4-Bromo-2-fluoroanisole 4-溴-2-氟苯甲醚

CAS 2357-52-0 MFCD00011710

化学结构图

2357-52-0
SMILES: COc1ccc(Br)cc1F

化学属性

Mol. FormulaC7H6BrFO
Mol. Weight205.02
Boiling Point215.1°C at 760 mmHg
Density1.59
Refractive index1.5430 to 1.5460
Flash Point98°C
TSCANo
Melting Point16°C
Solubility不溶
Appearance 4-溴-2-氟苯甲醚(2357-52-0)为无色透明液体。相对密度1.590。熔点16℃，沸点84℃，折光率 n 20/D 1.545， 闪点209 ;°F

别名和识别编码

Chemical Name4-Bromo-2-fluoroanisole
CAS Number2357-52-0
Alfabeta NameBROMOFLUOROANISOLE 42---
MDL NumberMFCD00011710
EC Number219-096-2
Beilstein Registry Number3240714
Synonym 4-Bromo-2-fluoroanisole {LY} 4-Bromo-2-fluoroanisole {} {LY} 4-Bromo-2-fluoroanisole {} {} {LY} 4-Bromo-2-fluoroanisole {} {} {} {LY} 4-Bromo-2-fluoroanisole {} {} {} {} {LY} 4-Bromo-2-fluoroanisole {} {} {} {} {} {LY} 4-Bromo-2-fluoroanisole {} {} {} {} {} {} {LY} 4-Bromo-2-fluoroanisole {} {} {} {} {} {} {} {LY} 4-Bromo-2-fluoroanisole {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-fluoroanisole {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-fluoroanisole {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-fluoroanisole {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-fluoroanisole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-fluoroanisole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-fluoroanisole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-fluoroanisole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID75378
Chemical Name Translation4-溴-2-氟苯甲醚
Reaxys-RN3240714
InChIKeyDWNXGZBXFDNKOR-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008422
InChIInChI=1S/C7H6BrFO/c1-10-7-3-2-5(8)4-6(7)9/h2-4H,1H3
Canonical SMILESCOC1=CC=C(Br)C=C1F
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分类

  • {SNA} Aryl Fluorinated Building Blocks, Building Blocks, C2 to C7, C7, Chemical Synthesis, Ethers, Fluorinated Building Blocks, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • Beilstein:6(4)1057

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • TCI Shanghai:4-溴-2-氟苯甲醚 4-Bromo-2-fluoroanisole,>;98.0%(GC)(2357-52-0)
  • Acros Organics:4-溴-2-氟茴香醚 4-Bromo-2-fluoroanisole, 99+%(2357-52-0)
  • 图谱信息:4-溴-2-氟苯甲醚(2357-52-0)核磁图( 1 HNMR) 4-溴-2-氟苯甲醚(2357-52-0)核磁图( 13 CNMR) 4-溴-2-氟苯甲醚(2357-52-0)质谱(MS) 4-溴-2-氟苯甲醚(2357-52-0)红外图谱(IR1)
  • Sigma Aldrich:2357-52-0(sigmaaldrich)
  • Hazard Note:Irritant
  • 4-溴-2-氟苯甲醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1855 4-溴-2-氟苯甲醚 4-Bromo-2-fluoroanisole 5G 430元 2014/06/02 B1855 4-溴-2-氟苯甲醚 4-Bromo-2-fluoroanisole 25G 1260元 2010/06/21 249880050 4-溴-2-氟苯甲醚 4-Bromo-2-fluoroanisole 99+% 5 ML 509元
  • MSDS 信息:4-Bromo-2-fluoroanisole(2357-52-0).msds
  • Alfa Aesar:4-溴-2-氟苯甲醚,97% 4-Bromo-2-fluoroanisole, 97%(2357-52-0)
  • MOL 文件:2357-52-0.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Other Fluorinated Organic Building Blocks - Organic Fluorinated Building Blocks
  6. Aryl Fluorinated Building Blocks 芳基氟化物
  7. C7 - Aryl Fluorinated Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  6. C2 to C8 - Ethers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides

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