Fluoranthene 荧蒽

CAS 206-44-0 MFCD00001184

化学结构图

206-44-0
SMILES: c1ccc2c(c1)-c1cccc3cccc-2c13

化学属性

Mol. FormulaC16H10
Mol. Weight202
Boiling Point384
Melting Point105-110
Solubility不溶于水,溶于苯、醚、乙醇、乙酸。
Flash Point-18 °C
Refractive index1.0996
Density1.252

别名和识别编码

Chemical NameFluoranthene
Synonym 1,2-(1,8-Naphthalene)benzene 1,2-(1,8-Naphthalenediyl)benzene 1,2-(1,8-Naphthalenediyl)benzene; 1,2-Benzacenaphthene; Benzo[j,k]fluorene 1,2-(1,8-Naphthylene)benzene 1,2-(1,8-naphthalene)benzene 1,2-(1,8-naphthalenediyl)-benzen 1,2-(1,8-naphthalenediyl)benzene 1,2-(1,8-naphthylene)-benzen 1,2-Benzacenaphthene 1,2-benzacenaphthene 1,2-苯并二氫苊 1,2-苯并苊 1,8-(o-Phenylen)-naphthalin 1,9苯嵌芴 1,2-Benzacenaphthene BENZO(J,K)FLUORENE Benzene, 1,2-(1,8-naphthalenediyl)- Benzene, 1,2-(1,8-naphthylene)- Benzo(j,k)fluorene Benzo(jk)fluorene Benzo[j,k]fluoren Benzo[jk]fluorene Benzo[jk]fluorene, idryl FLUORAN FLUORANTHENE
MDL NumberMFCD00001184
CAS Number206-44-0
PubChem Substance ID9154
EC Number205-912-4
Beilstein Registry Number5(3)2276
Chemical Name Translation荧蒽
Reaxys-RN1907918
Wiswesser Line NotationL C6566 1A PJ
LabNetwork Molecule IDLN00201166
InChIInChI=1S/C16H10/c1-2-8-13-12(7-1)14-9-3-5-11-6-4-10-15(13)16(11)14/h1-10H
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分类

  • {SNA} Arenes, Building Blocks, Chemical Synthesis, Organic Building Blocks
  • {SNA} All PAH Standards, Alphabetical Index of Analytical Standards, Analytical Standards, CRMs, Chromatography, Environmental Standards, F, FA -
  • {SNA} Additional Standards, All PAH Standards, Analytical Standards, CRMs, Certified Reference Materials (CRMs), Chromatography, Environmental Standards, Fluka CRMs for Chromatography (neats), Organic CRMs Alphabetical, Organic CRMs TraceCERT, Organic Pollutant Standards, PAHs, Polyaromatic Hydrocarbons (PAHs), Polycyclic Ar

产品应用

  • 用作非磁性金属表面探伤荧光剂,合成黄色、蓝色还原染料,制造医药等。

相关文献及参考

  • Short: II/27B
  • Short: II/27C
  • Beilstein:5(3)2276

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSLL4025000
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P330 Rinse mouth. 漱口
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard Codes
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R11 Highly flammable 非常易燃
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R38 Irritating to skin 刺激皮肤
  • R50/53
  • R50 Very toxic to aquatic organisms 对水生生物极毒
Packing GroupIII
UN Number
Storage condition APPROX 4°C
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 280 mg/kg/58W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
   Tumorigenic - tumors at site of application
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   56,1237,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#00205

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 156,61,1985

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - rat Embryo
DOSE/DURATION           : 50 mg/L
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   51,799,1973

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 9 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 174,125,1986

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 20 mg/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 6,539,1984

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 2 umol/L
REFERENCE :
   DTESD7 52 Vanderbilt Ave., New York, NY 10017)  V.1-15, 1977-87.
   Discontinued 52 Vanderbilt Ave., New York, NY 10017)  V.1-    1977-
   Volume(issue)/page/year: 10,277,1982

其他信息

  • 可燃性危险特性:可燃; 燃烧产生刺激烟雾
  • 荧蒽价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 F0016 荧蒽 Fluoranthene 25G 311元 2014/06/02 F0016 荧蒽 Fluoranthene 500G 3460元 2010/06/21 119171000 荧蒽 Fluoranthene 98% 100 GR 1131元
  • 用途二:用作非磁性金属表面探伤荧光剂,合成黄色、蓝色还原染料,制造医药等。
  • 方法一:从煤焦油中回收。提取荧蒽的最好原料是Ⅱ蒽油和沥青氧化过程中的馏出物(油类),将这些原料放入间歇式直接火加热的蒸馏,同时往锅内通入少量过热馏锅内,在真空度0.09MPa下进行蒸馏,同时往锅内通入少量过热蒸气。馏出的蒸气经过精馏塔,分凝器和冷却器,冷却到高于熔点的温度,流入受糟,取375-358℃馏出物进行结晶,离心脱油后得到粗荧蒽。粗荧蒽用混合溶剂(30%轻溶剂油和70%乙醇)重结晶即得成品,对375-385℃窄馏分的收率为40%,荧蒽的纯度可达99%。
  • 毒性分级:中毒
  • 类别:腐蚀物品
  • MOL 文件:206-44-0.mol
  • 荧蒽价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 F0016 荧蒽 Fluoranthene 25G 256元 2011/04/16 F0016 荧蒽 Fluoranthene 500G 2850元 2010/06/21 119171000 荧蒽 Fluoranthene 98% 100 GR 1131元
  • 用途一:可用作磁性金属表面探伤荧光剂和用于制合成染料、药物等
  • 储运特性:库房通风低温干燥;与氧化剂分开存放。
  • 急性毒性:口服- 大鼠 LD50: 2000 毫克/ 公斤
  • MSDS 信息:萤蒽(206-44-0).msds
  • Acros Organics:荧蒽 Fluoranthene, 93%(206-44-0)
  • 上游原料:焦油 --> 石油沥青 --> 油类 --> 蒽油 --> 轻溶剂油
  • Sigma Aldrich:206-44-0(sigmaaldrich)
  • 外观性质:黄绿色结晶或无色固体。常温下无臭无味。
  • 灭火剂:砂土、泡沫、雾状水
  • 爆炸物危险特性:对皮肤,角膜有腐蚀性
  • TCI Shanghai:荧蒽 Fluoranthene,>;98.0%(GC)(206-44-0)
  • 常温下无臭无味。可燃,有毒,不溶于水,稍溶于乙醇,可溶于二硫化碳、醋酸,易溶于乙醚、苯类。紫外线下显荧光。

系列性分类


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