D(+)-10-Camphorsulfonyl Chloride D(+)-10-樟脑磺酰氯
CAS 21286-54-4 MFCD00064156
化学结构图
SMILES: CC1(C)[C@H]2CC[C@]1(CS(=O)(=O)Cl)C(=O)C2
化学属性
| Mol. Formula | C10 |
|---|---|
| Mol. Weight | 251 |
| Melting Point | 65-67 |
| TSCA | No |
| Density | 1.331 |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | Camphor-10-sulfonyl chloride |
|---|---|
| CAS Number | 21286-54-4 |
| Synonym | (+)-10-Camphorsulfonic Acid Chloride (+)-Camphor-10-sulfonyl chloride (+)-樟脑-10-磺酰氯 (1S)-(+)-10-樟脑磺酰氯 (1S)-(+)-樟脑－10－磺酰氯 d-Camphorsulfonyl Chlo |
| PubChem Substance ID | 87566043 |
| EC Number | 244-314-8 |
| Beilstein Registry Number | 3205974 |
| MDL Number | MFCD00064156 |
| Reaxys-RN | 525867 |
| Chemical Name Translation | (1S)-(+)-10-樟脑磺酰氯 |
| InChIKey | BGABKEVTHIJBIW-GMSGAONNSA-N |
| LabNetwork Molecule ID | LN00189588 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Organic Building Blocks, Sulfonyl Halides
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Organic Building Blocks, Sulfonyl Halides
产品应用
- A chiral derivative of Camphor
相关文献及参考
- Beil. 11 ,IV,650
- Peng, R., et al.: Biochem. Pharmacol., 35, 1391
- Beilstein:11,316
- Resolving agent for optically-active alcohols: Chem. Pharm. Bull., 23, 1625 (1975). For use as a chiral leaving group, see: J. Chem. Soc., Perkin 1, 634 (1976).
安全信息
GHS Symbol
- H290 May be corrosive to metals 可能腐蚀金属。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
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