Trifluralin 氟乐灵
CAS 1582-09-8 MFCD00055241
化学结构图
SMILES: CCCN(CCC)c1c([N+](=O)[O-])cc(C(F)(F)F)cc1[N+](=O)[O-]
化学属性
| Mol. Formula | C13H16F3N3O4 |
|---|---|
| Mol. Weight | 335 |
| Melting Point | 48.5-49°C |
| Boiling Point | 139 ºC |
| Density | 0.64 |
| Solubility | 不溶于水，溶于多数有机溶剂。 |
| Flash Point | 100 °C |
别名和识别编码
| Chemical Name | Trifluralin solution |
|---|---|
| CAS Number | 1582-09-8 |
| Synonym | ######## 2,6-Dinitro-N,N-di-n-propyl-4-(trifluoromethyl)aniline 2,6-Dinitro-N,N-di-n-propyl-α,α,α-trifluoro-p-toluidine 2,6-Dinitro-N,N-dipropyl-4- 2,6-Dinitro-N,N-dipropyl-4-(trifluoromethyl)-benzamine 2,6-Dinitro-N,N-dipropyl-4-(trifluoromethyl)-benzamine; 4-(Di-n-propylamino)-3,5-dinitro-1-trifluoromethylbenzene; alpha,alpha,alpha-Trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine; Agreflan 24; Elancolan; L-36352; Treflam; Treflan; Trifurex; Trilin 4E 2,6-Dinitro-N,N-dipropyl-4-(trifluoromethyl)benzenamine 2,6-din 2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzenamine 2,6-二硝基-N,N-二丙基-4-(三氟甲基)苯胺 4-(Di-n-propylamino)-3,5-din 4-(Di-n-propylamino)-3,5-dinitro-1-(trifluoromethyl)benzene 4-(Di-n-propylamino)-3,5-dinitro-1-trifluoromethylbenzene 4-(Trifluoromethyl)-2,6-dinitro T |
| PubChem Substance ID | 5569 |
| EC Number | 216-428-8 |
| Beilstein Registry Number | 1893555 |
| MDL Number | MFCD00055241 |
| Chemical Name Translation | 氟乐灵 |
| Merck Number | 13,9757 |
| Wiswesser Line Notation | FXFFR CNW ENW DN3&3 |
| InChI | InChI=1S/C13H16F3N3O4/c1-3-5-17(6-4-2)12-10(18(20)21)7-9(13(14,15)16)8-11(12)19(22)23/h7-8H,3-6H2,1-2H3 |
信息真实价格透明
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信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Dinitroaniline, EPA, Endocrine Disruptors (Draft), Environmental Standards, Method and Regulation Specific, Oeko-Tex Standard 100, Pesticides, Q-Z, T, TP - TZ, 农残和代谢标准品, 按照字母排序, 灭草剂
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
- {SNA} Alphabetical Index of Analytical Standards,
- {SNA} All Herbicide Stan
- {SNA} Additional Standards, Analytical Standards, Dinitroaniline, EPA, Endocrine Disruptors (Draft), Method and Regulation Specific, Oeko-Tex Standard 100,
产品应用
- 优良的旱田除草剂。
相关文献及参考
- Merck:13,9757
- Short: EINECS
- Short: IV/8A
- Goldenthal, et al.: Toxicol. Appl. Pharmacol., 18, 185 (1971),
- Robens, J.F., et al.: Vet. Hum. Toxicol., 22, 328 (1980),
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H319 Causes serious eye irritation 严重刺激眼睛
- H330 Fatal if inhaled 吸入致命
- H332 Harmful if inhaled 吸入有害
- H351 Suspected of causing cancer 怀疑致癌
- H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P203
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P301+P312
- P301+P317
- P302+P352
- P304+P340
- P304+P340+P312
- P305+P351+P338
- P308+P313
- P308+P316
- P309+P311
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
- P316
- P318
- P319
- P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P332+P317
- P333+P313
- P333+P317
- P337+P313
- P337+P317
- P362+P364
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S2 Keep out of the reach of children 避免儿童触及；
- S37 Wear suitable gloves 戴适当手套；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S24 Avoid contact with skin 避免皮肤接触；
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R50/53
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R22 Harmful if swallowed 吞咽有害
- R23 Toxic by inhalation 吸入有毒
- R36 Irritating to eyes 刺激眼睛
- R11 Highly flammable 非常易燃
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
TYPE OF TEST : TD - Toxic dose (other than lowest) ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 340 gm/kg/78W-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors REFERENCE : NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD) No.0-205. For publisher information, see NTPTR*. Volume(issue)/page/year: NCI-TR-34,1978
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 2600 ug/kg/39D-I TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Blood - lymphoma, including Hodgkin's disease Tumorigenic - tumors at site of application REFERENCE : PATHAB Pathologica. (Via Alessandro Volta, 8 Casella Postale 894, 16128 Genoa, Italy) V.1- 1908- Volume(issue)/page/year: 73,707,1981
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 2600 ug/kg/39D-I TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Blood - lymphoma, including Hodgkin's disease Tumorigenic - tumors at site of application REFERENCE : PATHAB Pathol
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 180 gm/kg/78W-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors REFERENCE : NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD) No.0-205. For publisher information, see NTPTR*. Volume(issue)/page/year: NCI-TR-34,1978
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Unreported SPECIES OBSERVED : Mammal - species unspecified DOSE/DURATION : 5 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,604,1986
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1930 mg/kg TOXIC EFFECTS : Sense Organs and Special Senses (Eye) - mydriasis (pupillary dilation) Behavioral - somnolence (general depressed activity) Skin and Appendages - hair REFERENCE : FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 30,1031,1992
TYPE OF TEST : LC
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >5 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : WRPCA2 World Review of Pest Control. (London, UK) V.1-10, 1962-71.
