2-(Triphenylphosphoranylidene)Acetonitrile (三苯基膦)乙腈

CAS 16640-68-9 MFCD00567633

化学结构图

16640-68-9
SMILES: N#CC=P(c1ccccc1)(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC20H16NP
Mol. Weight301
Melting Point189-195

别名和识别编码

Chemical Name2-(Triphenylphosphoranylidene)Acetonitrile
Synonym (氰亚甲基)三苯基膦 Cyanomethyltriphenylphosphonium ylide
MDL NumberMFCD00567633
PubChem Substance ID87577659
CAS Number16640-68-9
EC Number240-689-7
Reaxys-RN750218
Chemical Name Translation(三苯基膦)乙腈
Beilstein Registry Number750218
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分类

  • {SA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. H. Holla, et al., Bioorg. Med. Chem. Lett. 21 , 4793-4797, (2011)
  • 2. C. Zhao, et al., J. Am. Chem. Soc. 133 , 10787-10789, (2011)
  • 3. F. Ziyanak, et al., Adv. Synth. Catal. 353 , 897-902, (2011)
  • 4. T. J. Martin, et al., Org. Lett. 13 , 2586-2589, (2011)
  • 5. Y. Hiraga, et al., Tetrahedron Asymmetry 22 , 226-237, (2011)
  • 6. F. Fang, et al., Eur. J. Org. Chem. 6 , 1084-1091, (2011)
  • 7. M. Yuan, et al., J. Organomet. Chem. 696 , 905-912, (2011)
  • 8. K. Lee, Bull. Korean Chem. Soc. 31 , 2776-2782, (2010)
  • 9. J. Org. Chem. 72 , 4378, (2007) 摘要

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P305+P351+P338
  • P301+P310+P330
  • P302+P352+P312+P361+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P305+P351+P338+P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H301+H311+H331
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Storage condition 0-10 0-10°C
UN Number 2811
Packing GroupIII
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Class6.1

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Cyanides/Nitriles - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Others - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Wittig & Horner-Emmons Reaction
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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