(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol (R)-(+)-α,α-二苯基脯氨醇

CAS 22348-32-9 MFCD00077754

化学结构图

22348-32-9
SMILES: OC(c1ccccc1)(c1ccccc1)[C@@H]1CCCN1

化学属性

Mol. FormulaC17H19NO
Mol. Weight253
Melting Point77-80
Density1.422
TSCANo

别名和识别编码

Chemical Name(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol
CAS Number22348-32-9
Alfabeta NameDIPHENYLPYRROLIDINEMETHANOL ALPHAALPHAR+2(())-----,
MDL NumberMFCD00077754
Synonym α,α-二苯基-D-脯氨醇 (R)-2-(二苯基羟甲基)吡咯烷 (R)-(+)-α,α-二苯基脯氨醇 ,-Diphenyl-D-prolinol; (R)-(+)-,-Diphenyl-2-pyrrolidinemethanol alpha,alpha-Diphenyl-D-prolinol; (R)-(+)-alpha,alpha-Diphenyl-2-pyrrolidinemethanol α,α-Diphenyl-D-prolinol; (R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol α,α-二苯基-D-脯氨醇 (R)-2-(二苯基羟甲基)吡咯烷
Beilstein Registry Number4353363
PubChem Substance ID87568801
EC Number250-023-7
Chemical Name Translation(R)-(+)-α,α-二苯基脯氨醇
Reaxys-RN4353363
InChIKeyOGCGXUGBDJGFFY-UHFFFAOYSA-N
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Proline-Based Organocatalysts

产品应用

  • 用于制备对应的噁唑硼烷，噁唑硼烷可用于酮的硼烷介导不对称还原反应。

相关文献及参考

  • Chiral precursor for the asymmetric reduction of ketones, see following entry.

安全信息

Warnings IRRITANT
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
WGK Germany3
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes Xi

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Proline-Based Organocatalysts - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Proline-Based Organocatalysts - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Aromatic alcohols 芳香醇
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes
  5. Solvias Ligands and Complexes
  6. Walphos Ligands

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