TYPE OF TEST : LD50 - Le
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 4600 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 20,554,1978
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 1 mg/plate REFERENCE : ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 8(Suppl 7),1,1986
TYPE OF TEST : Sister chromatid exchange TEST SYSTEM : Human Lymphocyte DOSE/DURATION : 1 mg/L REFERENCE : BSIBAC Bolletino della Societe Italiana di Biologia Sperimentale. (Casa Editrice Idelson, Via A. de Gasperi, 55, 80133 Naples, Italy) V.2- 1927- Volume(issue)/page/year: 60,2149,1984
TYPE OF TEST : Cytogenetic analysis TEST SYSTEM : Human Lymphocyte DOSE/DURATION : 2 ppm REFERENCE : PATHAB Pathologica. (Via Alessandro Volta, 8 Casella Postale 894, 16128 Genoa, Italy) V.1- 1908- Volume(issue)/page/year: 73,707,1981
TYPE OF TEST : DNA damage TEST SYSTEM : Human Lymphocyte DOSE/DURATION : 5 mg/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- V
TYPE OF TEST : Sex chromosome loss and nondisjunction TEST SYSTEM : Mold - Neurospora crassa DOSE/DURATION : 1 mg/L REFERENCE : EVHPAZ EHP, Environmental Health Perspectives. (U.S. Government Printing Office, Supt of Documents, Washington, DC 20402) No.1- 1972- Volume(issue)/page/year: 31,75,1979
TYPE OF TEST : Dominant lethal test
TYPE OF TEST : Sister chromatid exchange TEST SYSTEM : Rodent - hamster Ovary DOSE/DURATION : 160 ug/L REFERENCE : ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 7,1,1985
TYPE OF TEST : TDLo - Lowest published toxic dose ROUT
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE : 10 gm/kg SEX/DURATION : female 6-15 day(s) after conception TOXIC EFFECTS : Reproductive - Effects on Newborn - stillbirth REFERENCE : TJADAB Teratology, The International Journal of Abnormal Development. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1968- Volume(issue)/page/year: 23,33,1981
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE : 200 mg/kg SEX/DURATION : male 1 day(s) pre-mating TOXIC EFFECTS : Reproductive - Fertility - pre-implantation mortality (e.g. reduction in number of implants per female; total number of implants per corpora lutea) Reproductive - Effects on Embryo or Fetus - cytological changes (including somatic cell genetic material) Reproductive - Effects on Embryo or Fetus - fetal death REFERENCE : EESADV Ecotoxicology and Environmental Safety. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1977- Volume(issue)/page/year: 4,263,1980
