trans-1,2-Dichloroethylene, 99+%, stabilized 反-1,2-二氯乙烯

CAS 156-60-5 MFCD00062942

化学结构图

156-60-5
SMILES: Cl/C=C/Cl

化学属性

Mol. FormulaC2H2Cl2
Mol. Weight96.94
Refractive index1.4440 to 1.4470
Boiling Point48-60 °C at 760 mmHg
Vapor Pressure5.16 psi ( 20 °C)
Density1.257
Melting Point-57 °C
Flash Point6.11°C
TSCAYes
Solubility不溶于水,溶于醇、醚等。
Stability对光线敏感,对湿度敏感

别名和识别编码

Chemical Nametrans-1,2-Dichloroethylene, 99+%, stabilized
Synonym 1,2-trans-Dichloroethylene {LY} 1,2-trans-Dichloroethylene {} {LY} 1,2-trans-Dichloroethylene {} {} {LY} 1,2-trans-Dichloroethylene {} {} {} {LY} 1,2-trans-Dichloroethylene {} {} {} {} {LY} 1,2-trans-Dichloroethylene {} {} {} {} {} {LY} 1,2-trans-Dichloroethylene {} {} {} {} {} {} {LY} 1,2-trans-Dichloroethylene {} {} {} {} {} {} {} {LY} 1,2-trans-Dichloroethylene {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 1,2-trans-Dichloroethylene {} {} {} {} {} {} {} {} {} {LY} 1,2-trans-Dichloroethylene {} {} {} {} {} {} {} {} {} {} {LY} 1,2-trans-Dichloroethylene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-trans-Dichloroethylene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-trans-Dichloroethylene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-trans-Dichloroethylene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-trans-Dichloroethylene {} {} {} {} {} {}
MDL NumberMFCD00000925
CAS Number156-60-5
PubChem Substance ID638186
EC Number205-860-2
Beilstein Registry Number1420761
Merck Number92
Reaxys-RN1420761
Chemical Name Translation反-1,2-二氯乙烯
Wiswesser Line NotationG1U1G -T
LabNetwork Molecule IDLN00192984
InChIInChI=1S/C2H2Cl2/c3-1-2-4/h1-2H/b2-1+
Canonical SMILESCl/C=C/Cl
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chemical Class, Chloro, Chromatography, D,
  • {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {SNA} Additional Standards, Alpha Sort, Analytical Standards, Chemical Class, Chloro, Chromatography, D, Environmental Standards, Halogenated, Organic Pollutant Standards, Volatile & Semivolatile Standards, Volatiles/ Semivolatiles, 分析/色谱

产品应用

  • 水质分析

相关文献及参考

  • Merck:14,92 Beilstein: 1,IV,709
  • Short: II/25B
  • Short: II/2
  • Merck:14,92

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RTECSKV9400000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P307+P311
  • P308+P313
  • P309+P311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 1150 UN1150
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20 Harmful by inhalation 吸入有害
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
  • R52/53
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S29 Do not empty into drains 不要排入下水道;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
Hazard Codes 3 F,Xn,T
Storage condition 0-10 0-10°C Refrigerator 储存温度2-8℃ 通氩密封
Hazard Class3
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3952 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/yea

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 43 gm/m3/6H
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Behavioral - convulsions or effect on seizure threshold
   Gastrointestinal - nausea or vomiting
REFERENCE :
   AHBAAM Archiv fuer Hygiene und Bakteriologie.  (Munich, Fed. Rep. Ger.)
   V.101-154, 1929-71.  For publisher information, see ZHPMAT.
   Volume(issue)/page/year: 116,131,1936

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2122 mg/kg
TOXIC EFFECTS :
   Behavioral - altered sleep time (including change in righting reflex)
   Behavioral - somnolence (general depressed activity)
   Behavioral - ataxia
REFERENCE :
   DCTODJ Drug and Chemical Toxicology.  (Marcel Dekker, 270 Madison Ave., New
   York, NY 10016) V.1-    1977/78-  Volume(issue)/page/year: 8,373,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7411 mg/kg
TOXIC EFFECTS :
   Cardiac - other changes
   Lungs, Thorax, or Respiration - other changes
   Liver - fatty liver degeneration
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 7,141,1977

