1-Propynylmagnesium bromide 1-丙炔溴化镁

CAS 16466-97-0 MFCD00216588

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H98728
1-Propynylmagnesium bromide 1-丙炔溴化镁
0.5 M solution in THF, SpcSeal 25mL ¥ 70
库存 辽宁
中国国内现货 0.5 M solution 四氢呋喃
INFI H98728
1-Propynylmagnesium bromide 1-丙炔溴化镁
0.5 M solution in THF, SpcSeal 100mL ¥ 170
库存 辽宁
中国国内现货 0.5 M solution 四氢呋喃
INFI H98728
1-Propynylmagnesium bromide 1-丙炔溴化镁
0.5 M solution in THF, SpcSeal 500mL ¥ 450
库存 辽宁
中国国内现货 0.5 M solution 四氢呋喃
INFI H47561
1-Propynylmagnesium bromide 1-丙炔溴化镁
1.0 M solution in THF, SpcSeal 100mL ¥ 970
1.0 M solution 四氢呋喃
INFI H47561
1-Propynylmagnesium bromide 1-丙炔溴化镁
1.0 M solution in THF, SpcSeal 500mL ¥ 3,450
1.0 M solution 四氢呋喃
Aldrich 429007
1-Propynylmagnesium bromide solution 1-丙炔溴化镁 溶液
0.5 M in THF 0.5?M in THF 100mL ¥ 1,260
库存 SH
中国国内现货 0
Aldrich 429007
1-Propynylmagnesium bromide solution 1-丙炔溴化镁 溶液
0.5 M in THF 0.5?M in THF 800mL ¥ 4,713
库存 SH
中国国内现货 0
HY Y84159
1-Propynylmagnesium bromide 1-丙炔溴化镁
0.5 M solution in THF, HySeal 100mL ¥ -
0.5 M solution 四氢呋喃
HY Y84159
1-Propynylmagnesium bromide 1-丙炔溴化镁
0.5 M solution in THF, HySeal 800mL ¥ -
0.5 M solution 四氢呋喃
Acros C4260
100mL ¥ 722
Acros C4260
800mL ¥ 2,943
Acros C4260
1L ¥ 2,074
Energy-chemical W420234
1-PROPYNYLMAGNESIUM BROMIDE 1-丙炔溴化镁溶液
25mL ¥ 198
库存 上海市 北京市
中国国内现货 1.0 M
Energy-chemical W420234
1-PROPYNYLMAGNESIUM BROMIDE 1-丙炔溴化镁溶液
100mL ¥ 545
库存 上海市 北京市
中国国内现货 1.0 M
Energy-chemical W420234
1-PROPYNYLMAGNESIUM BROMIDE 1-丙炔溴化镁溶液
500mL ¥ 1,970
库存 上海市 北京市
中国国内现货 1.0 M
3A A01622
1-Propynylmagnesium bromide 1-丙炔溴化镁
0.5 M solution in THF, SpcSeal 100mL ¥ 380
0.5 M solution 四氢呋喃
3A A01622
1-Propynylmagnesium bromide 1-丙炔溴化镁
0.5 M solution in THF, SpcSeal 500mL ¥ 1,260
0.5 M solution 四氢呋喃
Acros 426071000
0.5M solution in THF, AcroSeal? 100mL ¥ 739
0.5 M solution 四氢呋喃
Acros 426078000
0.5M solution in THF, AcroSeal? 800mL ¥ 3,014
0.5 M solution 四氢呋喃
Aladdin P137858-25ml
0.5 M in THF 25mL ¥ 198
0.5 M solution 四氢呋喃
Adamas 28356B
0.5 M solution in THF,SafeSeal 100mL ¥ 540
0.5 M solution 四氢呋喃
Adamas 28356C
0.5 M solution in THF,SafeSeal 500mL ¥ 2,004
0.5 M solution 四氢呋喃
Aldrich 429007-100ML
0.5 M in THF 100mL ¥ 1,355
0.5 M solution 四氢呋喃
Aldrich 429007-800ML
0.5 M in THF 800mL ¥ 5,067
0.5 M solution 四氢呋喃

分类

  • {SNA} Alkynyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

产品应用

  • ⑴. 由于镁原子直接和碳链相连,极化作用使邻近镁原子的那个碳原子呈负电性,使得C-Mg键极具反应活性。为了保证该产品不发生其他反应,反应一般在醚类溶剂里进行,常用的有乙醚或四氢呋喃。 ⑵. 有强烈的亲核性质,可与物质中的活泼氢(如水、乙醇的羟基氢、乙炔的末端氢)反应,生成相应的烃基。 ⑶. 与CO2或O2的反应,可以与二氧化碳或氧气发生亲核加成反应生成增加一个碳的羧酸或同碳数的过氧化合物.格氏试剂与二氧化碳的加成反应在有机合成中也有着重要的意义,不仅通过生成新的 C-C 键实现了碳链的增长,而且恰到好处地

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P402+P404
  • P231+P232
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P370+P378
  • P403+P235
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P422 Store contents under… 存储目录在…之下。
  • P305+P351+P338
Signal word Danger
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Hazard Codes F,C
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R37 Irritating to respiratory system 刺激呼吸道
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R34 Causes burns 会导致灼伤
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用

其他信息

  • ⑴. 该品在启用过程中应最大限度的隔绝空气和水份,密封保存在低温、干燥,有氮气保护的容器中。 ⑵.不宜长时间存放。

化学结构图

CAS 16466-97-0  MFCD00216588
SMILES: CC#C[Mg]Br

化学属性

Mol. FormulaCH3C≡CMgBr
Mol. Weight143.26
Boiling Point65-67 °C
Density0.941 g/mL at 25 °C

别名和识别编码

Chemical Name1-Propynylmagnesium bromide
PubChem Substance ID24866829
Beilstein Registry Number3929146
MDL NumberMFCD00216588
CAS Number16466-97-0
Synonym 1-丙炔溴化镁 溶液
Chemical Name Translation1-丙炔溴化镁

系列性分类


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