Methoxytrimethylsilane 三甲基甲氧基硅

CAS 1825-61-2 MFCD00008344

化学结构图

1825-61-2
SMILES: CO[Si](C)(C)C

化学属性

Mol. FormulaC4H12OSi
Mol. Weight104.22
Refractive index1.3660 to 1.3710
Boiling Point57-58 °C at 760 mmHg
Density0.756
Flash Point-30°C(lit.)
TSCAYes

别名和识别编码

Chemical NameMethoxytrimethylsilane
Synonym Methoxytrimethylsilane {LY} Methoxytrimethylsilane {} {LY} Methoxytrimethylsilane {} {} {LY} Methoxytrimethylsilane {} {} {} {LY} Methoxytrimethylsilane {} {} {} {} {LY} Methoxytrimethylsilane {} {} {} {} {} {LY} Methoxytrimethylsilane {} {} {} {} {} {} {LY} Methoxytrimethylsilane {} {} {} {} {} {} {} {LY} Methoxytrimethylsilane {} {} {} {} {} {} {} {} {LY} Methoxytrimethylsilane {} {} {} {} {} {} {} {} {} {LY} Methoxytrimethylsilane {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Methoxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number1825-61-2
PubChem Substance ID15771
EC Number217-369-0
Beilstein Registry Number1731490
MDL NumberMFCD00008344
Reaxys-RN1731490
Chemical Name Translation三甲基甲氧基硅
InChIKeyPOPACFLNWGUDSR-UHFFFAOYSA-N
LabNetwork Molecule IDLN00222168
InChIInChI=1S/C4H12OSi/c1-5-6(2,3)4/h1-4H3
Canonical SMILESC[Si](C)(OC)C
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分类

  • {SNA} Materials Science, Micro/NanoElectronics, Mono-Alkoxy Silanes, Self Assembly & Contact Printing, Self-Assembly Materials, Silane Coupling Agents/Adhesion Promoters, Silanes
  • {SNA} Micro/NanoElectronics, Mono-Alkoxy Silanes, Self Assembly & Contact Printing, Self-Assembly Materials, Silane Coupling Agents/Adhesion Promoters, Silanes, 材料科学
  • Materials Science, Micro/NanoElectronics, Mono-Alkoxy Silanes, Self Assembly & Contact Printing, Self-Assembly Materials, Silane Coupling Agents/Adhesion Promoters, Silanes
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Beil. 4 ,IV,3994
  • Aldrich MSDS 1 , 1198:C / Corp MSDS 1 (2), 2276:C / FT-IR 1 (2), 1096:A / FT-IR 2 (3), 4367:D / FT-NMR 1 (3), 657:B / RegBook 1 (2), 2967:G / Structure Index 1 , 469:A:7 / Vapor Phase 3 , 1640:D
  • Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constant

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
Hazard Codes 3
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 1993 UN 1993 3/PG 2
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36 Irritating to eyes 刺激眼睛
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Storage condition 2-8°C {LY} 2-8°C Flammables area Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Packing GroupII
Hazard Class3

其他信息

  • 图谱信息:简称TMSOME(1825-61-2)核磁图( 13 CNMR) 简称TMSOME(1825-61-2)质谱(MS) 简称TMSOME(1825-61-2)红外图谱(IR1)
  • MOL 文件:1825-61-2.mol
  • 简称TMSOME价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0688 甲氧基三甲基硅烷 Methoxytrimethylsilane 250ML 1900元 2014/06/02 M0688 甲氧基三甲基硅烷 Methoxytrimethylsilane 25ML 416元 2010/06/21 392470250 简称TMSOME Methoxytrimethylsilane 96+% 25 GR 594元
  • Sigma Aldrich:1825-61-2(sigmaaldrich)
  • Acros Organics:三甲基甲氧基硅烷 Methoxytrimethylsilane, 96+%(1825-61-2)
  • Alfa Aesar:甲氧基三甲基硅烷,97+% Methoxytrimethylsilane, 97+%(1825-61-2)
  • 敏感性:Moisture Sensitive
  • TCI Shanghai:三甲基甲氧基硅 Methoxytrimethylsilane,>;98.0%(GC)(1825-61-2)
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Siloxanes - Organosilicon
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Self Assembly & Contact Printing - Micro/NanoElectronics
  4. Self-Assembly Materials - Self Assembly & Contact Printing
  5. Silanes - Self-Assembly Materials
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Self Assembly & Contact Printing - Micro/NanoElectronics
  4. Silane Coupling Agents/Adhesion Promoters - Self Assembly & Contact Printing
  5. Mono-Alkoxy Silanes - Silane Coupling Agents/Adhesion Promoters

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