Bis(Trimethylsilyl) Sulfate 双(三甲基硅基)硫酸酯

CAS 18306-29-1 MFCD00008268

化学结构图

18306-29-1
SMILES: C[Si](C)(C)OS(=O)(=O)O[Si](C)(C)C

化学属性

Mol. FormulaC6H18O4SSi2
Mol. Weight242.44
Boiling Point90°C/4mmHg(lit.)
Melting Point44-47
Flash Point-2°(27°F)
TSCANo

别名和识别编码

Chemical NameBis(Trimethylsilyl) Sulfate
Synonym bis(trimethylsilyl)sulfate Silanol, trimethyl-, sulfate (2:1) Bis(trimethylsilyl) sulfate bis(trimethylsilyl) sulphate sulfuric acid bis-trimethylsilanyl ester Bis-(trimethylsilyl)-sulfat BSS Sulfuric acid bis(trimethylsilyl)ester Bis(trimethylsilyl)-sulfat BSS Sulfuric acid bis(trimethylsilyl)ester Sulfuric acid bis(trimethylsilyl) ester
EC Number242-192-0
Beilstein Registry Number4(4)4009
MDL NumberMFCD00008268
CAS Number18306-29-1
Reaxys-RN1781429
PubChem Substance ID87564181
Chemical Name Translation双(三甲基硅基)硫酸酯
InChIKeyKRUQDZRWZXUUAD-UHFFFAOYSA-N
LabNetwork Molecule IDLN01739726
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分类

  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 463 p. 40 illus., Hardcover RefComment: Written for: Scientists and engineers in the fields of physics, chemistry, and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment, i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 "Nuclear Magnetic Resonance (NMR) Data" is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 ''NMR-Data'' is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei B-11 and P-31, subvolume III/35B contains the nuclei F-19 and N-15, subvolume III/35C contains the nucleus H-1, subvolume III/35D contains the nucleus C-13, subvolume III/35E contains the nucleus O-17, subvolume III/35F contains the nucleus Si-29, and subvolume III/35G contains the nucleus Se-77. More nuclei will be presented later.
  • Short: EINECS Title: EINECS (European Inventory of Existin

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H228 Flammable solid 易燃固体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P303+P361+P353+P310+P363
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P301+P330+P331
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P304+P340
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P310
  • P501a
  • P405 Store locked up. 上锁保管。
  • P303+P361+P353
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P305+P351+P338+P310
  • P301+P330+P331+P310
Signal word
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S25 Avoid contact with eyes 避免眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupIII
UN Number 2925
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R11 Highly flammable 非常易燃
Storage condition Moisture Sensitive
Hazard Codes
Hazard Class4.1/8

系列性分类


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