Benzene, 1-​bromo-​3-​methoxy- 间溴苯甲醚

CAS 2398-37-0 MFCD00000081

化学结构图

2398-37-0
SMILES: COc1cccc(Br)c1

化学属性

Mol. FormulaC7H7BrO
Mol. Weight187.04
Density1.477
Refractive index1.5620 to 1.5650
Boiling Point210.5°C at 760 mmHg
Flash Point98°C
TSCAYes
Melting Point2°C
Appearance 浅黄色油状液体。沸点210-211℃（100kPa），105℃（2.13kPa），相对密度1.477，折光率1.5635，闪点93℃。溶于醇、醚、苯和二硫化碳，不溶于水。
pH:A

别名和识别编码

Chemical NameBenzene, 1-​bromo-​3-​methoxy-
CAS Number2398-37-0
EC Number219-264-5
Beilstein Registry Number1524687
MDL NumberMFCD00000081
Reaxys-RN1524687
PubChem Substance ID87563564
Synonym 1-Bromo-3-methoxybenzene {LY} 1-Bromo-3-methoxybenzene {} {LY} 1-Bromo-3-methoxybenzene {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {} {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {} {} {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {} {} {} {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3-methoxybenzene {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation间溴苯甲醚
LabNetwork Molecule IDLN00196620
Canonical SMILESCOC1=CC(Br)=CC=C1
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分类

  • {SNA} Building Blocks, C2 to C7, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds
  • Aromatics
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ether; 1fragment

产品应用

  • 有机合成原料。

相关文献及参考

  • Beilstein:6,198
  • Short: II/24B
  • Short: II/27B

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Hazard Codes Xi
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 溶于醇、醚、苯和二硫化碳，不溶于水。
  • 用途一:用于有机合成
  • Alfa Aesar:3-溴苯甲醚,98+% 3-Bromoanisole, 98+%(2398-37-0)
  • 下游产品:盐酸曲马多 --> 2-氯-5-甲氧基苯硼酸 --> 3-甲氧基苯硼酸 --> 曲马多
  • 上游原料:甲醇 --> 硫酸 --> 溴 --> 苯 --> 氢 --> 溴酸钠 --> 间溴苯酚
  • 间溴苯甲醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B0545 3-溴苯甲醚 3-Bromoanisole 25G 451元 2011/04/16 B0545 3-溴苯甲醚 3-Bromoanisole 250G 2250元 2010/06/21 106621000 间溴苯甲醚 3-Bromoanisole 99+% 100 ML 1839元
  • Sigma Aldrich:2398-37-0(sigmaaldrich)
  • TSCA:T
  • 间溴苯甲醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0545 3-溴苯甲醚 3-Bromoanisole 25G 325元 2014/06/02 B0545 3-溴苯甲醚 3-Bromoanisole 250G 1720元 2010/06/21 106621000 间溴苯甲醚 3-Bromoanisole 99+% 100 ML 1839元
  • MOL 文件:2398-37-0.mol
  • 图谱信息:间溴苯甲醚(2398-37-0)核磁图( 13 CNMR) 间溴苯甲醚(2398-37-0)Raman光谱 间溴苯甲醚(2398-37-0)质谱(MS) 间溴苯甲醚(2398-37-0)红外图谱(IR2) 间溴苯甲醚(2398-37-0)红外图谱(IR1)
  • 海关编码:29093038
  • Hazard Note:Irritant
  • TCI Shanghai:3-溴苯甲醚 3-Bromoanisole,>;98.0%(GC)(2398-37-0)
  • MSDS 信息:1-Bromo-3-methoxybenzene(2398-37-0).msds
  • Acros Organics:3-溴茴香醚/间溴苯甲醚 3-Bromoanisole, 99+%(2398-37-0)
  • F:8
  • 方法一:由间溴苯酚与硫酸二甲酯反应而得。将间溴苯酚溶解在氢氧化钠溶液中，搅拌下慢慢滴加硫酸二甲酯，加热反应1h，冷却分层无色油状物。水层用乙醚提取，干燥，蒸馏回收乙醚，将残余物和油状物减压蒸馏即得成品。产率90%。
  • 用途二:有机合成原料。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  6. C2 to C8 - Ethers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Biochemicals Found in Plants
  4. Lipids
  5. Oils
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Nutrition Research
  4. Biochemicals Found in Plants
  5. Lipids
  6. Oils
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Lipids
  4. Fatty Acids
  5. Unsaturated fatty acids and derivatives
  6. Monoenoic fatty acids
  7. Others