1,718
3A A00067
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 5g ¥ 50
96-99 %
3A A00067
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 25g ¥ 120
96-99 %
3A A00067
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 100g ¥ 330
96-99 %
3A A00067
Trifluoromethanesulfonic acid 三氟甲磺酸
99% 500g ¥ 980
96-99 %
Aladdin T104298-500g
98% 500g ¥ 1,990
96-99 %
Aladdin T104298-25g
98% 25g ¥ 92
96-99 %
Aladdin T104298-100g
98% 100g ¥ 373
96-99 %
Aladdin T104298-5g
98% 5g ¥ 79
96-99 %
Acros 169890010
99% 1mL ¥ 622
96-99 %
Acros 169890500
99% 50mL ¥ 1,369
96-99 %
Acros 169892500
99% 250mL ¥ 5,714
96-99 %
Fluka 35317-1L
for titration in non-aqueous medium, standard, 0.1 M in acetic acid 1L ¥ 1,757
0.1 M solution 乙酸
TRC T790560
10g ¥ 2,700
TRC T790560
25g ¥ 3,540
TRC T790560
50g ¥ 4,870
TRC T790560
100g ¥ 6,900
Accela SY003089
98% 10g ¥ 180
96-99 %
Accela SY003089
98% 250g ¥ 1,395
96-99 %
Aldrich 347817-5G
=99%'>>=99% 5g ¥ 515
Aldrich 347817-25G
=99%'>>=99% 25g ¥ 2,168
Aldrich 347817-100G
=99%'>>=99% 100g ¥ 6,885
Aldrich 347817-500G
=99%'>>=99% 500g ¥ 18,634
药明康德 WXCD00900571
95.00% 100g ¥ -
90+ %
Acros 169890011
Trifluoromethanesulfonic acid 三氟甲磺酸
1L ¥ 17,598

分类

  • Acid Solutions, Analytical Reagents, Analytical/Chromatography, By Reference Material, Chemical Synthesis, Non-aqueous Titration Reagents, Organic Acids, Reference Material Potassium hydrogen
  • {SNA} Acid Solutions, Acids, Acids & Bases, By Reference Material, Chemical Synthesis,

产品应用

  • 异构化和烷基化的催化剂。制备2,3-二氢-2-茚酮、四氢萘酮。去除糖蛋白中糖苷。

相关文献及参考

  • Adds to both internal and terminal alkynes to give vinyl triflates: J. Am. Chem. Soc., 91, 4600 (1969); Org. Synth. Coll., 9, 472 (1998). Reaction in the presence of a nitrile provides a route to sterically hindered 2,4,6-trisubstituted pyrimidines: Synthesis, 881 (1990):
  • Short: II/25B
  • One of the strongest available monoprotic acids. For a review of the chemistry of triflic acid and its derivatives, see: Chem. Rev., 77, 69 (1977).
  • Merck:9676 Beilstein:3(4)34
  • Simple triflic esters, readily prepared by reaction with alcohols, are powerful alkylating agents and must be handled with extreme care because of their irritating effect on the lungs. For a review, see: Synthesis, 85 (1982).
  • For use in direct electrophilic amination of arenes, see Trimethyl­silyl­ azide, L00173. Effects direct oxy-functionalization of aromatics in combination with bis(TMS) peroxide: J. Org. Chem., 54, 1204 (1989); or sodium perborate: Synlett, 39 (1991).
  • Merck:9676

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302+H312
  • H226 Flammable liquid and vapour 易燃液体和蒸气
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
Precautionary statements
  • P303+P361+P353+P310+P363
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P405 Store locked up. 上锁保管。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P310
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P305+P351+P338+P310
  • P301+P330+P331+P310
Signal word
UN Number UN3265 UN 3265 8/PG 2 3265
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R35 Causes severe burns 会导致严重灼伤
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R10 Flammable 易燃
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition -20°C Hygroscopic 储存温度2-8℃ ,充氩保存 储存温度2-8℃ 密封阴凉干燥保存。
RTECSPB2771000
Packing GroupI
Hazard Class8

