tri-n-Propyltin Chloride 三正丙基氯化锡

CAS 2279-76-7 MFCD00013610

化学结构图

2279-76-7
SMILES: CCC[Sn](Cl)(CCC)CCC

化学属性

Mol. Formula(C3H7)3SnCl
Mol. Weight283
Density1.2678^2^8
Refractive index1.4910
Melting Point-23.5°
TSCANo
Boiling Point123°/13mm
Flash Point95°C
Solubility溶于多数有机溶剂。
Stability对湿度敏感

别名和识别编码

Chemical Nametri-n-Propyltin Chloride
Synonym tripropyl-tichloride Tin, chlorotripropyl- Tripropylchlorostannane Tripropyltin chloride Tri-n-propyltinchloride,98+% 三正丙基氯化锡 三丙基氯化锡 Tripropyltin(IV) chloride CHLOROTRIPROPYLSTANNANE Tri-n-propyltin chloride CHLOROTRIPROPYLTIN 三正丙基氯化锡代用品标样 Tripropylstannyl chloride Tin, tripropyl-, chloride Chlortripropylstannan Tripropylchlorstannan TRIPROPYLTIN CHLORIDE 三丙基氯化鍚 氯丙锡 TRIPROPYLCHLOROTIN TRI-N-PROPYLTIN CHLORIDE 氯化三丙锡 Stannane, chlorotripropyl- Tripropylstannylchlorid Chlorotripropyltin(IV) chlorotripropyl-stannan 三丙基锡 Chlorotripropyltin Tripropylzinnchlorid TRIPROPYLSTANNICCHLORIDE Tripropylstannium chloride Chlorotripropylstannane Tri-n-propylzinnchlorid Chlortripropylzinn TRI-N-PROPYLCHLOROTIN
CAS Number2279-76-7
MDL NumberMFCD00013610
EC Number218-910-3
Chemical Name Translation三正丙基氯化锡
Wiswesser Line NotationG-SN-3&3&3
LabNetwork Molecule IDLN02144884
PubChem Substance ID16784
InChIInChI=1S/3C3H7.ClH.Sn/c3*1-3-2;;/h3*1,3H2,2H3;1H;/q;;;;+1/p-1
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分类

  • {uni_hamburg} no charge; metal-organic; 1fragment

相关文献及参考

  • Short: III/35D5 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 5: Organometallic Compounds Author: Mikhova, Bozhana Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D5 Year: 2008 Keyword: Carbon-13; chemical shift; magnetic properties of nuclei; nuclear magnetic resonance data ISBN: 978-3-540-74188-6 (print) ISBN: 978-3-540-74189-3 (electronic) Internet Resource: DOI:10.1007/978-3-540-74189-3 RefComment: VIII, 241 p., Hardcover RefComment: Written for Scientists and engineers in the fields of physics, chemistry and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei 11B and 31P, subvolume III/35B contains the nuclei 19F and 15N, subvolume III/35C contains the nucleus 1H, subvolume III/35D contains the nucleus 13C, subvolume III/35E contains the nucleus 17O, and subvolume III/35G contains the nucleus 77Se. More nuclei will be presented later.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1

安全信息

Packing GroupII
UN Number 2788 UN2788
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R50/53
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S27/28
Storage condition Moisture Sensitive
Hazard Class6.1
Warnings 危化品目录(2015) 危险化学品
RTECSWH6870000 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02220

Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H331 Toxic if inhaled 吸入中毒
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P302+P352
  • P304+P340
  • P307+P311
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

  • 灭火剂:砂土、干粉、泡沫
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 类别:农药
  • 毒性分级:高毒
  • 三正丙基氯化锡代用品标样价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 41459 三正丙基氯化锡, 95% Tri-n-propyltin chloride, 95% 1g 456元 2010/05/25 71122 Tri-n-propyltin chloride 5g 1456元 2010/05/25 71122 Tri-n-propyltin chloride 25g 5404元
  • MSDS 信息:氯丙锡(2279-76-7).msds
  • Alfa Aesar:三正丙基氯化锡,95% Tri-n-propyltin chloride, 95%(2279-76-7)
  • MOL 文件:2279-76-7.mol
  • 外观性质:无色液体。
  • TSCA:No
  • 敏感性:Moisture Sensitive
  • 急性毒性:口服-小鼠 LD50: 109 毫克/公斤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organotin 有机锡

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