4-Methacryloyloxy-2,2,6,6-Tetramethylpiperidine 1-Oxyl Free Radical 4-甲基丙烯酰氧-2,2,6,6-四甲基哌啶1-氧自由基
CAS 15051-46-4 MFCD17677357
化学结构图
SMILES: CC(=C)C(O)=O.CC1(C)CCCC(C)(C)N1[O] |^1:16|
化学属性
| Mol. Weight | 240 |
|---|---|
| Melting Point | 86-90 |
| Mol. Formula | C13H22NO3 |
别名和识别编码
| Synonym | 4-氰基苯二硫代碳酸－1－氰基－1－甲基乙基酯 PTMA 单体 TEMPO methacrylate,PTMA monomer |
|---|---|
| MDL Number | MFCD17677357 |
| CAS Number | 15051-46-4 |
| Chemical Name | 4-Methacryloyloxy-2,2,6,6-Tetramethylpiperidine 1-Oxyl Free Radical |
| Chemical Name Translation | 4-甲基丙烯酰氧-2,2,6,6-四甲基哌啶1-氧自由基 |
| Reaxys-RN | 1377946 |
| PubChem Substance ID | 253659576 |
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分类
- {SNA} Acrylic Monomers, Chemical Synthesis, Methacrylate, Monomers, NMP Initiators, Polymer Science, Radical Chemistry, Reagents for Controlled Radical Polymerization, Reagents for Polymerization, Stable Radicals, Synthetic Reagents, TEMPO Derivatives, 材料科学
- {SA} Acrylic Monomers, Chemical Synthesis, Free Radical Initiators, Materials Science, Methacrylate, Monomers, NMP, Polymer Science, Polymerization Initiators, Radical Chemistry, Stable Radicals, Synthetic Reagents, TEM
相关文献及参考
- Yonekuta, Y.; Susuki, K.; Oyaizu, K.; Honda, K.; Nishide, H. J. Am. Chem. Soc. 129 , 14128, (2007) 摘要
- Nakahara, K.; Iwasa, S.; Satoh, M.; Morioka, Y.; Iriyama, J.; Suguro, M.; Hasegawa, E. Chem. Phys. Lett. 359 , 351, (2002)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P333+P313+P362+P364
- P305+P351+P338+P337+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
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