Ethylmagnesium Chloride 乙基氯化镁

CAS 2386-64-3 MFCD00000472

化学结构图

2386-64-3
SMILES: CC[Mg]Cl

化学属性

Mol. FormulaC2H5ClMg
Mol. Weight88.82
Density0.978
Solubility起反应
Flash Point1 °F
Appearance liq.
Stabilityair sensitive, moisture sensitive

别名和识别编码

Chemical NameEthylmagnesium Chloride
CAS Number2386-64-3
EC Number250-023-7
Beilstein Registry Number3647886
MDL NumberMFCD00000472
PubChem Substance ID87569432
Synonym Ethyl magnesium chloride,2.0M solution in THF,Safeseal {LY} Ethyl magnesium chloride,2.0M solution in THF,Safeseal Ethylmagnesium Chloride (18% in Tetrahydrofuran, ca. 2mol/l) Ethylmagnesium Chloride 2.0 M In Diethyl Ether Ethylmagnesium Chloride 2.0 M In Tetrahydrofuran Ethylmagnesium chloride, 1-2M in ether Ethylmagnesium chloride, 2.0M solution in THF Ethylmagnesium chloride, 25 wt% solution in THF Ethylmagnesium chloride, 2m solution in THF {} {LY} Ethyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {LY} Ethyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {LY} Ethyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {LY} Ethyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {} {LY} Ethyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {} {} { {} {} {} {} {} {} {LY} Ethyl magnesium chloride,2.0M soluti
Reaxys-RN3910296
Chemical Name Translation乙基氯化镁
InChIKeyZWNJJACKPNTXHY-UHFFFAOYSA-M
LabNetwork Molecule IDLN00224846
Canonical SMILESCC[Mg]Cl
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分类

  • {SNA} Acids & Bases, Alkyl, Bases, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents
  • {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents

相关文献及参考

  • Beilstein: 4,656

安全信息

Signal word Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S12 Do not keep the container sealed 不要将容器密封；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R12 Extremely flammable 极端易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P305+P351+P338+P310
  • P335+P334
  • P370+P378
  • P402+P404
  • P403+P233
  • P403+P235
  • P422 Store contents under… 存储目录在…之下。
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 4.3 F+,C,F F,C
UN Number 3399
Packing GroupI
Hazard Class4.3/3
Storage condition -20°C {LY} -20°C {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Restrict 危险品

其他信息

  • Sigma Aldrich:2386-64-3(sigmaaldrich)
  • 下游产品:四氢芳樟醇 --> 异维 A 酸 --> 4-(2,6,6-三-甲基3-环己烯-1-基)2-丁烯-1-酮
  • 乙基氯化镁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0135 乙基氯化镁(18%的四氢呋喃溶液,约2mol/L) Ethylmagnesium Chloride (18% in Tetrahydrofuran, ca. 2mol/L) 250G 220元 2010/06/21 252578000 乙基氯化镁 Ethylmagnesium chloride , 2.7M (25 wt.%) solution in THF, AcroSeal® 800 ML 1914元 2010/06/21 252570024 乙基氯化镁 Ethylmagnesium chloride , 2.7M (25 wt.%) solution in THF, AcroSeal® 2.4 LT 4893元
  • Acros Organics:乙基氯化镁 Ethylmagnesium chloride, 2.0M solution in THF, AcroSeal?(2386-64-3)
  • 存储注意事项:湿度敏感;惰性气体保护
  • F:1-3-10
  • TCI Shanghai:乙基氯化镁(18%的四氢呋喃溶液,约2mol/L) Ethylmagnesium Chloride (18% in Tetrahydrofuran, ca. 2mol/L)(2386-64-3)
  • MOL 文件:2386-64-3.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Organic Acids - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Salts - Synthetic Reagents
  4. Potassium - Inorganic Salts
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Grignard Reagents & Alkyl Metals
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents
  1. Analytical & Chromatography 分析化学与色谱
  2. Inorganic Salts
  3. Others
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkenyl
  1. Functional Group 官能团索引
  2. organomagnesium compound
  1. Grignard
  2. Magnesium

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