4-Nitrosodiphenylamine 4-亚硝基二苯胺

CAS 156-10-5 MFCD00002062

化学结构图

156-10-5
SMILES: O=Nc1ccc(Nc2ccccc2)cc1

化学属性

Mol. FormulaC12H10N2O
Mol. Weight198.22
Melting Point140.0 to 145.0 deg-C
Appearance 绿色结晶。熔点144℃（分解）。易溶于乙醇、醚、氯仿、苯，微溶于水。

别名和识别编码

Chemical Name4-Nitrosodiphenylamine
MDL NumberMFCD00002062
CAS Number156-10-5
PubChem Substance ID9074
EC Number205-848-7
Chemical Name Translation4-亚硝基二苯胺
Synonym 4-NITROSO-N-PHENYLANILINE 4-NITROSODIPHENYLAMINE 4-Niinylamine 4-Nitroso-N-phenylbenzenamine 4-Nitrosodiphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Reaxys-RN1952651
Merck Number6639
LabNetwork Molecule IDLN00238197
InChIInChI=1S/C12H10N2O/c15-14-12-8-6-11(7-9-12)13-10-4-2-1-3-5-10/h1-9,13H
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Nitroso Compounds, Organic Building Blocks

安全信息

Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
RTECSJK0175000
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
WGK Germany3
GHS Symbol
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Hazard Codes Xn
Risk Statements
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Packing GroupIII
Hazard Class6.1(b)
UN Number 2811 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 204 gm/kg/57W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-190,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1365 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
   to Man.  (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210)
   V.1-    1972-  Volume(issue)/page/year: 27,227,1982

Storage condition -20°C -20℃

其他信息

  • 下游产品:对氨基二苯胺 --> 蓝色基 RT
  • TCI Shanghai:4-亚硝基二苯胺 4-Nitrosodiphenylamine,>;95.0%(T)(156-10-5)
  • 用途一:橡胶硫化促进剂。
  • 方法一:将30g苯胺、30g硝基苯和120g干燥的氢氧化钠粉末混匀，加热至110-120℃，搅拌后变成稀液，再升温至120-125℃，反应液颜色变深并浓筒，当反应液固化时，反应即达终点。冷却，溶于热水，冷却，过滤，滤液通二氧化碳后滤出蓝黑色针状晶体。滤液再通二氧化碳，滤取第二批产物。合并两批产物，用乙醇重结晶，得纯品对业硝基二苯胺。
  • MOL 文件:156-10-5.mol
  • 4-亚硝基二苯基胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0263 4-亚硝基二苯胺 4-Nitrosodiphenylamine 25G 1130元 2010/06/21 214310050 4-亚硝基二苯基胺 4-Nitrosodiphenylamine 75%, tech. 5 GR 254元 2010/06/21 214311000 4-亚硝基二苯基胺 4-Nitrosodiphenylamine 75%, tech. 100 GR 579元
  • Sigma Aldrich:156-10-5(sigmaaldrich)
  • 上游原料:二氧化碳 --> 二苯胺
  • Acros Organics:4-亚硝基二苯胺 4-Nitrosodiphenylamine, tech., 75%(156-10-5)
  • 图谱信息:4-亚硝基二苯基胺(156-10-5)质谱(MS) 4-亚硝基二苯基胺(156-10-5)核磁图( 1 HNMR) 4-亚硝基二苯基胺(156-10-5)红外图谱(IR2) 4-亚硝基二苯基胺(156-10-5)核磁图( 13 CNMR) 4-亚硝基二苯基胺(156-10-5)红外图谱(IR1)

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Stable Isotopes 稳定同位素
  3. Alphabetical Listings for Stable Isotope Labeled Products
  4. N-O - Alphabetical Listings
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitroso Compounds - Nitrogen Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. N - Alphabetic
  5. NA - NI - N
  1. Functional Group 官能团索引
  2. nitroso compound

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