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 21800 mg/kg SEX/DURATION : multigeneration TOXIC EFFECTS : Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured before birth) Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight gain) REFERENCE : FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 30,1031,1992
其他信息
- 用途二:属芽前除草剂，用于防除棉花、饲用豆类田一年生杂草
- 储运特性:库房通风低温干燥; 与食品原料分开储运
- 注意事项:[1]大豆田播前施用该药，应在播前5－7天施药 [2]低温干旱地区，持效期较长，下茬不宜种高粱、谷子等敏感作物
- 类别:农药
- 可燃性危险特性:燃烧产生有毒氮氧化物和氟化物气体
- 毒性分级:中毒
- 用途:氟乐灵适用于大豆、棉花、玉米、小麦、旱稻、甘蔗、甜菜、向日葵、番茄、甘蓝、菜豆、胡萝卜、芹菜、香菜等40多种作物及果园、林业苗圃、花卉、草坪、种植 园等防除稗草、野燕麦、狗尾草、马唐、牛筋草、碱茅、千金子、早熟禾、看麦娘、藜、苋、繁缕、猪毛菜、宝盖草、马齿苋等一年生禾本科杂草及部分双子叶杂草。大豆于播前5~7天土壤处理，立即交叉混土5~7厘米深。用药量根据土壤有机质含量不同而异，一般每公顷用48%氟乐灵乳油1.5~3升。与灭草猛、嗪草酮、甲羧除草醚等除草剂混用，可互补不足，扩大杀草谱，提高作物安全性。油菜、花生、芝麻、棉花、十字花科蔬菜等作物田使用，应在播前或苗前施药。不可在百合科、菊科、茄科、葫芦科、藜科蔬菜的直播育苗田中应用，对移载蔬菜番茄、茄子、柿子椒、甘蓝、菜花等，应在移载前或移载后杂草出苗前使用，在移载黄瓜田，待苗高10~15厘米上架时方可作土壤处理，移栽芹菜、洋葱、沟葱、老根韭菜，缓苗后可应用。冬小麦在浇冻水前处理。葡萄、苹果等种植园，春季松土后，杂草
- 毒性:大鼠急性经口LD 50 >10000mg/kg，小鼠为5000mg/kg，狗>2000mg/kg，家兔急性经皮LD 50 >2000mg/kg；以2000mg/kg剂量喂养大鼠2年，未见不良影响。对鱼类毒性较在，鲤鱼LC 50 为4.2mg/L (48h)，金鱼为0.59mg/L，蓝鳃鱼为0.058mg/L。蜜蜂致死量为24mg/只。
- 用途三:广谱的旱地芽前除草剂。可用于棉花、大豆、豌豆、油菜、花生、土豆、冬小麦、大麦、蓖麻、
- 急救治疗:尚无特效解毒剂。若摄入量大，病人十分清醒，可用吐根糖浆诱吐，还可在服用的活性炭泥中加入山梨醇。
- 用途四:优良的旱田除草剂。主要用于棉花、大豆、花生、向日葵、甘蓝、辣椒、豆类、果园等，也可用于麦地和旱稻田，防除一年生禾本科和种子繁殖的多所生杂草和某些阔叶杂草，如稗草、狗尾草、马唐、看麦娘、蟋蟀草、千金子、早熟禾、雀麦、野燕麦、雀舌草、藜、苋、粟米草、繁缕、地肤、马齿苋等。对龙葵、苍耳、苘麻等宿根性多年生杂草防效差或基本无效。对成株杂草无效。高梁、谷子等敏感作物不能使用；甜菜、番茄、马铃薯、黄瓜等抗
- 上游原料:硝酸 --
- MSDS 信息:氟乐灵(1582-09-8).msds
- 用途五:优良的旱田除草剂。主要用于棉花；大豆；花生；向日葵；甘蓝；辣椒；豆类；果园等，也可用于麦地和旱稻田，防除一年生禾本科和种子繁殖的多所生杂草和某些阔叶杂草，如稗草；狗尾草；马唐；看麦娘；蟋蟀草；千金子；早熟禾；雀麦；野燕麦；雀舌草；藜；苋；粟米草；繁缕；地肤；马齿苋等。对龙葵；苍耳；苘麻等宿根性多年生杂草防效差或基本无效。对成株杂草无效。高梁；谷子等敏感作物不能使用；甜菜；番茄；马铃薯；黄瓜等抗性不强，又能用作移栽田。合世界年消费量达万吨及水平。
- Sigma Aldrich:1582-09-8(sigmaaldrich)
- 用途一:用作水果、棉花、大豆等多种作物的除草剂
- 方法一:4-三氟甲基-2，4-二硝基氯苯的制备 甲苯经催化制得氯甲苯，再在光催化下通氯，制得对氯三
- 外观性质:纯度为98% 是橙黄色结晶，有芳香气味。
- 产品特性:选择性芽前二硝基苯胺类除草剂。商品名特福力、氟特力。密封保存稳定期为3年。能与大多数农药混配。对高等动物低毒，对家兔眼睛、皮肤有刺激作用。作用机制
- 产品特性:选择性芽前二硝基苯胺类除草剂。商品名特福力、氟特力。密封保存稳定期为3年。能与大多数农药混配。对高等动物低毒，对家兔眼睛、皮肤有刺激作用。作用机制 对已出土杂草无效。施药后要立即混土 ，在温暖潮湿的土壤中，按推荐药量，药效长8~12周。
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