Bromophos-methyl 甲基-溴硫磷

CAS 2104-96-3 MFCD00055261

化学结构图

2104-96-3
SMILES: COP(=S)(OC)Oc1cc(Cl)c(Br)cc1Cl

化学属性

Mol. FormulaC8H8BrCl2O3PS
Mol. Weight366.00
Melting Point53-56 °C
Flash Point>100 °C
Solubility微溶于水,溶于苯、乙醚、四氯化碳。
Density1.21
Boiling Point140-142 °C at 760 mmHg

别名和识别编码

Chemical NameBromophos-methyl
Synonym Bromofos {LY} Bromofos {} {LY} Bromofos {} {} {LY} Bromofos {} {} {} {LY} Bromofos {} {} {} {} {LY} Bromofos {} {} {} {} {} {LY} Bromofos {} {} {} {} {} {} {LY} Bromofos {} {} {} {} {} {} {} {LY} Bromofos {} {} {} {} {} {} {} {} {LY} Bromofos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromofos {} {} {} {} {} {} {} {} {} {} {LY} Bromofos {} {} {} {} {} {} {} {} {} {} {} {LY} Bromofos {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromofos {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromofos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromofos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromofos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromofos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromofos {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00055261
CAS Number2104-96-3
EC Number218-277-3
Beilstein Registry Number1988276
Chemical Name Translation甲基-溴硫磷
Wiswesser Line NotationGR DG BE EOPS&O1&O1
PubChem Substance ID16422
InChIInChI=1S/C8H8BrCl2O3PS/c1-12-15(16,13-2)14-8-4-6(10)5(9)3-7(8)11/h3-4H,1-2H3
Canonical SMILESS=P(OC)(OC)OC1=C(Cl)C=C(Br)C(Cl)=C1
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分类

  • {SNA} A-B, Acaricides, Analytical Standards, Bromophos metabolites, Insecticides, Organophorous, 代谢物, 农残和代谢标准品, 农残标准品, 分析/色谱, 按照字母排序
  • {SN
  • {SNA} A-B, Acaricides, Analytical Standards, Bromophos metabolites, Insecticides, Organophorous, 代谢物, 农残和代谢标准品, 分析/色谱, 按照字母排序
  • {SNA} A-B, Acaricides, All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography,

相关文献及参考

  • Short: EINECS
  • Short: IV/8A
  • Merck: 14,1431

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSTE7175000
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P301+P312+P330
Signal word Warning
Hazard Codes Xn;N Xn;N,N,Xn Xn,N
Safety Statements
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S2 Keep out of the reach of children 避免儿童触及;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R50/53
Storage condition 0-6°C 储存温度2-8℃
UN Number UN3077 9/PG 3
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1625 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de
   Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France)
   V.1-  1947-  Volume(issue)/page/year: 32,40,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 3750 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 41(8),82,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   14,515,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >12 gm/kg
TOXIC EFFECTS :
   Behavioral - changes in motor activity (specific assay)
   Skin and Appendages - hair
REFERENCE :
   AJDKA8 Azabu Juika Daigaku Kenkyu Hokoku.  Bulletin of Azabu Veterinary
   College.  (Sagamihara, Japan) No.1-31, 1954-76; V.1-4, 1976-79.
   Volume(issue)/page/year: 30,213,1975

TYPE OF TEST

{ha

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 73200 ug/kg
REFERENCE :
   RTOPDW Regulatory Toxicology and Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1981-  Volume(issue)/page/year:
   6,416,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 293 mg/kg
SEX/DURATION            : female 6-12 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   RTOPDW Regulatory Toxicology and Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1981-  Volume(issue)/page/year:
   6,416,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 293 mg/kg
SEX/DURATION            : female 6-12 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   RTOPDW Regulatory Toxicology and Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1981-  Volume(issue)/page/year:
   6,416,1986

其他信息

  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 类别:农药
  • 毒性分级:中毒
  • 杀虫剂单一组分标准液
  • 急性毒性:口服- 大鼠 LD50: 1600 毫克/ 公斤; 口服- 小鼠 LD50: 2829 毫克/ 公斤
  • 可燃性危险特性:燃烧产生有毒磷氧化物、硫氧化物和氯化物气体
  • Sigma Aldrich:2104-96-3(sigmaaldrich)
  • 职业标准:STEL 0.5 毫克/ 立方米
  • 灭火剂:干粉、泡沫、砂土
  • MOL 文件:2104-96-3.mol
  • MSDS 信息:甲基溴硫磷(2104-96-3).msds
  • 外观性质:淡黄色结晶。

系列性分类


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