(2-Hydroxyethyl)Triphenylphosphonium Chloride (2-羟基乙基)三苯基氯化鏻

CAS 23250-03-5 MFCD00011754

化学结构图

23250-03-5
SMILES: [Cl-].OCC[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaHOCH2CH2P(C6H5)3Cl
Mol. Weight342.80
Melting Point234-235 °C (dec.)(lit.)

别名和识别编码

Chemical Name(2-Hydroxyethyl)Triphenylphosphonium Chloride
Beilstein Registry Number3922778
PubChem Substance ID24878811
CAS Number23250-03-5
EC Number245-521-6
MDL NumberMFCD00011754
Synonym 氯化(2-羟乙基)三苯基磷
Chemical Name Translation(2-羟基乙基)三苯基氯化鏻
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. Gautam, D. R.; et al. J. Heterocycl. Chem. 40 , 399, (2003)
  • Aldrich MSDS 1 , 1060:A / Corp MSDS 1 (1), 1924:D / FT-IR 2 (2), 3332:C / FT-IR 1 (2), 546:D / FT-NMR 1 (2), 1672:A / RegBook 1 (2), 2275:H / Structure Index 1 , 356:D:3
  • Beil. 16 ,IV,986

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination

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