Cyclopropylmagnesium bromide 环丙基溴化镁

CAS 23719-80-4 MFCD00672094

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H96998
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 100mL ¥ 160
库存 辽宁
中国国内现货 0.5 M solution 四氢呋喃
INFI H96998
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 500mL ¥ 490
0.5 M solution 四氢呋喃
INFI H96998
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 1L ¥ 780
0.5 M solution 四氢呋喃
INFI H92936
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in THF, SpcSeal 100mL ¥ 240
库存 辽宁 保定市
中国国内现货 1.0 M solution 四氢呋喃
INFI H92936
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in THF, SpcSeal 500mL ¥ 750
1.0 M solution 四氢呋喃
INFI H92936
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in THF, SpcSeal 1L ¥ 1,210
1.0 M solution 四氢呋喃
INFI H36785
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in 2-Methyl-THF, SpcSeal 100mL ¥ 240
库存 辽宁
中国国内现货 0.5 M solution 二甲基四氢呋喃
INFI H36785
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in 2-Methyl-THF, SpcSeal 500mL ¥ 640
库存 辽宁
中国国内现货 0.5 M solution 二甲基四氢呋喃
INFI H36785
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in 2-Methyl-THF, SpcSeal 1L ¥ 1,080
库存 辽宁
中国国内现货 0.5 M solution 二甲基四氢呋喃
INFI H68833
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 100mL ¥ 320
0.5 M solution 四氢呋喃
INFI H68833
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 500mL ¥ 820
0.5 M solution 四氢呋喃
INFI H68833
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 800mL ¥ 1,120
0.5 M solution 四氢呋喃
INFI H86451
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in 2-Methyl-THF, SpcSeal 100mL ¥ 250
库存 辽宁
中国国内现货 1.0 M solution 二甲基四氢呋喃
INFI H86451
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in 2-Methyl-THF, SpcSeal 500mL ¥ 860
库存 辽宁
中国国内现货 1.0 M solution 二甲基四氢呋喃
Innochem C4100
Cyclopropylmagnesium bromide, 1.0 M solution in THF, in resealable bottle
100mL ¥ 270
1.0 M solution 四氢呋喃
Innochem C4100
Cyclopropylmagnesium bromide, 1.0 M solution in THF, in resealable bottle
500mL ¥ 1,120
1.0 M solution 四氢呋喃
Innochem C4100
Cyclopropylmagnesium bromide, 1.0 M solution in THF, in resealable bottle
800mL ¥ 1,540
1.0 M solution 四氢呋喃
Innochem C4101
100mL ¥ 320
Innochem C4101
500mL ¥ 820
Innochem C4101
800mL ¥ 1,120
Alfa H26273
Cyclopropylmagnesium bromide
0.5M-0.7M in THF 25mL ¥ 946
库存 上海市 北京 China, PRC
中国国内现货 0.5 M solution THF
Alfa H26273
Cyclopropylmagnesium bromide
0.5M-0.7M in THF 100mL ¥ 2,586
库存 上海市 北京 China, PRC
中国国内现货 0.5 M solution THF
TCI C2039
Cyclopropylmagnesium Bromide (ca. 10% in Tetrahydrofuran, ca. 0.7mol/L)
100g ¥ 1,200
库存 上海市 Tokyo, Japan
中国国内现货 10+ % solution THF
Alfa H51158
Cyclopropylmagnesium bromide, 0.5M in MeTHF
N/A 50mL ¥ 1,806
库存 上海市 北京
中国国内现货 0.5 M solution 四氢呋喃
Alfa H51158
Cyclopropylmagnesium bromide, 0.5M in MeTHF
N/A 100mL ¥ 2,884
库存 上海市 北京
中国国内现货 0.5 M solution 四氢呋喃
Alfa H66668
1.0M in 2-MeTHF 25mL ¥ 862
库存 上海市 北京
中国国内现货 1.0 M solution 四氢呋喃
Alfa H66668
1.0M in 2-MeTHF 100mL ¥ 2,421
1.0 M solution 四氢呋喃
J&K 615371
Cyclopropylmagnesium bromide, 0.5 M solution in THF, J&KSeal;
N/A 100mL ¥ 286
库存 HB
中国国内现货 0.5 M solution THF
J&K 615371
Cyclopropylmagnesium bromide, 0.5 M solution in THF, J&KSeal;
N/A 500mL ¥ 1,425
库存 HB
中国国内现货 0.5 M solution THF
J&K 992504
Cyclopropylmagnesium bromide, 1.0 M solution in 2-MeTHF, J&KSeal;
N/A 25mL ¥ 1,189
库存 HB
中国国内现货 1.0 M solution 四氢呋喃
J&K 992504
Cyclopropylmagnesium bromide, 1.0 M solution in 2-MeTHF, J&KSeal;
N/A 100mL ¥ 3,336
库存 HB
中国国内现货 1.0 M solution 四氢呋喃
Acros 39761
Cyclopropylmagnesium bromide, 0.5M solution in THF, AcroSeal?
0.5M solution in THF, AcroSeal® 100mL ¥ 1,415
库存 上海市 China, PRC
中国国内现货 0.5 M solution THF
Aldrich 772844
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran 1.0?M in 2-methyltetrahydrofuran 25mL ¥ 1,218
1.0 M solution 2-Methyl-THF
Aldrich 772844
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran 1.0?M in 2-methyltetrahydrofuran 100mL ¥ 3,415
1.0 M solution 2-Methyl-THF
Energy-chemical E080310
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0mol/L in THF,EnergySeal 100mL ¥ 295
库存 上海市 北京市
中国国内现货 1.0 M solution THF
Energy-chemical E080310
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0mol/L in THF,EnergySeal 500mL ¥ 845
库存 上海市 北京市
中国国内现货 1.0 M solution THF
Energy-chemical E080310
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0mol/L in THF,EnergySeal 1L ¥ 1,570
库存 上海市
中国国内现货 1.0 M solution THF
Aladdin C115964