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 50 ug/plate
REFERENCE :
   TECSDY Toxicological and Environmental Chemistry.  (Gordon & Breach Science
   Pub. Inc., 1 Park Ave., New York, NY 10016)  V.3(3/4)-    1981-
   Volume(issue)/page/year: 15,101,1987

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 80 mmol/L
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   4,365,1984

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 6500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 182,135,1987

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 22 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 206,209,1988

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 51500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 206,209,1988

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 6000 ppm/6H
SEX/DURATION            : female 7-16 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   20,225,1993

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 12000 ppm/6H
SEX/DURATION            : female 7-16 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   20,225,1993

其他信息

  • 职业标准:TLV-TWA 200 PPM(790 毫克/ 立方米)
  • 外观性质:无色、略带刺激气味的易挥发液体。
  • 毒性分级:中毒
  • RTECS号:KV9360000
  • HazardClass:3.1
  • 有类似氯仿气味。 蒸气与空气形成爆炸性混合物。受热分解有毒的光气和氯化氢等气体
  • 蒸气压:5.32 psi ( 20 °C)
  • 刺激数据:皮肤- 兔子 100 毫克/24小时 中度; 眼- 兔子 10 毫克 中度
  • Acros Organics:反式-1,2-二氯乙烯 trans-1,2-Dichloroethylene, stabilized, 99.70%(156-60-5)
  • 外观性质:无色透明易流动液体,有类似氯仿气味。 蒸气与空气形成爆炸性混合物。受热分解有毒的光气和氯化氢等气体。沸点:48℃熔点:-50℃密度:1.26 折光率:1.4460 闪点:6℃
  • 用途:可用作油漆、树脂、蜡、橡胶、乙酸纤维的溶剂,用于干洗剂,杀虫剂,杀菌剂,麻醉剂,低温萃取剂及冷冻剂等。
  • 爆炸物危险特性:与铜接触生成可爆化合物; 与空气混合可爆
  • MOL 文件:156-60-5.mol
  • 类别:易燃液体
  • 挥发性有机化合物(VOCs)单组分标准液
  • 可燃性危险特性:明火、受热、氧化剂可燃; 遇酸、受热放出含氯化物有毒气体
  • 灭火剂:雾状水、泡沫、二氧化碳、1211灭火剂
  • Alfa Aesar:反-1,2-二氯乙烯,98%,stab.with4-methoxyphenol trans-1,2-Dichloroethylene, 98%, stab. with 4-methoxyphenol(156-60-5)
  • 图谱信息:反-1,2-二氯乙烯(156-60-5)核磁图( 1 HNMR)
  • 反-1,2-二氯乙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 L1399402 Lancaster 100g 1370元 2011/04/16 D0368 反-1,2-二氯乙烯(含稳定剂MEHQ) trans-1,2-Dichloroethylene (stabilized with MEHQ) 25G 661元 2011/04/16 S0622 反-1,2-二氯乙烯(1mg/ml的甲醇溶液)[用于水分析] trans-1,2-Dichloroethylene (1mg/ml in Methanol) [for Water Analysis] 1ML 198元
  • 急性毒性:口服- 大鼠 LD50: 1235 毫克/ 公斤; 口服- 小鼠 LD50: 2122 毫克/ 公斤
  • 储运特性:库房通风低温干燥; 轻装轻卸、与氧化剂和酸类分开存放
  • TCI Shanghai:反-1,2-二氯乙烯(1mg/ml的甲醇溶液)[用于水分析] trans-1,2-Dichloroethylene (1mg/ml in Methanol) [for Water Analysis](156-60-5)
  • 生产方法:由1,1,2,2-四氯乙烷经锌粉或铁粉脱氯而得;也可由乙炔和氯在惰性溶剂中反应制得;还可由1,1,2-三氯乙烷通过载于浮石上的氯化铜裂解而得。
  • 用途一:水质分析
  • PackingGroup:II
  • Sigma Aldrich:156-60-5(sigmaaldrich)
  • 有类似氯仿气味。 蒸气与空气形成爆炸性混合物。受热分解有毒的光气和氯化氢等气体。
  • MOL 文件:540-59-0.mol

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