Benzylchlorodimethylsilane 苄基二甲基氯硅烷

CAS 1833-31-4 MFCD00018089

化学结构图

1833-31-4
SMILES: C[Si](C)(Cl)Cc1ccccc1

化学属性

Mol. FormulaC9H13ClSi
Mol. Weight184.74
Refractive index1.5070 to 1.5120
Boiling Point211°C(lit.)
Density1.018 g/mL at 25 °C(lit.)
Flash Point73°C(lit.)
Melting Point<0°C

别名和识别编码

Chemical NameBenzylchlorodimethylsilane
Synonym Benzyldimethylchlorosilane BENZYLCHLORODIMETHYLSILANE Benzyldimethylchlorsilan benzyldimethylchlorosilane benzylchlorodimethyl-silan Benzylchlordimethylsilan chlorodimethyl(phenylmethyl)-silan BENZYLDIMETHYLCHLOROSILANE 苄基二甲基氯硅烷 Silane, chlorodimethyl(phenylmethyl)- Benzylchlorodimethylsilane Dimethylchlorobenzylsilane benzyl-chloro-dimethyl-silane
MDL NumberMFCD00018089
CAS Number1833-31-4
PubChem Substance ID87565160
Reaxys-RN2935456
Beilstein Registry Number16(4)1497
Chemical Name Translation苄基二甲基氯硅烷
InChIKeyABHNFDUSOVXXOA-UHFFFAOYSA-N
Wiswesser Line NotationG-SI-1&1&1R
LabNetwork Molecule IDLN01360394
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分类

  • {SNA} Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: III/35D2 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 2: Aromatic Compounds Author: Mikhova, B. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D2 Year: 2005 Keyword: aromatic compounds; carbon-13; chemical shift; coupling constant; molecular structure ISBN: 978-3-540-20189-2 ISBN: 3-540-20189-0 Internet Resource: DOI:10.1007/b83345 RefComment: VIII, 291 p., Hardcover RefComment: Written for Science and engineers in the fields of physics, chemistry and physical chemistry who inted to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, orient by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei 11B and 31P, subvolume III/35B contains the nuclei 19F and 15N, subvolume III/35C contains the nucleus 1H, subvolume III/35D contains the nucleus 13C, subvolume III/35E contains the nucleus 17O, and subvolume III/35G contains the nucleus 77Se. More nuclei will be presented later.
  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Lan

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSVV1810000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353+P310+P363
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P405 Store locked up. 上锁保管。
  • P370+P378
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P304+P340
  • P303+P361+P353
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P310
  • P301+P330+P331+P310
  • P403+P235
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Hazard Codes C
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
UN Number UN 2987 8/PG 2 2987
Packing GroupII
Hazard Class8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04165

其他信息

  • 储运特性:通风低温干燥; 与库房食品原料分开存放
  • TCI Shanghai:苄基二甲基氯硅烷 Benzylchlorodimethylsilane,>;98.0%(GC)(1833-31-4)
  • 可燃性危险特性:可燃; 燃烧产生有毒氯化物烟雾
  • 毒性分级:高毒
  • 急性毒性:静脉-小鼠 LD50; 56 毫克/公斤
  • Sigma Aldrich:1833-31-4(sigmaaldrich)
  • TSCA:Yes
  • MOL 文件:1833-31-4.mol
  • 苄基二甲基氯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B2334 苄基二甲基氯硅烷 Benzylchlorodimethylsilane 5G 1030元
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 类别:有毒物品

系列性分类


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