(S)-2-amino-3,3-dimethylbutanoic acid L-叔亮氨酸

CAS 20859-02-3 MFCD00064218

化学结构图

20859-02-3
SMILES: CC(C)(C)[C@H](N)C(=O)O

化学属性

Mol. FormulaC6H13NO2
Mol. Weight131.17
Melting Point300°C
TSCANo
Solubility125.5 G/L (20 ºC)
Density1.038
Boiling Point217.7±23.0 °C at 760 mmHg

别名和识别编码

Chemical Name(S)-2-amino-3,3-dimethylbutanoic acid
CAS Number20859-02-3
Alfabeta NameLEUCINE TERTL--
MDL NumberMFCD00064218
Synonym (S)-2-Amino-3,3-dimethylbutanoic acid {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {} {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {} {} {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {} {} {} {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {} {} {} {} {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {} {} {} {} {} {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {} {} {} {} {} {} {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {} {} {} {} {} {} {} {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {} {} {} {} {} {} {} {} {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {} {} {} {} {} {} {} {} {} {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-2-Amino-3,3-dimethylbutanoic acid {} {} {} {} {} {} {} {} {} {} {
EC Number424-750-7
Beilstein Registry Number1721824
PubChem Substance ID164608
Reaxys-RN1721824
Chemical Name TranslationL-叔亮氨酸
InChIInChI=1S/C6H13NO2/c1-6(2,3)4(7)5(8)9/h4H,7H2,1-3H3,(H,8,9)/t4-/m1/s1
LabNetwork Molecule IDLN00008029
Canonical SMILESN[C@@H](C(C)(C)C)C(O)=O
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分类

  • {SNA} Chemical Biology, Chemical Synthesis, Leucine Derivatives, Peptide Chemistry, Unnatural Amino Acid Derivatives

相关文献及参考

  • Beilstein:4(4)2785
  • ɑ-Amino acids have been used in combination with NaBH4 for the asymmetric reduction of ketones. Of a number of amino acids the sterically hindered tert-leucine was found to give the highest ee (95%) in the reduction of the carbonyl group of a 1,5-benzothiazepine intermediate in an efficient synthesis of the calcium antagonist diltiazem: J. Org. Chem., 61, 8586 (1996).

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
GHS Symbol
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

系列性分类

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