1,4-Bis(oxiran-2-ylmethoxy)butane 1,4-丁二醇二缩水甘油醚

CAS 2425-79-8 MFCD00005146

化学结构图

2425-79-8
SMILES: C(CCOCC1CO1)COCC1CO1

化学属性

Mol. FormulaC10H18O4
Mol. Weight202.25
Refractive index1.4510 to 1.4550
Boiling Point266°C at 760 mmHg
Density1.1
Flash Point140°C
TSCAYes
Vapor Pressure~10 mmHg ( 20 °C)
Solubility可溶
Stability易吸潮
Melting Point-21.49°C

别名和识别编码

Chemical Name1,4-Bis(oxiran-2-ylmethoxy)butane
CAS Number2425-79-8
PubChem Substance ID87563920
EC Number219-371-7
Beilstein Registry Number115238
MDL NumberMFCD00005146
Reaxys-RN115238
Synonym 1,4-Bis(oxiran-2-ylmethoxy)butane {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {} {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {} {} {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {} {} {} {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {} {} {} {} {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {} {} {} {} {} {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {} {} {} {} {} {} {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {} {} {} {} {} {} {} {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {} {} {} {} {} {} {} {} {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Bis(oxiran-2-ylmethoxy)butane {} {} {} {} {} {}
Chemical Name Translation1,4-丁二醇二缩水甘油醚
Wiswesser Line NotationT3OTJ B1O4O1- BT3OTJ
LabNetwork Molecule IDLN00225284
InChIInChI=1S/C10H18O4/c1(3-11-5-9-7-13-9)2-4-12-6-10-8-14-10/h9-10H,1-8H2
Canonical SMILESC1(COCCCCOCC2OC2)OC1
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分类

  • {SNA} Epoxide Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Epoxide Monomers, Materials Science, Monomers, Polymer Science

相关文献及参考

  • Beilstein: 17,V,3,23

安全信息

GHS Symbol
WGK Germany1
Hazard Codes Xn
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H302+H312+H332
  • H302+H312
  • H332 Harmful if inhaled 吸入有害
  • H312 Harmful in contact with skin 皮肤接触有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSEJ5100000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352
  • P302+P352+P312+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Risk Statements
  • R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R52/53
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Storage condition 2-8°C {LY} 2-8°C Hygroscopic {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 32960 mg/kg/2Y-I
TOXIC EFFECTS :
   Nutritional and Gross Metabolic - dehydration
   Skin and Appendages - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0571421

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1134 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Behavioral - somnolence (general depressed activity)
   Skin and Appendages - hair
REFERENCE :
   TSCAT* Office of Toxic Substances Report.  (U.S. Environmental Protection
   Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460)
   Volume(issue)/page/year: OTS0206386

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1100 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555389

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1130 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 20,390,1959

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >250 ppm/6H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555389

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 300 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 231,205,1990

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 172,105,1986

TYPE OF TEST            : Heritable translocation test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 28 ppb
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   23,51,1994

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 28400 ppm
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   23,51,1994

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 6250 nmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 249,55,1991

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 100 mg/kg
REFERENCE :
   BJPCAL British Journal of Pharmacolo

其他信息

  • Sigma Aldrich:2425-79-8(sigmaaldrich)
  • 可燃性危险特性:热分解排出有毒辛辣刺激烟雾
  • 急性毒性:口服-大鼠 LD50: 1134 毫克/公斤
  • 图谱信息:1,4-丁二醇二缩水甘油醚(2425-79-8)核磁图( 1 HNMR) 1,4-丁二醇二缩水甘油醚(2425-79-8)Raman光谱 1,4-丁二醇二缩水甘油醚(2425-79-8)质谱(MS) 1,4-丁二醇二缩水甘油醚(2425-79-8)核磁图( 13 CNMR) 1,4-丁二醇二缩水甘油醚(2425-79-8)红外图谱(IR1)
  • 类别:有毒物质
  • Acros Organics:1,4-丁二醇二缩水甘油醚 1,4-Butanediol diglycidyl ether, tech., 50-60%(2425-79-8)
  • MOL 文件:2425-79-8.mol
  • 毒性分级:中毒
  • F:3-10
  • 蒸气压:~10 mm Hg ( 20 °C)
  • 储运特性:库房通分, 低温, 干燥
  • TCI Shanghai:1,4-丁二醇二缩水甘油醚 1,4-Butanediol Diglycidyl Ether,>;90.0%(GC)(2425-79-8)
  • 刺激数据:皮肤-兔 10 毫克/24小时 中度; 眼睛-兔 100 毫克 中度
  • Alfa Aesar:1,4-丁二醇二缩水甘油醚,96% 1,4-Butanediol diglycidyl ether, 96%(2425-79-8)
  • 灭火剂:水, 干粉, 沙土, 二氧化碳, 泡沫
  • 1,4-丁二醇二缩水甘油醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0964 1,4-丁二醇二缩水甘油醚 1,4-Butanediol Diglycidyl Ether 25ML 495元 2014/06/02 B0964 1,4-丁二醇二缩水甘油醚 1,4-Butanediol Diglycidyl Ether 250ML 2980元 2010/06/21 154310025 1,4-丁二醇二缩水甘油醚 1,4-Butanediol diglycidyl ether 50-60%, tech. 2.5 KG 4960元
  • MSDS 信息:1,4-Butanediol diglycidyl ether(2425-79-8).msds

系列性分类


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