其他信息

  • color:slightly brown
  • 用途一:用于有机合成
  • MOL 文件:1493-13-6.mol
  • 下游产品:三氟甲磺酸酐 --> 2,2-双(4-羧基苯基)六氟丙烷 --> 4-硝基喹啉-N-氧化物 --> 4-溴-7-氮杂吲哚 --> 三氟甲烷磺酸甲酯 --> C10-18 脂酸甘油三酯类 --> 叔丁基二甲硅基三氟甲磺酸酯 --> 三氟甲磺酸二丁硼 --> 2,6-二叔丁基-4-甲基吡啶 --> 三氟甲烷磺酸锌 --> 三氟甲烷磺酸镧 --> 三氟甲烷磺酸酮
  • Acros Organics:三氟甲磺酸 Trifluoromethanesulfonic acid, extra pure, 99%(1493-13-6)
  • F:3-10
  • 三氟甲磺酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 C169890500 三氟甲烷磺酸 50ml 983元 2011/08/23 LA1017301 三氟甲烷磺酸 10g 218元 2011/08/23 L0670601 三氟甲烷磺酸, 10g 218元
  • 湿空气中发烟,易吸湿形成一水合物。强酸性。与水混溶,溶于多数极性有机溶剂,如二甲基亚砜、二甲基砜。有腐蚀性。
  • 用途二:异构化和烷基化的催化剂。制备2,3-二氢-2-茚酮、四氢萘酮。去除糖蛋白中糖苷。
  • TCI Shanghai:三氟甲磺酸 Trifluoromethanesulfonic Acid,>;98.0%(T)(1493-13-6)
  • Hazard Note:Corrosive/Hygroscopic
  • MSDS 信息:Trifluoromethanesulfonic acid(1493-13-6).msds
  • Alfa Aesar:三氟甲烷磺酸,98+% Trifluoromethanesulfonic acid, 98+%(1493-13-6)
  • 蒸气压:8 mm Hg ( 25 °C)
  • Sigma Aldrich:1493-13-6(sigmaaldrich)
  • 图谱信息:三氟甲磺酸(1493-13-6)红外图谱(IR1)
  • 蒸气密度:5.2 (vs air)
  • 存储注意事项:惰性气体保护
  • 制备方法:黄棕色液体。沸点167~170℃。折射率1.331。相对密度1.708。为最强的有机酸,极易溶于水。 以二硫化碳为原料,与五氟化碘反应生成三氟甲基二硫化物。与汞反应得三氟甲硫基汞(CF3S)2Hg,后者经过氧化氢氧化即得三氟甲磺酸。
  • 海关编码:29049020
  • 敏感性:Hygroscopic

化学结构图

CAS 1493-13-6  MFCD00007514
SMILES: O=S(=O)(O)C(F)(F)F

化学属性

Mol. FormulaCHF3O3S
Mol. Weight150.07
Refractive index1.3260 to 1.3310
Density1.69
SolubilitySoluble in water, DMSO, DMF, and acetonitrile.
TSCAYes
Boiling Point162°C(lit.)
Flash PointNone
Melting Point-40
Vapor Density5.2 (vs air)
Vapor Pressure8 mmHg ( 25 °C)
Stability空气及湿度敏感
Appearance 三氟甲磺酸(1493-13-6)为淡棕色液体。熔点 -40 °C ,沸点 162 ;°C ,密度 1.696 ;g/mL ;at 25 ;°C ,折光率 n 20/D 1.327 ,蒸气压 8 mm Hg ( 25 °C) ,蒸气密度 5.2 (vs air)
Mol. FormulaCHF3O3S
Mol. Weight150.07
Density1.696
Appearance colorless to light brown fuming liq.
Stabilityhygroscopic
Boiling Point162°C

别名和识别编码

Chemical NameTrifluoromethanesulfonic acid
CAS Number1493-13-6
PubChem Substance ID62406
Beilstein Registry Number3(4)34
MDL NumberMFCD00007514
Reaxys-RN1812100
Merck Number9676
Synonym perfluoromethanesulfonic acid 三氟甲烷磺酸, 98+% TFMSA FC-24 trifluoromethane-sulfonic acid Triflicacid trifluoro-methanesulfonic acid Triflate Triflic acid;Triflate trifluoromethanesulfonic TRIFLUOROMETHYLSULFONIC ACID Trifluoromethanesulphonic acid/Triflic acid trifluoro-methanesulfonicaci trifluoromethanesulfonic acid 三氟甲烷磺酸 trifluoromethylsulfonic acid TRIFLIC ACID 三氟甲磺酸;全氟甲磺酸;三氟利克酸;三氟甲基磺酸 TRIFLUOROMETHANESULFONIC ACID, REAGENTPLUS, >=99% 三氟甲基磺酸 TRIFLUOROMETHANESULFONIC ACID Fluorad FC 24 trifluormethansulfonsäure Trifluoromethanesulfonnic acid TRIMESYLATE ACID
EC Number216-087-5
Chemical Name Translation三氟甲磺酸
LabNetwork Molecule IDLN00007166
Chemical NameTrifluoromethanesulfonic acid
Chemical Name Translation三氟甲磺酸
InChIInChI=1S/CHF3O3S/c2-1(3,4)8(5,6)7/h(H,5,6,7)
MDL NumberMFCD00007514
CAS Number1493-13-6

系列性分类


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