4,4-Dimethyl-2-phenyl-4,5-dihydrooxazole 4,4-二甲基-2-苯基-4,5-二氢噁唑

CAS 19312-06-2 MFCD00030446

化学结构图

19312-06-2
SMILES: CC1(C)COC(=N1)C1C=CC=CC=1

化学属性

Mol. FormulaC11H13NO
Mol. Weight175.23
Density1.025 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.5322(lit.)
Flash Point102°(215°F)
TSCANo
Boiling Point124 °C/20 mmHg(lit.)
Melting Point20-24 °C(lit.)

别名和识别编码

Chemical Name4,4-Dimethyl-2-phenyl-4,5-dihydrooxazole
MDL NumberMFCD00030446
CAS Number19312-06-2
Beilstein Registry Number132225
Synonym 4,4-二甲基-2-苯基-2-噁唑啉 4,4-Dimethyl-2-phenyl-4,5-dihydro-1,3-oxazole
PubChem Substance ID24861389
Chemical Name Translation4,4-二甲基-2-苯基-4,5-二氢噁唑
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Oxazolines/Oxazolidines

相关文献及参考

  • The phenyl group can be ortho-lithiated. For use in carbonylative cyclization via an aroyllithium intermediate, see: J. Org. Chem., 65, 7944 (2000). For reviews of the chemistry of oxazolines, see: Chem. Rev., 71, 483 (1971); Angew. Chem. Int. Ed., 15, 270 (1976), Tetrahedron, 41, 837 (1985), 50, 2297 (1994). See also 2-Amino-2-methyl-1-propanol, A17814.

安全信息

Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Hazard Codes Xi
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning

系列性分类


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