(Methoxycarbonylmethyl)Triphenylphosphonium Bromide (甲氧基羰基甲基)三苯基溴化鏻

CAS 1779-58-4 MFCD00011801

化学结构图

1779-58-4
SMILES: COC(=O)C[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-]

化学属性

Mol. FormulaC21H20BrO2P
Mol. Weight415.27
Melting Point172°C
TSCANo
Stability易吸潮

别名和识别编码

Chemical Name(Methoxycarbonylmethyl)Triphenylphosphonium Bromide
Synonym (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide {LY} (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide {} {LY} (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {LY} (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {LY} (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {LY} (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {LY} (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {LY} (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {LY} (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {LY} (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {LY} (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {LY} (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Methoxy-2-oxoet
Beilstein Registry Number3812975
PubChem Substance ID2733211
CAS Number1779-58-4
EC Number217-222-0
MDL NumberMFCD00011801
Reaxys-RN3812975
Chemical Name Translation(甲氧基羰基甲基)三苯基溴化鏻
InChIKeyWAUPCPBLQVSZQD-UHFFFAOYSA-N
LabNetwork Molecule IDLN00201723
InChIInChI=1S/C21H20O2P.BrH/c1-23-21(22)17-24(18-11-5-2-6-12-18,19-13-7-3-8-14-19)20-15-9-4-10-16-20;/h2-16H,17H2,1H3;1H/q+1;/p-1
Canonical SMILESO=C(OC)C[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • Beilstein:16(4)988

安全信息

Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
WGK Germany3
GHS Symbol
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition RT, stored under nitrogen {LY} RT, stored under nitrogen {} {LY} RT, stored under nitrogen {} {} {LY} RT, stored under nitrogen {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Sigma Aldrich:1779-58-4(sigmaaldrich)
  • TCI Shanghai:(甲氧基羰基甲基)三苯基溴化 Methoxycarbonylmethyl(triphenyl)phosphonium Bromide,>;97.0%(T)(1779-58-4)
  • F:9
  • 图谱信息:甲氧甲酰基甲基三苯基溴化膦(1779-58-4)质谱(MS) 甲氧甲酰基甲基三苯基溴化膦(1779-58-4)红外图谱(IR1) 甲氧甲酰基甲基三苯基溴化膦(1779-58-4)红外图谱(IR2)
  • MOL 文件:1779-58-4.mol
  • 敏感性:Hygroscopic
  • Alfa Aesar:(甲氧基羰基甲基)三苯基溴化,98+% (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%(1779-58-4)
  • 甲氧甲酰基甲基三苯基溴化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1326 甲氧基羰基甲基(三苯基)溴化 Methoxycarbonylmethyl(triphenyl)phosphonium Bromide 25G 383元 2010/05/25 A16301 (甲氧基羰基甲基)三苯基溴化, 98+% (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+% 500g 2940元 2010/05/25 A16301 (甲氧基羰基甲基)三苯基溴化, 98+% (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+% 25g 297元

系列性分类


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