(S)-2,6-Bis-tert-butoxycarbonylaminohexanoic acid (S)-2,6-二叔丁氧羰基氨基己酸
CAS 2483-46-7 MFCD00038515
化学结构图
SMILES: CC(C)(C)OC(=O)NCCCC[C@H](NC(=O)OC(C)(C)C)C(=O)O
化学属性
| Mol. Formula | C16H30N2O6 |
|---|---|
| Mol. Weight | 346.42 |
| Density | 1.109 |
| Solubility | Soluble in Chloroform, Ether, Ethyl Acetate and Methanol |
| Boiling Point | 514°C at 760 mmHg |
| Melting Point | 65 °C |
别名和识别编码
| Chemical Name | (S)-2,6-Bis-tert-butoxycarbonylaminohexanoic acid |
|---|---|
| CAS Number | 2483-46-7 |
| Synonym | (S)-2,6-Bis((tert-butoxycarbonyl)amino)hexanoic acid {LY} (S)-2,6-Bis((tert-butoxycarbonyl)amino)hexanoic acid {} {LY} (S)-2,6-Bis((tert-butoxycarbonyl)amino)hexanoic acid {} {} {LY} (S)-2,6-Bis((tert-butoxycarbonyl)amino)hexanoic acid {} {} {} {LY} (S)-2,6-Bis((tert-butoxycarbonyl)amino)hexanoic acid {} {} {} {} {LY} (S)-2,6-Bis((tert-butoxycarbonyl)amino)hexanoic acid {} {} {} {} {} {LY} (S)-2,6-Bis((tert-butoxycarbonyl)amino)hexanoic acid {} {} {} {} {} {} {LY} (S)-2,6-Bis((tert-butoxycarbonyl)amino)hexanoic acid {} {} {} {} {} {} {} {LY} (S)-2,6-Bis((tert-butoxycarbonyl)amino)hexanoic acid {} {} {} {} {} {} {} {} {LY} (S)-2,6-Bis((tert-butoxycarbonyl)amino)hexanoic acid {} {} {} {} {} {} {} {} {} {LY} (S)-2,6-Bis((tert-butoxycarbonyl)amino)hexanoic acid {} {} {} {} {} {} {} {} {} {} {LY} (S)-2,6-Bis((tert-butoxycarbonyl)amino)hexanoic acid {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-2,6-Bis((tert-butoxycarbonyl)amino)hexanoic acid {} {} {} {} {} {} {} {} {} {} {} |
| MDL Number | MFCD00038515 |
| Chemical Name Translation | (S)-2,6-二叔丁氧羰基氨基己酸 |
| LabNetwork Molecule ID | LN00241118 |
| PubChem Substance ID | 7349648 |
| Canonical SMILES | O=C(O)[C@H](CCCCNC(OC(C)(C)C)=O)NC(OC(C)(C)C)=O |
| InChI | InChI=1S/C16H30N2O6/c1-15(2,3)23-13(21)17-10-8-7-9-11(12(19)20)18-14(22)24-16(4,5)6/h11H,7-10H2,1-6H3,(H,17,21)(H,18,22)(H,19,20)/t11-/m0/s1 |
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分类
- Amino Acids & Derivatives
- {SNA} Amines, Building Blocks, C15 to C19, C16 to C21, Chemical Synthesis, Ethers, Nitrogen Compounds, Organic Building Blocks, Oxygen Compounds
相关文献及参考
- Chen, Y., et al.: Mol. Pharm., 6, 696 (2009),
- Shen, W., et al.: Bioorg. Med. Chem. Lett., 19, 792 (2009),
安全信息
GHS Symbol
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P304+P340
- P305+P351+P338
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P319
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P362+P364
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- (S)-2,6-Bis-tert-butoxycarbonylaminohexanoic acid
- 上游原料:氢氧化钠 --> 乙酸乙酯 --> 正己烷 --> 1,4-二氧六环 --> 二碳酸二叔丁酯 --> L-赖氨酸 --> 硫酸氢钾 --> L-赖氨酸盐酸盐
- MOL 文件:2483-46-7.mol
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