Cyclopropylmagnesium Bromide 环丙基溴化镁
1mol/L in THF 25mL ¥ 790
库存 上海市
中国国内现货 1.0 M solution 四氢呋喃
Aladdin C115964
Cyclopropylmagnesium Bromide 环丙基溴化镁
1mol/L in THF 100mL ¥ -
库存 上海市
中国国内现货 1.0 M solution 四氢呋喃
Aladdin C115964
Cyclopropylmagnesium Bromide 环丙基溴化镁
1mol/L in THF 500mL ¥ -
库存 上海市
中国国内现货 1.0 M solution 四氢呋喃
Aladdin C115964
Cyclopropylmagnesium Bromide 环丙基溴化镁
1mol/L in THF 1L ¥ -
1.0 M solution 四氢呋喃
Acros 445958000
AcroSeal? 800mL ¥ 4,270
Shao Yuan SY015564
0.5MinTHF 500mL ¥ 1,937
HY Y34678
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
0.5 M solution in THF, HySeal 100mL ¥ -
0.5 M solution THF
HY Y34678
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
0.5 M solution in THF, HySeal 500mL ¥ -
0.5 M solution THF
HY Y34678
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
0.5 M solution in THF, HySeal 800mL ¥ -
0.5 M solution THF
HY Y32682
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M solution in THF, HySeal 100mL ¥ -
1.0 M solution THF
HY Y32682
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M solution in THF, HySeal 500mL ¥ -
1.0 M solution THF
HY Y32682
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M solution in THF, HySeal 800mL ¥ -
1.0 M solution THF
Adamas 39897F
1.0 M solution in THF, SafeSeal 100mL ¥ 290
库存 上海市 北京
中国国内现货 1.0 M solution THF
Adamas 39897D
0.5 M solution in THF, SafeSeal 500mL ¥ 855
0.5 M solution THF
Adamas 39897E
0.5 M solution in THF, SafeSeal 800mL ¥ 1,230
0.5 M solution THF
Adamas 39897H
1.0 M solution in THF, SafeSeal 800mL ¥ 1,700
1.0 M solution THF
Adamas 39897G
1.0 M solution in THF, SafeSeal 500mL ¥ 980
1.0 M solution THF
Adamas 39897C
0.5 M solution in THF, SafeSeal 100mL ¥ 195
库存 上海市 北京 China, PRC
中国国内现货 0.5 M solution 四氢呋喃
HY Y21389
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran 25mL ¥ -
1.0 M solution 2-Methyl-THF
HY Y21389
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran 100mL ¥ -
1.0 M solution 2-Methyl-THF
HY Y29660
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran HySeal 25mL ¥ -
1.0 M solution 2-Methyl-THF
HY Y29660
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran HySeal 100mL ¥ -
1.0 M solution 2-Methyl-THF
HY Y29660
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran HySeal 500mL ¥ -
1.0 M solution 2-Methyl-THF
HY Y29660
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran HySeal 800mL ¥ -
1.0 M solution 2-Methyl-THF
Meryer M11439
环丙基溴化镁
1mol/L THF溶液 100mL ¥ 569
1.0 M solution 四氢呋喃
Meryer M11439
环丙基溴化镁
1mol/L THF溶液 500mL ¥ 1,511
1.0 M solution 四氢呋喃
Acros C4459
100mL ¥ 857
Energy-chemical W420056
Cyclopropylmagnesium bromide 环丙基溴化镁
100mL ¥ 198
库存 上海市 北京市
中国国内现货
Energy-chemical W420056
Cyclopropylmagnesium bromide 环丙基溴化镁
500mL ¥ 545
库存 上海市
中国国内现货
Energy-chemical W420056
Cyclopropylmagnesium bromide 环丙基溴化镁
1L ¥ 975
库存 上海市
中国国内现货
3A A11067
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in THF, SpcSeal 100ml ¥ 260
1.0 M solution THF
3A A11067
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in THF, SpcSeal 500ml ¥ 750
1.0 M solution THF
3A A11067
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in THF, SpcSeal 1L ¥ 1,320
1.0 M solution THF
3A A11083
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 100ml ¥ 180
0.5 M solution THF
3A A11083
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 500ml ¥ 490
0.5 M solution THF
3A A11083
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 1L ¥ 850
0.5 M solution THF
3A A11377
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in 2-Methyl-THF, SpcSeal 100ml ¥ 240
0.5 M solution 2-Methyl-THF
3A A11377
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in 2-Methyl-THF, SpcSeal 500ml ¥ 690
库存 北京
中国国内现货 0.5 M solution 2-Methyl-THF
3A A11377
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in 2-Methyl-THF, SpcSeal 1L ¥ 1,180
0.5 M solution 2-Methyl-THF
Aladdin C115964-100ml
100mL ¥ 599
库存 上海市 北京
中国国内现货
Aladdin C115964-500ml
500mL ¥ 845
库存 上海市 北京
中国国内现货
Acros 445951000
100mL ¥ 818
库存 北京
中国国内现货
Acros 397611000
100mL ¥ 946
库存 北京
中国国内现货
Aladdin C137862-25ml
25mL ¥ 359
库存 北京
中国国内现货
Aldrich 772844-25ML
25mL ¥ 1,318
Aldrich 526797-100ML
100mL ¥ 3,215
Aldrich 772844-100ML
100mL ¥ 3,695
Aldrich 526797-800ML
800mL ¥ 19,718
Matrix 121744
50mL ¥ 5,395
Matrix 121744
100mL ¥ 7,362
Matrix 121744
500mL ¥ 14,031
Aladdin C137862-100ml
100mL ¥ 999
Aladdin C137862-500ml
500mL ¥ 3,499
Aladdin C115964-1L
1L ¥ 1,570

