1-Butyl-3-Methylimidazolium Hexafluorophosphate 1-丁基-3-甲基咪唑六氟磷酸盐
CAS 174501-64-5 MFCD03093295
化学结构图
SMILES: CCCCN1C=[N+](C)C=C1.F[P-](F)(F)(F)(F)F
化学属性
| Mol. Formula | C8 |
|---|---|
| Mol. Weight | 284 |
| Boiling Point | ＞340 |
| Melting Point | N\/A6.5 |
| Density | 1.38 |
| Refractive index | 1.4090 to 1.4130 |
| TSCA | No |
| Stability | 易吸潮 |
别名和识别编码
| Chemical Name | 1-Butyl-3-Methylimidazolium Hexafluorophosphate |
|---|---|
| CAS Number | 174501-64-5 |
| Alfabeta Name | BUTYLMETHYLIMIDAZOLIUMHEXAFLUOROPHOSPHATE 13--- |
| MDL Number | MFCD03093295 |
| Synonym | |
| EC Number | 000-000-0 |
| Merck Number | 1581 |
| Beilstein Registry Number | 8026031 |
| PubChem Substance ID | 87565152 |
| Reaxys-RN | 8026031 |
| Chemical Name Translation | 1-丁基-3-甲基咪唑六氟磷酸盐 |
| LabNetwork Molecule ID | LN00119727 |
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信息真实价格透明
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分类
- {SNA} Chemical Synthesis, Imidazolium, Ionic Liquids, Specialty Synthesis
产品应用
- 离子液体,用在许多环保型的反应中。
相关文献及参考
- Heck reactions with aryl halides can be carried out with controlled microwave heating: J. Org. Chem., 67, 6243 (2002).
- Merck: 14,1581
- Ionic liquid.
- For use in dihydroxylation of alkenes with Osmium(VIII) oxide, 12103, facilitating the reuse of the Os catalyst, see: Org. Lett., 4, 2197 (2002).
- Recyclable medium for oxidation of alcohols, catalyzed by TEMPO, A12733, and CuCl, to give aldehydes and ketones chemoselectively under mild conditions: Org. Lett., 4, 1507 (2002).
- A copper-free Sonogashira coupling of terminal alkynes with aryl iodides, catalyzed by trans-Dichlorobis(triphenylphosphine)palladium(II), 10491, has been adapted to a microflow system for efficient catalyst recycling: Org. Lett., 4, 1691 (2002).
安全信息
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P305+P351+P338+P337+P313
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
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