分类

  • {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
  • {SNA} 12 Principles Aligned Products, Alkyl, Chemical Synthesis, Greener Alternative Products, Grignard Reagents, Organometallic Reagents, Synthetic Reagents

产品应用

  • ⑴. 由于镁原子直接和碳链相连,极化作用使邻近镁原子的那个碳原子呈负电性,使得C-Mg键极具反应活性。为了保证该产品不发生其他反应,反应一般在醚类溶剂里进行,常用的有乙醚或四氢呋喃。 ⑵. 有强烈的亲核性质,可与物质中的活泼氢(如水、乙醇的羟基氢、乙炔的末端氢)反应,生成相应的烃基。 ⑶. 与CO2或O2的反应,可以与二氧化碳或氧气发生亲核加成反应生成增加一个碳的羧酸或同碳数的过氧化合物.格氏试剂与二氧化碳的加成反应在有机合成中也有着重要的意义,不仅通过生成新的 C-C 键实现了碳链的增长,而且恰到好处地

安全信息

WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Packing GroupI
UN Number
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
Storage condition
  • Air & Moisture Sensitive
  • 储存温度2-8℃,充氩保存
Signal word
GHS Symbol
Precautionary statements
  • P210261280305+351+338
  • P335+334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. 刷掉皮肤松散颗粒。浸入冷水中/用湿绷带包扎
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P305+351+338+310
  • P305+351
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P231+232 Handle under inert gas. Protect from moisture. 在惰性气体中。防止受潮。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P210231+232280305+351+338310422
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
Hazard Codes
  • F,C
  • F,Xi
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302 Harmful if swallowed 吞食有害
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
Hazard Class4.3/3

其他信息

  • ⑴. 该品在启用过程中应最大限度的隔绝空气和水份,密封保存在低温、干燥,有氮气保护的容器中。 ⑵.不宜长时间存放。

化学结构图

CAS 23719-80-4  MFCD00672094
SMILES: Br[Mg]C1CC1

化学属性

Mol. FormulaC3H5BrMg
Mol. Weight145.28
Density1.022
Boiling Point65
Flash Point-17°C(lit.)
TSCANo
Stability空气及湿度敏感

别名和识别编码

Chemical NameCyclopropylmagnesium bromide
MDL NumberMFCD00672094
PubChem Substance ID87558777
CAS Number23719-80-4
EC Number250-023-7
Beilstein Registry Number2384789
Synonym
  • Cyclopropylmagnesium Bromide, 0.5 M in Tetrahydrofuran
  • Cyclopropylmagnesium Bromide 0.75 M In Tetrahydrofuran
  • Cyclopropylmagnesium Bromide (15% in Tetrahydrofuran, ca. 1mol/L)
  • 环丙基溴化镁 溶液
  • Cyclopropylmagnesium bromide, ca 0.5M in THF
  • 环丙基溴化镁, 0.5M于THF中
  • Cyclopropylbromomagnesium
  • CYCLOPROPYLMAGNESIUM BROMIDE
  • CYCLOPROPYLMAGNESIUM BROMIDE, 0.5 M IN THF
  • 环丙基溴化镁
  • Bromocyclopropylmagnesium
  • cyclopropylmagnesium bromide solution
    Reaxys-RN3647938
    Chemical Name Translation环丙基溴化镁
    LabNetwork Molecule IDLN01314448

    系列性分类


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